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11.
A complete assignment of the 1H, 13C and 19F NMR spectra of 1,1,4,4-tetrafluoro-2-propylidene-3-methyl-6-tert-butyl-1,4-disila-5-cyclohexene 3, the product of the cycloaddition reaction between tetrafluorodisilacyclobutene 1 and cis, trans-2,4-hexadiene mediated by (n5-C5H5)Mn(CO)3, has been made by means of various 2D NMR chemical shift correlation methods and selective heteronuclear decoupling techniques. An analysis of the three bond 13C-1H coupling constants and two bond 13C-19F coupling constants and the molecular modeling results enabled the determination of the conformation and configuration of compound 3. The conformation of 3 provides insight into mechanistic details of the Mn-mediated cycloaddition. 相似文献
12.
Han-Lang Wu Chen-Chi M. Ma Chia-Hsun Li Tzong-Ming Lee Chih-Yuan Chen Chin-Lung Chiang Chen Wu 《Journal of membrane science》2006,280(1-2):501-508
Poly(amide imide) (PAI) was synthesized using 1,2,4-benzenetricarboxylic anhydride (BTBA) and 4,4′-methylenebis(phenyl isocyanate) (MBPI). SPEEK/PAI blend membranes were prepared and investigated by NMR, GPC, FT-IR and AFM. The chemical structures of PAI and SPEEK were characterized by using NMR and FT-IR. The adsorption of the SPEEK/PAI blend membrane of water or methanol solution was also characterized. The significant swelling of the blend membrane in concentrated methanol solution was explained by the solubility parameter. The water diffusion coefficient (DH2O) was related to the lambda value of the membrane. The SPEEK/PAI blend membrane had a lower proton conductivity and methanol permeability than Nafion. However, the relative selectivity (proton conductivity divided by methanol permeability) of the SPEEK/PAI 70/30 (w/w) blend membrane was 3.46 × 104 S s cm−3, which is closed to that of Nafion (3.30 S s cm−3). 相似文献
13.
Chi-Chang?HuEmail author Hong-Ru?Chiang Chen-Ching?Wang 《Journal of Solid State Electrochemistry》2003,7(8):477-484
The electrochemical characteristics of ruthenium oxides, formed on Ru-plated Ti electrodes in 0.5 M H2SO4 by potential cycling with different CV upper potential limits (E
SU), were systematically compared. The repeated potential cycling between 0.2 and 0.75 V activated the formation/reduction of
surface Ru oxides with hysteretic behavior. This application of repeated CVs also modified the ability of Ru deposits for
hydrogen adsorption/desorption. An irreducible Ru oxide accumulated on the electrode at potentials more positive than ca.
0.95 V, whose capacitive characteristics are applicable for electrochemical supercapacitors. This irreducible oxide was composed
of an aggregate consisting of Ru in various oxidation states, bridged oxygen, OH and water in a 3D-like structure with a relatively
ordered and compact nature, from the X-ray photoelectron spectroscopic and voltammetric results. The surface reconstruction
of the Ru deposits induced by the repeated potential cycling with E
SU≥0.75 V was clearly observed from the SEM photographs. From the X-ray diffraction patterns, all the anodically formed Ru oxides
showed an amorphous nature. 相似文献
14.
The UV light irradiation of isoniazid (I) in methanol four products, isonicotinic acid (II), isonicotinamide (III), N, N′-bis(isonicotinic acid)hydrazide (IV) and isonicotinaldehyde isonicotinyl hydrazone (V), in ethanol three products, (III), (IV) and acetaldehyde isonicotinyl hydrazone (VI) were isolated and identified. Also, the photoreaction mechanism of isoniazid in methanol and ethanol were discussed. 相似文献
15.
16.
Denote bymi(G) the number of maximal independent sets ofG. This paper studies the setS(k) of all graphsG withmi(G) = k and without isolated vertices (exceptG K
1) or duplicated vertices. We determineS(1), S(2), andS(3) and prove that |V(G)| 2
k–1
+k – 2 for anyG inS(k) andk 2; consequently,S(k) is finite for anyk.
Supported in part by the National Science Council under grant NSC 83-0208-M009-050 相似文献
17.
The effects of three-dimensionality on the turbulence producing near-wall structures over a rotating disk are examined using hydrogen bubble visualization. Laser Doppler anemometry measurements of the tangential and radial velocities indicate the flow to resemble that of an infinite disk. It was found that the crossflow acts to reduce vertical mixing during the turbulence ejection events, thus reducing the efficiency of the boundary layer in producing shear stress.This research has been sponsored by the Department of Energy Office of Basic Energy Sciences through Grants DE-FG03-86ER13608 and DE-FG03-93ER12309. 相似文献
18.
19.
For a stochastic matrix (Q
ij
T
)
i,j=1
M
withQ
ij
T
exp(–U(ij)/T) at the off-diagonal positions, we develop an algorithm to evaluate the asymptotic convergence rate of all eigenvalues ofQ
ij
T
asT 0 using Ventcel's optimal graphs. As an application we can compare the convergence rates of some random updating schemes used in image processing.This research was partially supported by the National Science Council, Taiwan and Air Force Office of Scientific Research Contract No. F49620 S5C 0144, and was completed while Tzuu-Shuh Chiang was visiting the Center for Stochastic Processes, Department of Statistics, University of North Carolina, Chapel Hill, NC 27599-3260, USA. 相似文献
20.