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991.
Ho Cheol Jeong Suk Hyun Lim Youngku Sohn Young-Il Kim Hoeun Jang Dae Won Cho Patrick S. Mariano 《Tetrahedron letters》2017,58(10):949-954
Single electron transfer (SET)-promoted photoaddition reactions between fullerene C60 and both various alkyl (Me, Et, i-Pr, t-Bu)- and para-substituted (p-Me, p-OMe, p-F, p-CF3) arene ring containing, N-α-trimethylsilyl-N-alkyl-N-benzylamines were explored to gain information about photoproduct profiles and how the electronic and steric nature of the amine substrates influence reaction efficiencies. The results show that visible light (λ > 540 nm) irradiation of 10% EtOH-toluene solutions containing C60 and N-α-trimethylsilyl-N-alkyl-N-benzylamines produce 1-aminomethyl-1,2-dihydrofullerenes as a sole photoproduct. In addition, SET-promoted photoaddition reactions of unsubstituted and para-electron donating group substituted arene ring containing N-α-trimethylsilyl-N-alkyl-N-benzylamines take place to give photoproducts more efficiently than those containing para-electron withdrawing group substituted arene rings. Moreover, although steric factors are less significant than the electronic nature of the amine substrates in governing reaction efficiencies, sterics do play a significant role in photoreactions of electron deficient amine substrates. 相似文献
992.
This paper discusses the existence of at least one or two nondecreasing positive solutions for the following singular nonlinear third-order differential equation
993.
The crystallization of monodisperse linear polyethylene confined in nanoporous alumina is investigated with the calorimetric measurements. We observe a drastic change in crystallization behavior, specifically nucleation, with a decrease in the pore diameter. Crystallization in relatively larger pores with the diameters of 62 and 110 nm occurs at lower temperatures within a very narrow range, whereas crystallization in smaller pores with diameters of 15-48 nm occurs at a higher and broad range of temperatures. Nucleation and crystallization kinetics in nanopores is discussed based on classical nucleation theory as well as the Avrami theory. 相似文献
994.
Shin H Schweinsberg A Gehring G Schwertz K Chang HJ Boyd RW Park QH Gauthier DJ 《Optics letters》2007,32(8):906-908
When a pulse superposed on a cw background propagates through an erbium-doped fiber amplifier with a negative group velocity, either pulse broadening or pulse compression can be observed. These effects can be explained in terms of two competing mechanisms: gain recovery and pulse spectrum broadening. The distortion of the pulse shape caused by these effects depends on input pulse width, pump power, and background-to-pulse power ratio. With the proper choice of these three parameters, we can obtain significant pulse advancement with minimal pulse distortion. 相似文献
995.
Exercise type and muscle fiber specific induction of caveolin-1 expression for insulin sensitivity of skeletal muscle 总被引:1,自引:0,他引:1
Oh YS Kim HJ Ryu SJ Cho KA Park YS Park H Kim M Kim CK Park SC 《Experimental & molecular medicine》2007,39(3):395-401
It is well known that exercise can have beneficial effects on insulin resistance by activation of glucose transporter. Following up our previous report that caveolin-1 plays an important role in glucose uptake in L6 skeletal muscle cells, we examined whether exercise alters the expression of caveolin-1, and whether exercise-caused changes are muscle fiber and exercise type specific. Fifty week-old Sprague Dawley (SD) rats were trained to climb a ladder and treadmill for 8 weeks and their soleus muscles (SOL) and extensor digitorum longus muscles (EDL) were removed after the last bout of exercise and compared with those from non-exercised animals. We found that the expression of insulin related proteins and caveolins did not change in SOL muscles after exercise. However, in EDL muscles, the expression of insulin receptor beta (IR beta) and glucose transporter-4 (GLUT-4) as well as phosphorylation of AKT and AMPK increased with resistance exercise but not with aerobic exercise. Also, caveolin-1 and caveolin-3 increased along with insulin related proteins only in EDL muscles by resistance exercise. These results suggest that upregulation of caveolin-1 in the skeletal muscle is fiber specific and exercise type specific, implicating the requirement of the specific mode of exercise to improve insulin sensitivity. 相似文献
996.
997.
Nehru K Kim SJ Kim IY Seo MS Kim Y Kim SJ Kim J Nam W 《Chemical communications (Cambridge, England)》2007,(44):4623-4625
A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions. 相似文献
998.
999.
1000.
A novel tren-based tripodal chemosensor 1 bearing a rhodamine and two tosyl groups was synthesized and its sensing behavior toward metal ions was investigated by UV/vis and fluorescence spectroscopies. Addition of a Hg2+ ion to a CH3CN solution of 1 gave a visual color change as well as significantly enhanced fluorescence, while other ions including Pb2+, Zn2+, Cu2+, Ca2+, Ba2+, Cd2+, Co2+, Mg2+, Ag+, Cs+, Li+, and Na+ induced no or much smaller color/spectral changes, which constituted a Hg2+-selective fluorescent chemosensor (OFF-ON). 相似文献