全文获取类型
收费全文 | 84662篇 |
免费 | 1724篇 |
国内免费 | 1534篇 |
专业分类
化学 | 29316篇 |
晶体学 | 893篇 |
力学 | 7081篇 |
综合类 | 94篇 |
数学 | 32745篇 |
物理学 | 17791篇 |
出版年
2023年 | 150篇 |
2022年 | 279篇 |
2021年 | 293篇 |
2020年 | 325篇 |
2019年 | 327篇 |
2018年 | 10662篇 |
2017年 | 10493篇 |
2016年 | 6365篇 |
2015年 | 1269篇 |
2014年 | 747篇 |
2013年 | 812篇 |
2012年 | 4416篇 |
2011年 | 11171篇 |
2010年 | 6135篇 |
2009年 | 6433篇 |
2008年 | 7081篇 |
2007年 | 9161篇 |
2006年 | 590篇 |
2005年 | 1622篇 |
2004年 | 1788篇 |
2003年 | 2232篇 |
2002年 | 1341篇 |
2001年 | 488篇 |
2000年 | 426篇 |
1999年 | 288篇 |
1998年 | 275篇 |
1997年 | 210篇 |
1996年 | 271篇 |
1995年 | 189篇 |
1994年 | 129篇 |
1993年 | 128篇 |
1992年 | 91篇 |
1991年 | 95篇 |
1990年 | 88篇 |
1989年 | 80篇 |
1988年 | 70篇 |
1987年 | 67篇 |
1986年 | 63篇 |
1985年 | 60篇 |
1984年 | 49篇 |
1983年 | 42篇 |
1982年 | 43篇 |
1981年 | 41篇 |
1980年 | 46篇 |
1979年 | 45篇 |
1914年 | 45篇 |
1913年 | 40篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
121.
122.
稀土固体是重要的激光和光电子材料。目前 ,由于以宽带信号和太赫兹比特数据传输率为特征的信息技术的发展 ,稀土固体材料的相干瞬态动力学过程成为宽带与高速信息光子学的基本物理问题之一。研究了室温下稀土粉末样品Eu3+ ∶Y2 O3自由感应衰减的相干瞬态光谱 ,这有助于理解有效的光吸收动力学、激发态弛豫、相干能量传递和超短光脉冲在稀土固体中的传播。用一对紫外飞秒相干光脉冲作用于稀土粉末样品Eu3+ ∶Y2 O3,然后监测物质激发态的布居数随两个激发脉冲之间的延时的变化 ,测量到其自由感应衰减量子拍 (FID) ,从拍频周期分析确定了其能级精细结构 ,能级的退相时间长达皮秒量级。理论分析和实验结果符合得很好。对稀土离子的量子干涉的研究 ,表明其在受激受控光放大方面具有潜在的应用前景 相似文献
123.
QuanXiangwu YanPingSHI LiYANG 《中国化学快报》2004,15(12):1441-1444
From the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala, three novel eremophilane sesquiterpene lactones, 6α, 10α-dihydroxy- 1-oxoeremophila-7(11), 8(9)-dien-8, 12-olide, 613, 10α-dihydroxy-1-oxoeremophila-7 (ll), 8 (9)-dien-8, 12-olide and 10α-hydroxy-1-oxoeremophila-7(l 1), 8(9)-dien-8, 12-olide were isolated. Their structures were elucidated by various spectroscopic methods including intensive 2D NMR techniques (COSY,HMQC, HMBC and ^1H-^1H NOESY) and HR-MS. 相似文献
124.
XiangGuoSHI DaFangZHONG YuMingSUN YuFengZHANG 《中国化学快报》2004,15(4):431-434
A sensitive analytical method to identify active metabolites of bitespiramycin in rat urine and bile was developed by liquid chromatography-electrospray ionization tandem mass spectrometry(LC/ESI-MS^n).Bitespiramycin and its major active metabolites in rat urine and bile were isolated and identified as M1 serial(spiramycin Ⅰ,Ⅱ,Ⅲ),M2 serial(platenomycin A1,josamycin and leucomycin A1) and M3 serial(deisovalerylplatenomycin A1,deisovaleryljosamycin,deisovalerylleucomycin A1). 相似文献
125.
DongXiangLI WanGuoHOU ShuPingLI MingTuHAO GaoYongZHANG 《中国化学快报》2004,15(2):224-227
The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations. 相似文献
126.
XiangBaoMENG HuiLI QingLI ZhongJunLI 《中国化学快报》2004,15(7):777-778
An unusual reductive ring-opening reaction of phthalimide with sodium hydride in anhydrous DMF was observed for the first time. The presumed mechanism was described in detail. 相似文献
127.
We shall answer several questions concerning additive or multiplicative commutators in a division ring which are algebraic of bounded degree over its center. 相似文献
128.
Panos M. Pardalos Wanpracha Chaovalitwongse Leonidas D. Iasemidis J. Chris Sackellares Deng-Shan Shiau Paul R. Carney Oleg A. Prokopyev Vitaliy A. Yatsenko 《Mathematical Programming》2004,101(2):365-385
There is growing evidence that temporal lobe seizures are preceded by a preictal transition, characterized by a gradual dynamical change from asymptomatic interictal state to seizure. We herein report the first prospective analysis of the online automated algorithm for detecting the preictal transition in ongoing EEG signals. Such, the algorithm constitutes a seizure warning system. The algorithm estimates STLmax, a measure of the order or disorder of the signal, of EEG signals recorded from individual electrode sites. The optimization techniques were employed to select critical brain electrode sites that exhibit the preictal transition for the warning of epileptic seizures. Specifically, a quadratically constrained quadratic 0-1 programming problem is formulated to identify critical electrode sites. The automated seizure warning algorithm was tested in continuous, long-term EEG recordings obtained from 5 patients with temporal lobe epilepsy. For individual patient, we use the first half of seizures to train the parameter settings, which is evaluated by ROC (Receiver Operating Characteristic) curve analysis. With the best parameter setting, the algorithm applied to all cases predicted an average of 91.7% of seizures with an average false prediction rate of 0.196 per hour. These results indicate that it may be possible to develop automated seizure warning devices for diagnostic and therapeutic purposes.Mathematics Subject Classification (1991):20E28, 20G40, 20C20 相似文献
129.
Harish Seshadri 《Mathematische Zeitschrift》2004,247(3):487-503
We study closed Einstein 4-manifolds which admit S1 actions of a certain type, i.e., warped products. In particular, we classify them up to isometry when the fixed point of the S1 action satisfies certain natural geometric conditions. The proof uses the Bochner-Weitzenböck formula for 1-forms and the theory of minimal surfaces in 3-manifolds.in final form: 22 January 2003 相似文献
130.