离子液体二维结构制备及其特性研究进展

由于阴阳离子间特殊的静电、氢键作用,具有二维结构的离子液体呈现出独特的结构特征及热力学、动力学特性,在化学化工和材料领域都有着巨大的应用前景,已成为离子液体领域重要的研究方向之一.本综述重点介绍了离子液体二维结构常用的制备方法,包括自组装法、Langmuir-Blodgett法以及物理气相沉积法,并总结了这些制备方法相应的优缺点.随后归纳了离子液体二维结构的相变特征及在力学和电学方面的特性,并综述了其在摩擦润滑领域的应用.最后展望了离子液体二维结构的发展方向及应用前景.     

Evaluation of glass-forming ability criterion from phase-transformation kinetics

Applying kinetic analysis upon crystallization of metallic glass, a quantitative relation between the critical cooling rate and the onset temperature of crystallization was obtained for glass-forming alloys. Effects of the onset temperature of crystallization, the liquidus temperature and the glass transition temperature on the critical cooling rate were analytically described. Three rules guiding the development of more reliable glass-forming ability criteria are suggested.     

超高效液相色谱-串联质谱法测定乳与乳制品中牛乳铁蛋白

建立了超高效液相色谱-串联质谱技术定量检测乳制品中牛乳铁蛋白含量的方法。样品经脱脂、酶解后,利用超高效液相色谱-四极杆/静电场轨道阱高分辨质谱(UPLC-Q/Exactive-HRMS)和Protein Pilot软件分析,实现了乳铁蛋白及其肽段的鉴定;通过初级局部序列搜索工具(basic local alignment search tool, BLAST)与Uniprot数据库对比分析筛选出牛乳铁蛋白的8个特征肽段;选择其中3个响应强度高、稳定性好的特征肽段进一步通过超高效液相色谱-三重四极杆质谱(UPLC-QqQ-MS)进行验证和多反应监测(MRM)定量研究,并考察了空白基质匹配的外标法和内标法对乳铁蛋白检测结果的差异。采用外标法定量时,3个肽段在各自范围内线性关系良好,检出限为0.023～0.041 mg/kg,定量限为0.077～0.137 mg/kg,平均回收率为93.8%～103.9%,日内精密度≤8.8%,日间精密度≤9.5%。该方法抗干扰能力强,灵敏度高,重复性好,适用于乳及乳制品中牛乳铁蛋白的含量测定。     

一种求解瑞利波散射问题的修正边界元方法

边界元法的一大优势是用于求解半空间等无限域问题,但在求解弹性波的传播问题中,传统边界元法采用的全平面或全空间格林函数会在截断边界处产生虚假的反射回波,这会引起散射场求解的误差.为了避免这种误差,论文在传统边界元法基础上提出一种修正边界元法,该修正方法主要包括:以瑞利波形式的远端散射场代替原本因截断而舍去的部分,通过互易定理建立单位瑞利波和全平面格林函数的积分方程,求得修正系数,并代入修正边界元矩阵,计算出瑞利波的散射场.文中基于该方法计算了无缺陷平面的瑞利波(与解析解的误差为1.24×10-5),并运用该方法计算了不同缺陷的散射场.由文中对比结果表明,论文所提修正边界元法可准确求解瑞利波散射场,为基于表面波的缺陷反演问题研究提供了有效的正演途径.     

Highly selective acetoxylation of sulfonamides via using phenyliodine(III) diacetate

A highly efficient acetoxylation reaction of N-aryl-arylsulfonamides has been developed, presumably proceeding via the selective functionalization of N-aryl C–H bonds. A stoichiometric amount of PhI(OAc)₂ was generally employed as the oxidation reagent, and various para-acetoxylated sulfonamide derivatives had been generated in excellent yields. This chemistry endowed an economic synthesis of valuable acetoxylated sulfonamides through direct C–O bond formation processes.     

CW激光辐照薄板热力响应全场测量

实验研究了CW激光辐照铝合金薄板的热力响应过程,利用三维数字图像相关技术（3D-DIC）结合红外测温系统对整个过程的变形场和温度场实现了全场实时测量。分析了入射激光功率对变形场和温度场的影响,发现变形和温度均随入射激光功率线性增长。建立了三维有限元模型对实验过程进行模拟,模拟结果与实验结果吻合较好,验证了有限元模型的可靠性。3D-DIC结合红外测温系统可以很好地对激光破坏试验中的靶体变形场和温度场进行实时测量,是一种很有效的实验测量手段。     

Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic‐Polymer‐Based Iridium Catalysts

As a new energy source that could replace petroleum, the global reserves of methane hydrate (combustible ice) are estimated to be approximately 20 000 trillion cubic meters. A large amount of methane hydrate has been found under the seabed, but the transportation and storage of methane gas far from coastlines are technically unfeasible and expensive. The direct conversion of methane into value‐added chemicals and liquid fuels is highly desirable but remains challenging. Herein, we prepare a series of iridium complexes based on porous polycarbazoles with high specific areas and good thermochemical stabilities. Through structure tuning we optimized their catalytic activities for the selective monoborylation of methane. One of these catalysts (CAL‐3‐Ir) can produce methyl boronic acid pinacol ester (CH₃Bpin) in 29 % yield in 9 h with a turnover frequency (TOF) of approximately 14 h^?1. Because its pore sizes favor monoborylated products, it has a high chemoselectivity for monoborylation (CH₃Bpin:CH₂(Bpin)₂=16:1).     

Certain Sufficient Conditions for Starlikeness and Convexity of Meromorphically Multivalent Functions

In this paper we derive certain sufficient conditions for starlikeness and convexity of order α of meromorphically multivalent functions in the punctured unit disk.