Random coil phosphorus chemical shift of deoxyribonucleic acids

Random coil phosphorus chemical shift has been studied using 16 17-nucleotide DNA sequences. Due to the presence of residual base stacking in these sequences, the temperature and sequence effects were investigated at 50 and 55 degrees C. The phosphorus chemical shifts of random coil DNA sequences have been found to be independent of temperature. Sequence effect analysis shows that the phosphorus chemical shift of a nucleotide in a random coil DNA sequence depends on both its 5'- and 3'-nearest neighbors. A trimer model has been used to establish the random coil 31P chemical shift prediction protocol which shows an accuracy of 0.02 ppm.     

Inside or outside a ligand cleft? Synthetic, structural, and kinetic inertness studies of zinc, cadmium, and mercury complexes of cross-bridged cyclam and cyclen

Ethylene cross-bridging of the popular tetraazamacrocyclic ligand cyclam has led to metal complexes with enhanced kinetic inertness. The synthesis and spectral characterization of zinc(II), cadmium(II), and mercury(II) complexes of cross-bridged cyclam (L1) as well as cross-bridged cyclen (L2) are reported along with the details of our synthetic route to L2. X-ray structural studies revealed that all Zn(II) and Cd(II) cations are fully kappa(4)N-coordinated inside the respective ligand's molecular cleft with L1 providing the better fit for Zn(II). While Hg(II) is similarly coordinated to L2, it has been found to complex L1 outside the ligand cleft in a novel exo-kappa(2)N-mode. Solution NMR data of the kappa(4)N complexes are consistent with the presence of only a single cis-folded isomer in each case. Ligand (1)H and (13)C coupling to both (111,113)Cd and (199)Hg in their complexes can be clearly discerned. The relative kinetic inertness of representative cross-bridged complexes in acidic aqueous solution has been assessed and found to be in the following order: Zn(II) > Cd(II)[dbl greater-than] Hg(II). The data also reaffirm that cross-bridged cyclam ligand L1 forms a substantially more inert complex with zinc(II) than either the smaller cyclen analogue L2 or the unbridged 1,4,8,11-tetramethyl-cyclam L3.     

Robust H ∞ Filtering for a Class of Nonlinear Discrete-Time Markovian Jump Systems

This paper considers the problem of the robust H filtering for a class of nonlinear discrete-time Markovian jump systems with real time-varying norm-bounded parameter uncertainty. For each mode, the nonlinearity is assumed to satisfy the global Lipschitz conditions and appears in both the state and measured output equations. The problem that we address is the design of a nonlinear filter which ensures robust stochastic stability and a prescribed H performance level of the filtering error system for all admissible uncertainties. A sufficient condition for the solvability of this problem is obtained in terms of a set of linear matrix inequalities; an explicit expression of a desired nonlinear H filter is also given. Finally, an example is provided to demonstrate the effectiveness of the proposed approach.     

Stabilization and H{infty} control of two-dimensional Markovian jump systems

This paper extends the results obtained for one-dimensionalMarkovian jump systems, to investigate the problems of stochasticstabilization and H control of two-dimensional (2D) systemswith Markovian jump parameters. The mathematical model of 2Djump systems is established upon the well-known Roesser model,and sufficient conditions are obtained for the existence ofdesired controllers in terms of linear matrix inequalities,which can be readily solved by available numerical software.These obtained results are further extended to more generalcases whose system matrices also contain parameter uncertaintiesrepresented by either polytopic or norm-bounded approaches.A numerical example is provided to show the applicability ofthe proposed theories.     

A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction

A highly enantioselective, nitroaldol reaction catalyzed by a chiral Cu(II) bis(oxazoline) complex has been developed. The reaction scope includes both aromatic and aliphatic aldehydes (15 examples) affording products in good yields and enantioselectivities (87-94% ee). An X-ray structure of the catalyst has been provided along with a rationalization of the sense of asymmetric induction.     

Four modes of optical parametric operation for squeezed state generation

We report a versatile instrument, based on a monolithic optical parametric amplifier, which reliably generates four different types of squeezed light. We obtained vacuum squeezing, low power amplitude squeezing, phase squeezing and bright amplitude squeezing. We show a complete analysis of this light, including a full quantum state tomography. In addition we demonstrate the direct detection of the squeezed state statistics without the aid of a spectrum analyser. This technique makes the nonclassical properties directly visible and allows complete measurement of the statistical moments of the squeezed quadrature.Received: 10 March 2003, Published online: 26 August 2003PACS: 42.50.Dv Nonclassical states of the electromagnetic field, including entangled photon states; quantum state engineering and measurementsU.L. Andersen: Present address: Institute of Optics, Information and Photonics, Max-Planck Research Group, University of Erlangen-Nuernberg, 91058 Erlangen, Germany.     

On Some Three-Color Ramsey Numbers

 In this paper we study three-color Ramsey numbers. Let K _i,j denote a complete i by j bipartite graph. We shall show that (i) for any connected graphs G ₁, G ₂ and G ₃, if r(G ₁, G ₂)≥s(G ₃), then r(G ₁, G ₂, G ₃)≥(r(G ₁, G ₂)−1)(χ(G ₃)−1)+s(G ₃), where s(G ₃) is the chromatic surplus of G ₃; (ii) (k+m−2)(n−1)+1≤r(K _1,k , K _1,m , K _n )≤ (k+m−1)(n−1)+1, and if k or m is odd, the second inequality becomes an equality; (iii) for any fixed m≥k≥2, there is a constant c such that r(K _k,m , K _k,m , K _n )≤c(n/logn), and r(C _2m , C _2m , K _n )≤c(n/logn) ^m/(m−1) for sufficiently large n. Received: July 25, 2000 Final version received: July 30, 2002 RID="*" ID="*" Partially supported by RGC, Hong Kong; FRG, Hong Kong Baptist University; and by NSFC, the scientific foundations of education ministry of China, and the foundations of Jiangsu Province Acknowledgments. The authors are grateful to the referee for his valuable comments. AMS 2000 MSC: 05C55     

The Weight Distribution of C 5(1, n)

In [2] the codes C _q (r,n) over were introduced. These linear codes have parameters , can be viewed as analogues of the binary Reed-Muller codes and share several features in common with them. In [2], the weight distribution of C ₃(1,n) is completely determined.In this paper we compute the weight distribution of C ₅(1,n). To this end we transform a sum of a product of two binomial coefficients into an expression involving only exponentials an Lucas numbers. We prove an effective result on the set of Lucas numbers which are powers of two to arrive to the complete determination of the weight distribution of C ₅(1,n). The final result is stated as Theorem 2.     

Finite groups embeddable in division rings

In a tour de force in 1955, S. A. Amitsur classified all finite groups that are embeddable in division rings. In particular, he disproved a conjecture of Herstein which stated that odd-order emdeddable groups were cyclic. The smallest counterexample turned out to be a group of order 63. In this note, we prove a non-embedding result for a class of metacyclic groups, and present an alternative approach to a part of Amitsur's results, with an eye to ``de-mystifying" the order 63 counterexample.

     

Direct observation of the temperature field during ablation of materials by multiple femtosecond laser pulses

We report a direct observation of the temperature field on a steel specimen during ablation by multiple femtosecond laser pulses using an infrared thermography technique. From the experimental results and simulation study of the temperature field, we quantified the deposited thermal power into the specimen during the ablation process. We found that more than two thirds of the incident laser power was deposited in the steel specimen when ablated by multiple femtosecond laser pulses. This result provides further understanding of the heating effect in materials processing by ultrashort laser pulses.