全文获取类型
收费全文 | 6181篇 |
免费 | 1068篇 |
国内免费 | 796篇 |
专业分类
化学 | 4282篇 |
晶体学 | 42篇 |
力学 | 446篇 |
综合类 | 34篇 |
数学 | 772篇 |
物理学 | 2469篇 |
出版年
2024年 | 10篇 |
2023年 | 132篇 |
2022年 | 160篇 |
2021年 | 186篇 |
2020年 | 227篇 |
2019年 | 243篇 |
2018年 | 179篇 |
2017年 | 183篇 |
2016年 | 274篇 |
2015年 | 304篇 |
2014年 | 302篇 |
2013年 | 364篇 |
2012年 | 543篇 |
2011年 | 605篇 |
2010年 | 404篇 |
2009年 | 322篇 |
2008年 | 425篇 |
2007年 | 379篇 |
2006年 | 359篇 |
2005年 | 333篇 |
2004年 | 284篇 |
2003年 | 198篇 |
2002年 | 177篇 |
2001年 | 147篇 |
2000年 | 113篇 |
1999年 | 149篇 |
1998年 | 106篇 |
1997年 | 118篇 |
1996年 | 127篇 |
1995年 | 116篇 |
1994年 | 82篇 |
1993年 | 67篇 |
1992年 | 59篇 |
1991年 | 65篇 |
1990年 | 69篇 |
1989年 | 54篇 |
1988年 | 41篇 |
1987年 | 27篇 |
1986年 | 34篇 |
1985年 | 27篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1982年 | 11篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1957年 | 3篇 |
排序方式: 共有8045条查询结果,搜索用时 15 毫秒
141.
142.
143.
Morelos A Albuquerque IF Bondar NF Carrigan RA Chen D Cooper PS Dai Lisheng Denisov AS Dobrovolsky AV Dubbs T Endler AM Escobar CO Foucher M Golovtsov VL Gottschalk H Gouffon P Grachev VT Khanzadeev AV Kubantsev MA Kuropatkin NP Lach J Lang Pengfei Li Chengze Li Yunshan Luksys M Mahon JR McCliment E Newsom C Pommot Maia MC Samsonov VM Schegelsky VA Shi Huanzhang Smith VJ Tang Fukun Terentyev NK Timm S Tkatch II Uvarov LN Vorobyov AA Yan Jie Zhao Wenheng Zheng Shuchen Zhong Yuanyuan 《Physical review letters》1993,71(14):2172-2175
144.
145.
146.
A novel self-assembling crosslinking second harmonic generation nonlinear optical (SHG/NLO) film with high SHG coefficient (2×10-7 e.s,u.by IR dichroism) was prepared by morecular design and "in-situ poling and sol-gel process".The content of the NLO chromophore (S)-(-)-1-(4)-mtrophenyl-2-pyrrolidinemethanol (NPP) is as high as 50 mol% since NPP molecules probably disperse in the film at a molecular level The film is rigid,uni form and transparent.This designed clathrate supermolecular structure was poved by IR,atomic force microseopv (AFM) and differential scanning calorimetry (DSC) detection.The title film exhibits a long-term temporal stability with 95% of the initial value of SHG coefficient maintained even after 20 d at 65℃(by UV spectroscopy) 相似文献
147.
我们已对O(~3p)原子和酮类分子化学反应速率常数进行了系列测定,分析讨论了羰基对O(~3p)抽提氢原子反应速率的影响,关于O(~3p)与醛类分子反应速率的测定也有报道。本文用流动微波放电-化学发光光子计数方法测定O(~3p)原子与丙醛和正丁醛化学反应速率常数及其与温度的关系,并由动力学数据对醛基中C—H键的离解能进行了讨论。 相似文献
148.
In this paper, a sensitive and rapid chromatographic procedure using a selective analytical detection method (electrospray ionization-mass spectrometry in selected-ion monitoring mode) in combination with a simple and efficient sample preparation step is first presented for the determination of zaleplon in human plasma. The separation of the analyte, internal standard, and possible endogenous compounds are accomplished on a phenomenex Luna 5-microm C8(2) column (250- x 4.6-mm i.d.) with methanol-water (75:25, v/v) as the mobile phase. In order to optimize the mass detection of zaleplon, several parameters such as ionization mode, fragmentor voltage, m/z ratios of ions monitored, type of organic modifier, and eluent additive in the mobile phase are discussed. An internal standard is selected to guarantee the quantitative accuracy. Each analysis takes less than 6 min. The calibration curve of zaleplon in the range of 0.1-60.0 ng/mL in plasma is linear with a correlation coefficient of > 0.9992, and the detection limit (s/n = 3) is 0.1 ng/mL. The within- and between-day variations (relative standard deviation) in the zaleplon plasma analysis are less than 2.4% (n = 15) and 4.7% (n = 15), respectively. The application of this method is demonstrated for the analysis of zeleplon plasma samples in a Phase-I human pharmacokinetic study. 相似文献
149.
Kim WS Park M Lee DW Moon MH Lim H Lee S 《Analytical and bioanalytical chemistry》2004,378(3):746-752
Fly ash has been regarded as hazardous because of its high adsorption of toxic organic and/or inorganic pollutants. Fly ash is also known to have broad distributions of different chemical and physical properties, such as size and density. In this study, fly ash emitted from a solid waste incinerator was pre-fractionated into six sub-populations by use of gravitational SPLITT fractionation (GSF). The GSF fractions were then analyzed by sedimentation field-flow fractionation (SdFFF) and ICP–AES. SdFFF analysis showed the fly ash has a broad size distribution ranging from a few nanometers up to about 50 µm. SdFFF results were confirmed by electron microscopy. Inductively coupled plasma–atomic emission spectroscopy (ICP–AES) analysis of the GSF fractions showed the fly-ash particles contain a variety of inorganic elements including Ca, Si, Mg, Fe, and Pb. The most abundant in fly ash was Ca, followed by Si then Mg. No correlations were found between trace element concentration and particle size. 相似文献
150.