New Quantum Private Comparison Protocol Using χ-Type State

We present a new quantum private comparison protocol based on the four-particle χ-type states. Different from previous protocols using the four-particle χ-type states, our protocol have some advantages. Without using the entangled character, we only need to prepare one type of χ-type state and N χ-type states. And we use the Pauli local unitary operation on particles to encode the information and to extract information by measurement. We also discuss that our protocol can withstand all various kinds of outside attacks and participant attacks.     

Viscoelastic measurement of complex fluids using forced oscillating torsion resonator with continuously varying frequency capability

Traditional torsional resonators, often obtaining the viscoelastic moduli of complex fluids only at one or several given discrete frequencies, lack the continuously varying frequency capability. This is an obvious disadvantage of the traditional torsional resonator technique. This paper presents an improved strategy, based on our previous discrete-frequency-measuring method (Wang et al., J Rheol 52:999–1011, 2008), to overcome such restriction and thus accomplish the continuously varying frequency capability of the traditional torsional resonator for measuring the viscoelastic properties of complex fluids. The feasibility of this strategy is demonstrated with the Newtonian fluids (several water–glycerol solutions) of viscosities varying from 10 to 1,400 cp by using our homemade torsion resonator apparatus in the 10 ~ 2,500 rad/s frequency range (continuous frequencies). Some results for typical viscoelastic polymers (two polyethylene oxide (PEO) aqueous solutions) are also given. Additionally, a comparison of the PEO results is made with the common rheometer technique. It is demonstrated that this improved strategy could enable the traditional torsional resonators, with one oscillating resonance mode, to work as the microrheological technique and the common rheometer technique in the continuous frequency range.     

“锥形嵌套"结构CNx纳米管的生长机理及拉曼光谱研究

在氮气、氢气以及氯化铵热解产生的氨气环境下,以钴作为催化剂,在780℃—940℃温度范围内使二甲苯与二茂铁受热分解,合成了CNx纳米管.在高分辨率透射电子显微镜下观察,合成的纳米管呈现“锥形嵌套”的形貌特征.从不同结构的分子面形成能的角度探讨了CNx纳米管的催化生长机理.不同温度下所制备样品的拉曼光谱研究表明,ID/IG值可以反映氮的掺杂所带来的纳米管结晶有序程度的降低,并通过G带向高波数移动证实了氮的掺杂.     

Bare-State Time-Evolving Operator Solution to Raman Model in A Configuration

We derive exact analytical expressions of time-evolving bare-state operators of level occupation numbers and the photon numbers for a composite system consisting of a three-level atom interacting with two modes of a quantized electromagnetic field in A configuration. These results demonstrate the oscillations with three-family frequencies for a nonzero detuning, which dramatically differ from the previous results showing only single-family Rabi oscillations.     

壳聚糖亚胺环钯化合物的合成及其催化性能研究

壳聚糖与苯甲醛或其衍生物作用制得壳聚糖席夫碱, 再与氯化钯锂的甲醇溶液作用, 制得壳聚糖亚胺环钯催化剂. 该类催化剂对空气和水稳定, 对于苯乙烯与芳基碘的交叉偶联反应具有较高的催化活性和选择性, 经简单分离回收可重复使用多次. 为立体选择性合成各种取代的1,2-二苯乙烯提供了一种制备简单、实用的高活性绿色催化剂体系.     

[Cp*Rh(CO)2Me]BF4和二环庚二烯的反应机理研究

[Cp^*Rh(CO)₂Me]BF₄与二环庚二烯反应生成的含五元环产物可以作为烯烃/羰基共聚的潜在催化剂。本文采用密度泛函(DFT)方法对该类反应的机理进行了研究。研究表明，甲基转移是整个反应的决速步骤。计算得到，该步反应的活化焓变为71.67 kJ·mol^-1, 跟实验中得到的相应的焓变值(72 ± 2 kJ·mol^-1)吻合得很好。计算结果同时证实，该反应在热力学上非常有利。结构分析表明，二环庚二烯和金属中心配位后，二环庚二烯内的环张力得以释放以及螯合环的生成是导致热力学有利的主要原因。     

Preparation and Characteristics of GaN Films on Freestanding CVD Thick Diamond Films

Prefer-oriented and fine grained polycrystalline GaN films are prepared by plasma enhanced metal organic chemical vapour deposition on nucleation surfaces of freestanding thick diamond films. The characteristics of the GaN films are characterized by x-ray diffraction, reflection high energy electron diffraction and atomic force microscopy. The results indicate that the structure and morphology of the films are strongly dependent on the deposition temperature. The most significant improvements in morphological and structural properties of GaN films are obtained under the proper deposition temperature of 400°C.     

Theoretical mechanistic study on the radical-molecule reaction of CH2Br/CHBrCl with NO2

The radical-molecule reaction mechanisms of CH₂Br and CHBrCl with NO₂ have been explored theoretically at the UB3LYP/6-311G(d, p) level. The single-point energies were calculated using UCCSD(T) and UQCISD(T) methods. The results show that the title reactions are more favorable on the singlet potential energy surface than on the triplet one. For the singlet potential energy surface of CH₂Br + NO₂ reaction, the association of CH₂Br with NO₂ is found to be a barrierless carbon-to-oxygen attack forming the adduct IM1 (H₂BrCONO-trans), which can isomerize to IM2 (H₂BrCNO₂), and IM3 (H₂BrCONO-cis), respectively. The most feasible pathway is the 1, 3-Br shift with C–Br and O–N bonds cleavage along with the N–Br bond formation of IM1 lead to the product P1 (CH₂O + BrNO) which can further dissociate to give P4 (CH₂O + Br + NO). The competitive pathway is the 1, 3-H-shift associated with O–N bond rupture of IM1 to form P2 (CHBrO + HNO). For the singlet potential energy surface of CHBrCl + NO₂ reaction, there are three important reaction pathways, all of which may have comparable contribution to the reaction of CHBrCl with NO₂. The theoretically obtained major products CH₂O and CHClO for CH₂Br + NO₂ and CHBrCl + NO₂ reactions, respectively, are in good agreement with the kinetic detection in experiment.     

Mechanistic and dual-level direct dynamics studies on the reaction Cl + CH2FCl

Theoretical investigations are carried out on the reaction Cl + CH₂FCl by means of direct dynamics method. The minimum energy path (MEP) is obtained at the MP2/6-311G(d, p) level. The energetic information is further improved by single-point energy calculations using QCISD(T)/6-311++G(d, p) method. The kinetics of this reaction are calculated by canonical variational transition state theory incorporating with the small-curvature tunneling correction over a wide temperature range of 220–3,000 K, and rate constant expression are found to be k(T) = 1.48 × 10^?17 T ^2.04exp(?913.91/T). For the title reaction, H-abstraction reaction channel is the major channel at the lower temperatures. At higher temperatures, the contribution of Cl-abstraction reaction channel should be taken into account.     

Spectroscopic Studies of a Water-soluble Derivative of Hypocrellin A and Its One- and Two-Electron Reduction Products

In this study the spectroscopic characteristics of a water-soluble derivative of hypocrellin A (HA), 14-dehydroxy-15-deacetyl-hypocrellin A-13-sulfonate(13-SO3Na-DDHA),and its one- and two-electron reduction products have been investigated. From the changes in absorbance with pH it was observed that the two phenolic hydroxy groups at C-3 and C-10 positions of 13-SO3Na-DDHA or HA dissociated stepwise with increase of pH values. The pKa values for 13-SO3Na-DDHA and HA were determined using an effective method established in this study. Attempts were also made to use absorption and ESR spectroscopies to study the photoreduction of 13-SO3Na-DDHA. It was found that 13-SO3Na-DDHA was directly reduced to its two-electron reduction product in buffered aqueous solution (pH 7. 7). However, in DMF-buffer (1 :1/ v : v,pH 7. 7), it proceeded with one-electron reduction to generate its semiquinone radical anions. The semiquinone radical anions decayed according to second-order kinetics. indicating that the terminatio