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991.
992.
A previously developed laser spallation technique has been modified to measure the tensile strength of thin film interfaces in-situ at temperatures up to 1100°C. Tensile strengths of Nb/A-plane sapphire, FeCrAl/A-plane sapphire and FeCrAlY/A-plane sapphire were measured up to 950°C. The measured strengths at high temperatures were substantially lower compared with their corresponding strengths at ambient temperature. For example, at 850°C, the interface tensile strength for the Nb/sapphire (151 ± 17 MPa), FeCrAl/sapphire (62 ± 8 MPa) and FeCrAlY/sapphire (82 ± 11 MPa) interface systems were lower by factors of approximately, 3, 5, and 8, respectively, over their corresponding ambient values. These results underscore the importance of using such in-situ measured values under operating conditions as the failure criterion in any life prediction or reliability models of such coated systems where local interface temperature excursions are expected. The results on alloy film interfaces also demonstrate that the presence of Y increases the strength of FeCrAl/Al2O3 interfaces. 相似文献
993.
Two-photon resonant nondegenerate four-wave mixing (NFWM) with the
addition of a coupling field in Ba atomic vapour has been studied. We
find that coherence of the atomic level transitions leads to
suppression of the NFWM signal, giving rise to a dip with a linewidth
that is linearly proportional to the intensity of the coupling field. 相似文献
994.
Solvent and electric field dependence of the photocurrent generation in donor:acceptor blend system 下载免费PDF全文
This paper reports that the blend films of poly
(2-methoxy-5-(2'-ethyl-hexyloxy)-p-phenylene vinylene) (MEH-PPV)
and N,N'-bis(1-ethylpropyl)-3,4: 9,10-perylene bis
(tetracarboxyl diimide) (EP-PDI) with the weight ratio of 1:2.5
have been prepared by spin-coating from chloroform (CF) and
chlorobenzene (CB) solutions respectively. The absorption
spectra and the morphology of the blend films show that large
crystal-like EP-PDI aggregates are formed in film prepared from
CB solution, which corresponds to a new absorption shoulder near
590nm, while there is no shoulder around 590\,nm in the
UV--Vis absorption spectra of the blend film from CF solution.
The electric-field dependence spectra of the photocurrent
generation quantum yield of the film from CB solution shows that
at weak electric field the EP-PDI aggregates act as more
efficient sensitizers, but at strong electric field the quantum
yields become almost invariable over the entire spectral range
no matter what the state of EP-PDI, monomer or aggregate. At
strong electric field, the photocurrent generation yields of
both films from CF and CB solution saturate and their yield
spectra become spectrally similar, mentioning that at strong
electric field the photoexcitons dissociate efficiently and the
free charges are collected by the electrodes almost completely. 相似文献
995.
996.
Evidence for an oxygen diffusion model for the electric pulse induced resistance change effect in transition-metal oxides 总被引:1,自引:0,他引:1
Electric-pulse induced resistance hysteresis switching loops for Pr0.7Ca0.3MnO3 perovskite oxide films were found to exhibit an additional sharp "shuttle tail" peak around the negative pulse maximum for films deposited in an oxygen-deficient ambient. The resistance relaxation in time of this "shuttle tail" peak as well as resistance relaxation in the transition regions of the resistance hysteresis loop show evidence of oxygen diffusion under electric pulsing, and support a proposed oxygen diffusion model with oxygen vacancy pileup at the metal electrode interface region as the active process for the nonvolatile resistance switching effect in transition-metal oxides. 相似文献
997.
高压下MgO的热弹性研究 总被引:1,自引:0,他引:1
利用第一原理平面波赝势方法和广义梯度近似研究了广泛温度和压强范围内MgO的热弹性特性.MgO从低压NaCl到高压CsCl结构的相变压强为397 GPa,表明它在地球内部不会发生相变.在压强上升到150 GPa时,MgO的绝热弹性模量跟0 GPa时的实验值和其他赝势在高压下的计算结果基本一致.从0 GPa上升到20 GPa时,MgO的各向异性逐渐减小;在20?150 GPa时绝对值逐渐增大.MgO明显地违背了Cauchy条件,反应出非中心多体力是重要的.另外,MgO的热力学参量与实验也符合的很好. 相似文献
998.
999.
X.J. Liu Z.Q. Li A. Yu M.L. Liu W.R. Li B.L. Li P. Wu H.L. Bai E.Y. Jiang 《Journal of magnetism and magnetic materials》2007
We have investigated the magnetic, electrical transport and electron spin resonance (ESR) properties of polycrystalline Fe-doped manganite LaMn0.7Fe0.3O3+δ prepared by sol–gel method. A typical cluster-glass feature is presented by DC magnetization and AC susceptibility measurements and a sharp but shallow memory effect was observed. Symmetrical Lorentzian lines of the Mn/Fe spectra were detected above 120 K, where the sample is a paramagnetic (PM) insulator. When the temperature decreases from 120 K, magnetic clusters contributed from ferromagnetic (FM) interaction between Mn3+ and Mn3+/Fe3+ ions develop and coexist with PM phase. At lower temperature, these FM clusters compete with antiferromagnetic (AFM) ones between Fe3+ ions, which are associated with a distinct field-cooled (FC) effect in characteristic of cluster-glass state. 相似文献
1000.
Correlation of foreign exchange rates in currency markets is investigated based on the empirical data of USD/DEM and USD/JPY exchange rates for a period from February 1 1986 to December 31 1996. The return of exchange time series is first decomposed into a number of intrinsic mode functions (IMFs) by the empirical mode decomposition method. The instantaneous phases of the resultant IMFs calculated by the Hilbert transform are then used to characterize the behaviors of pricing transmissions, and the correlation is probed by measuring the phase differences between two IMFs in the same order. From the distribution of phase differences, our results show explicitly that the correlations are stronger in daily time scale than in longer time scales. The demonstration for the correlations in periods of 1986–1989 and 1990–1993 indicates two exchange rates in the former period were more correlated than in the latter period. The result is consistent with the observations from the cross-correlation calculation. 相似文献