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991.
Two series of Al2O3-ZrO2 powders with various contents of ZrO2 were synthesized by sol-gel (chemical polymerization) and coprecipitation methods. The effect of ZrO2 content and preparation method on the structure and texture of the resultant powders were determined. The samples were characterized by nitrogen sorption, thermal gravimetric analysis, X-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. The sol-gel method yields more homogeneous powder and retards the aggregation of particles. It produces powders with a larger surface area, a smaller pore size, and a narrower pore size distribution than the coprecipitated one. The X-ray diffraction results show that the powders are amorphous at the calcination temperature below 700°C for both methods. Incorporation of zirconia into alumina greatly affects the surface properties of the powders upon heating, exerting a protective effect against sintering, and inhibiting both the crystallization of the -Al2O3 phase and the - to -phase transformation. Zirconia is dispersed in alumina matrix and does not form a new structure. 相似文献
992.
Highly effective sulfated zirconia nanocatalysts grown out of colloidal silica at high temperature 总被引:1,自引:0,他引:1
Zhu G Wang C Zhang Y Guo N Zhao Y Wang R Qiu S Wei Y Baughman RH 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(19):4750-4754
A large surface-to-volume ratio is a prerequisite for highly effective catalysts. Making catalysts in the form of nanoparticles provides a good way to achieve the aim. However, agglomeration of nanoparticles during the preparation and utilization of nanocatalysts remains a formidable problem. Here, we present a novel approach in which nano units of catalysts are formed in the matrix of a colloidal carrier, with assistance of a cross-linking agent, and then grow out of the carrier upon calcination at high temperature. This ensures that the catalysts not only do not agglomerate, but also have a low cost and high catalytic efficiency due to the large surface-to-volume ratio and the absence of carbon deposition. The technique is demonstrated by the successful preparation of a binary nanocatalyst that consists of a silica nanoparticle core and a sulfated zirconia (SZ) nanocrystal shell (JML-1). The synthesis was achieved by converting sulfated zirconia (SZ) and silica solutions into a composite gel by means of sol-gel processing in the presence of triethoxysilane as the cross-linking agent, followed by heating at 50 degrees C and calcining at 550 degrees C. Relative to other catalysts, such as pure SZ, non-nanodispersed SZ over silica (SZ/SiO2), and zeolites Y, Beta, and ZSM-5, JML-1 exhibits superior catalytic activity in many reactions. For example, the activity of JML-1 in the production of gasoline by alkylation of 1-butene with isobutene remained at 95% or higher after 20 h of reaction and was over 90% after being regenerated five times. In sharp contrast, SZ and SZ/SiO2 give a high activity only for 2 h and the initial activity of zeolites Beta and ZSM-5 are about 88 and 60%, respectively. These findings demonstrate that non-agglomerated nanoparticles anchored onto a carrier surface can be prepared and the technique provides a versatile route to new highly effective nanocatalyst systems. 相似文献
993.
994.
Yen Wei Ramakrishnan Hariharan Jayanta K. Ray 《Journal of polymer science. Part A, Polymer chemistry》1991,29(5):749-758
A new acetylene-terminated Schiff base monomer, N,N′-(1,4-phenylenedimethylidyne)-bis-(4-ethynylaniline) (PPP), was synthesized and was characterized by nuclear magnetic resonance and infrared spectroscopy. This monomer was then polymerized to yield a new polymer (PPPP) with alternating units of aromatic imine and diacetylene via an oxidative coupling polymerization of the acetylenic terminal groups. The monomer was also polymerized by thermal curing at elevated temperatures up to 400°C to afford a crosslinked polymer network without significant structural decomposition. Thermal properties and thermal reactions of the monomer and the polymers were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The polymers exhibit excellent thermal stabilities in an inert atmosphere. Electronic properties of the polymers are also discussed. 相似文献
995.
Fungal biomass with grafted poly(acrylic acid) for enhancement of Cu(II) and Cd(II) biosorption 总被引:1,自引:0,他引:1
The biomass of Penicillium chrysogenum was modified by graft polymerization of acrylic acid (AAc) on the surface of ozone-pretreated biomass. The sorption capacity for copper and cadmium increased significantly as a large number of carboxyl groups were present on the biomass surface, especially when the carboxylic acid group was converted to carboxylate ions using NaOH. When modeled using the Langmuir isotherm, the sorption capacities were 1.70 and 1.87 mmol g(-1) for copper and cadmium, respectively. The loaded biosorbent was regenerated using HCl solution and used repeatedly over five cycles with little loss of uptake capacity beyond the second cycle. The sorption of the two metals was time-dependent, and the kinetics fitted the pseudo-second-order equation well. The Freundlich, Langmuir, Temkin, and Dubinin-Redushkevich isotherms were used to model the metal sorption isotherms, and the thermodynamic parameters calculated show that the sorption was spontaneous and endothermic under the condition applied and that the biomass has similar sorption affinities for the two metals. Fourier transform infrared and X-ray photoelectron spectroscopy reveal that carboxyl, amide, and hydroxyl groups on the biomass surface were involved in the sorption of copper and cadmium and ion exchange and complexation dominated the sorption process. 相似文献
996.
Flow Injection Analysis of Chloramphenicol by Using a Disposable Wall‐Jet Ring Disk Carbon Electrode
A preanodized screen‐printed ring disk carbon electrode was applied to the determination of chloramphenicol (Ph? NO2, CAP) by flow injection analysis (FIA). By setting up the first irreversible reduction reaction of Ph? NO2 to Ph? NHOH at the disk electrode, the following reversible oxidation of hydroxylamine (Ph? NHOH) to the nitroso (Ph? NO) derivative can be monitored/collected at the ring electrode for CAP analysis. The interference from dissolved oxygen and others can thus be avoided by using this approach and precise CAP determination can be easily performed by FIA under aerobic conditions. Preanodization treatment helps to lower the overpotential of the electrochemical reaction of CAP and favors the selective detection in aqueous medium. Under the optimum conditions, ten repetitive determinations at 1 μM and 10 μM CAP resulted in relative standard deviations of less than 4%, indicating good reproducibility of the system. A linear calibration range of 0.1–20 μM with a detection limit of 0.074 μM (S/N=3) was obtained. Veterinary pharmaceutics were finally analyzed by this sensor to validate its practical applicability. 相似文献
997.
3,3‐Dialkyl‐4,5‐diphenyl‐3H‐pyrazoles undergo readily photoinduced electron transfer (PET) reaction with 2,4,6‐triphenylpyrylium tetrafluoroborate (TPP+) in acetonitrile to produce cyclopropenes and 2H‐pyrroles. During prolonged irradiation, the new ring‐closure products derived from 2H‐pyrroles as the secondary photoproducts are also produced. However, the corresponding ester analog exhibits different behavior to obtain the cyclopropene as the primary photoproduct and a [2+2] dimer of the cyclopropene as the secondary photoproduct. A rationale for the different behavior is offered. 相似文献
998.
Selenium possesses interesting chemical, biochemical and geochemical behaviors. However, studies of its photochemical properties in aqueous systems are scarce. A better understanding of these phenomena is of great importance for further application of such properties to selenium speciation. In this work, the photochemical behavior of selenium and some of its organic compounds have been systematically studied in various aqueous matrices under UV irradiation at 300 nm. It was observed that the photochemical oxidation rate of Se(IV) to Se(VI) was greatly enhanced in the presence of HN03 at ≥1 × 10−3 M, but not by NaNO3. However this photo-oxidation could be inhibited by the presence of Cl−. Under UV irradiation, organoselenium compounds went through two successive photochemical reactions in pure water: a direct photolysis (photo-cleavage) followed by a photo-oxidation to form Se(VI). These two steps could also be greatly accelerated in presence of NO3− although the second step required an acidic condition. The photo cleavage rates varied from one organic compound to another and 10-fold differences were observed. Similarly to Se(IV), the further oxidation to Se(VI) could be prevented by Cl− for all studied organoselenium compounds. Detailed reaction mechanisms involving OH radicals are proposed to explain Se photochemical behaviors in different matrices. 相似文献
999.
Chun-Wei?Yeh Yung-Sheng?Yen Wen-Bin?Lin Chang-Wei?Su Jhy-Der?ChenEmail author Ju-Chun?Wang 《Structural chemistry》2005,16(2):141-148
The compound N, N-di(6-methyl-2-pyridyl)formamidine (HDMepyF) has been exploited in preparation of porous materials of divalent metal complexes of the formulae M(HDMepyF)2(NO3)2 (M=Cd, 1; Co, 2; Ni, 3) and M(HDMepyF)2X2 (M=Mn, X=Cl, 4; M=Mn, X=Br, 5; M=Ni, X=Cl, 6; M=Ni, X=Br, 7). Their structures have been determined by X-ray crystallography. Each metal center of these complexes is approximately octahedrally coordinated by four nitrogen and two halogen or oxygen donor atoms. Complexes 1– 5 and 7 self-assemble through similar hydrogen bonding motifs which involve the C–HsX (X=Cl, Br or O) hydrogen bondings and – stacking interactions between the HDMepyF ligand and the X atoms to form porous structures. 相似文献
1000.
The problem of differentiating spectral data to yield the third and fourth derivatives is converted into one of solving an integral equation of the first kind. This equation is solved by Tikhonov regularization. The method of General Cross Validation is used to guide the choice of the regularization parameter that keeps noise amplification under control. The performance of this route to third and fourth derivative spectra is demonstrated by applying it to a number of published spectra. A computational problem associated with General Cross Validation has been identified. 相似文献