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981.
Jung HS Lee JK Nastasi M Lee SW Kim JY Park JS Hong KS Shin H 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10332-10335
Sol-gel-derived Mg(OH)(2) gel was coated onto TiO(2) nanoparticles, and the subsequent thermal topotactic decomposition of the gel formed a highly nanoporous MgO crystalline coating. The specific surface area of the electrode that was prepared from the core-shell-structured TiO(2) nanoparticles significantly increased compared with that of the uncoated TiO(2) electrode. The increase in the specific surface area of the MgO-coated TiO(2) electrode was attributed to the highly nanoporous MgO coating layer that resulted from the topotactic reaction. Dye adsorption behavior and solar cell performance were significantly enhanced by employing the MgO-coated TiO(2) electrode. Optimized coating of a MgO layer on TiO(2) nanoparticles enhanced the energy conversion efficiency as much as 45% compared to that of the uncoated TiO(2) electrode. This indicates that controlling the extrinsic parameters such as the specific surface area is very important to improve the energy conversion efficiency of TiO(2)-based solar cells. 相似文献
982.
Polyelectrolyte multilayer capsule reactors (PEMCRs) for the synthesis of two types of nanoparticles were prepared. The tunable PEMCRs containing two different functional groups that can be used to synthesize two types of nanoparticles simultaneously and to control the composition of two types of nanoparticles within the shell of PEMCs. These PEMCRs enabled the composition as well as the amount of the loaded two types of nanoparticles within the shell of PEMCs to be controlled by the copolymer ratio and the number of reaction cycles. Another interesting finding is that, as a result of the synthesis of two types of nanoparticles, these specially designed PEMCs containing both silver and goethite nanocrystals can be used as antimicrobial capsules, which can move by an external magnetic field. Such a technology has the potential for use in sterilization at the desirable sites. 相似文献
983.
984.
Jung-Kyen Moon Jung-Won Park Woo Song Lee Young-Jin Kang Hyun-A Chung Mi-Seon Shin Yong-Jin Yoon Ki Hun Park 《Journal of heterocyclic chemistry》1999,36(3):793-798
This paper presents the synthesis of 2-amino-, 2-acetamido- and 2-benzamidothioxanthones and their 10,10-dioxides. 相似文献
985.
Sung Joong Lee Semin Park Jin Young Choi Jae‐Han Shim Eun‐Ho Shin Jeong‐Heui Choi Soo Taek Kim A. M. Abd El‐Aty Jong Sung Jin Dong Won Bae Sung Chul Shin 《Biomedical chromatography : BMC》2009,23(7):719-731
It would be preferable for pesticide residues substituted by hydrolyzable functionality to be analyzed after cooking because their structures are apt to degrade during boiling and/or heating. A liquid chromatography–tandem mass spectrometry (LC‐MS/MS) method for the quantitative determination of 44 pesticide residues with hydrolyzable functional group in five typical vegetable widely consumed in Republic of Korea is described. The sample clean‐up was carried out according to the method of Food Code No. 83 established by the Korea Food and Drug Administration (KFDA). Zorbox XDB‐C18 column was selected for the analysis because of the best peak separation. The LC mobile phase consisted of water and 5 mm methanolic ammonium formate, which resulted in a peak shape with good symmetry at each run. Tandem mass spectroscopic (MS/MS) experiments were performed in ESI positive mode and the multiple reaction monitoring modes. A conventional matrix effect was modified to more comprehensive form 100γij (%). A high matrix effect (30%) was detected for the seven polar pesticides, namely thiamethoxam, clothianidin, acetamiprid, aldicarb, thiacloprid, pirimicarb and methabenzthiazuron. The limits of detection were in the range of 0.1–8.1 µg/kg, indicating a good sensitivity. Most of the recoveries ranged from 70 to 131% with RSDs ≤ 20%. The current method allowed rapid quantitation and identification of low pesticide levels in the cooked vegetable samples. Of the screened pesticide residues, only fluquinconazole and dimethomorph below the maximum residue levels established by the KFDA were detected in onion and cucumber samples. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
986.
Jaehyun Moon Yong-Hae Kim Choong-Heui Chung Su-Jae Lee Dong-Jin Park Yoon-Ho Song 《Applied Surface Science》2008,254(20):6422-6427
The growth of Si oxide by means of a cyclic radio-frequency (rf) plasma oxidation process has been explored in a low temperature range of 100-200 °C. The growth mechanism exhibits Cabrera-Mott (CM) oxidation, that is, the transport of mobile ionic species is assisted by an electric field. The low activation energy of 0.3 eV is attributed to the small size of O− and the assistance of the electric field. The oxide becomes off-stoichiometric as one approaches to the exterior surface of the oxide layer. 相似文献
987.
Soojin Park Wha‐Keun Ahn Sunyoung Lee Sang Yun Han Bum Ku Rhee Han Bin Oh 《Rapid communications in mass spectrometry : RCM》2009,23(23):3609-3620
Ultraviolet (UV) photodissociation (PD) experiments using 266 nm light were performed for a series of phosphopeptide cations in a Fourier transform mass spectrometer. The objective of the experiments was to determine whether 266 nm UV irradiation on the phosphopeptide cations would induce unique peptide backbone dissociation. In addition, the general behavior of the phosphate loss (?80 or ?98 Da) was monitored, particularly for those phosphopeptides with a phosphotyrosine residue that itself is a UV chromophore. For phosphopeptides with a UV chromophore, their photodissociation behavior was very similar to that of low‐energy sustained off‐resonance irradiation collisionally activated dissociation (SORI‐CAD), with a few exceptions. For example, b‐ and y‐type peptide backbone fragments were prevalent, and their dephosphorylation behavior was consistent with that of the SORI‐CAD results. For phosphoserine peptides, the loss of a phosphate group was always observed. On the other hand, for phosphotyrosine peptides, the phosphate loss was found to be dependent on the presence of a basic amino group in the sequence and the charge state of the precursor ions, in agreement with the CAD results in the literature. However, hydrogen atom loss or aromatic side chain loss, which is known to be the excited state specific fragmentation pathway, was rarely observed in our 266 nm UV PD experiments, in contrast to the previous UV PD literature (particularly at 220 nm). The mechanism for these observations is described in terms of dominant internal conversion followed by intramolecular vibrational energy redistribution (IVR). Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
988.
This article proposes a new method for measuring an aggregative efficiency of multiple period production systems. Every organization or firm generates a time series of data that represent its performances in the resource utilization and output production over multiple periods, and often desires an aggregated measure of efficiency for several periods of interest. Data envelopment analysis (DEA) has become an accepted and well-known approach to evaluating efficiency performance in a wide range of cases. However, most of the DEA studies have dealt primarily with ways to gauge the efficiency of production in only a single period so this efficiency reflects the insufficient or partial performance of multiple period productions. The new method is developed through extensions of the concept of Debreu–Farrell technical efficiency and is applied to evaluating the efficiency of cable TV service units with 3-year data. 相似文献
989.
Hye Seok Park Dong Wan Seo Seung Woo Choi Young Gi Jeong Ju Ho Lee Dong Il Kim Whan‐Gi Kim 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1792-1799
Branched sulfonated poly(ether ketone sulfone)s (Br‐SPEKS) were prepared with bisphenol A, bis(4‐fluorophenyl)sulfone, 3,3′‐disodiumsulfonyl‐4,4′‐difluorobenzophenone, and THPE (1,1,1‐tris‐p‐hydroxyphenylethane), respectively, at 180 °C using potassium carbonate in NMP (N‐methylpyrrolidinone). THPE, as a branching agent, was used with 0.4 mol % of bisphenol A to synthesize branched copolymers. Copolymers containing 10–50 mol % disulfonated units were cast from dimethylsulfoxide solutions to form films. Linear sulfonated poly(ether ketone sulfone)s (SPEKS) were also synthesized without THPE. The films were converted from the salt to acid forms with dilute hydrochloric acid. A series of copolymers were studied by Fourier transform infrared, 1H‐NMR spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Sorption experiments were conducted to observe the interaction of sulfonated polymers with water and methanol. The ion‐exchange capacity (IEC), a measure of proton conductivity, was evaluated. The synthesized Br‐SPEKS and SPEKS membranes exhibit conductivities (25 °C) from 1.04 × 10?3 to 4.32 × 10?3 S/cm, water swell from 20.18 to 62.35%, IEC from 0.24 to 0.83 mequiv/g, and methanol diffusion coefficients from 3.2 × 10?7 to 4.7 × 10?7 cm2/S at 25 °C. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1792–1799, 2008 相似文献