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861.
A. Maignan Ch. Simon V. Caignaert B. Raveau 《Zeitschrift für Physik B Condensed Matter》1995,99(1):305-310
The exploration of the magnetic and transport properties of four series of manganese perovskites, Pr0.7Ca0.34−xAxMnO3−δ (A=Sr, Ba), Pr0.7−xLaxCa0.3 MnO3−δ and Pr0.66Ca0.34−x
SrxMnO3−δ has allowed four phases with colossal magnetoresistive (CMR) properties to be isolated: Pr0.7Ca0.25Sr0.025MnO3−δ and Pr0.66Ca0.26Sr0.08MnO3−δ that exhibit a variation of resistance of 2.5. 107% and 109% at μ0 H=5 T for T=88 K and 50 K respectively, Pr0.58La0.12Ca0.3 MnO3−δ that exhibits a variation of 6.106% for μ0 H=5 T at T=80 K and Pr0.7Ba0.025Ca0.275MnO3−δ for which a resistance variation of 5.109%, at T=50 K, for μ0 H=5 T is evidenced. for each compound of this series except the barium phase, one observes that the temperature Tmax, which corresponds to the resistance maximum on the R(T) curves in zero magnetic field, increases dramatically as the mean
size of the interpolated cations increases, and that the CMR effect correlatively decreases dramatically. The comparison of
the two series Pr0.7Ca0.3−xSrxMnO3−δ and Pr0.66Ca0.34−xSrxMnO3−δ shows also the crucial role of the hole carrier density: for a same mean ionic radius of the interpolated cation Tmax is decreased of about 50 K by introducing 0.034 hole per Mn mole. 相似文献
862.
Electric fields of the anions, cations and neutral forms of 2-aminopurine and 6-thioguanine have been mapped. Certain important
features of the maps are similar to those found earlier in the neutral and ionic forms of adenine and guanine. The computed
electric field patterns satisfactorily explain reactive sites and biological activity of the molecules. 相似文献
863.
We study the stochastic dynamics of deposition-evaporation cooperative processes of dimers, trimers, etc., in two- and higher-dimensional lattices. The dimer system in bipartite lattices allows for an exact solution of dynamic correlations and scaling functions by means of a quantum spin equivalence. Autocorrelations exhibit a diffusive asymptotic kinetics and crossovers of different dynamic regimes in highly anisotropic lattices. Monte Carlo simulations combined with finite-size scaling arguments support the validity of the diffusive picture in more general situations. Steady-state coverages and diffusion constants are obtained using mean-field approaches, spin wave calculations, and random walk analyses in nearly jammed configurations. 相似文献
864.
P. C. Chen 《中国化学会会志》1995,42(5):755-760
Three ab initio calculations (HF/6-3IG, HF/6-3IG*, and HF/6-3IG**) on 2,4,6-trinitrotoluene were made, The results compare well with xray data, except dihedral angles of NO2 relative to the plane of the benzene ring. The deviations are attributed to packing forces and steric effects in the crystal. The most stable structure was a torsional angle 10° of the methyl top with the benzene ring, unlike toluene. The rotational barriers of the methyl top and the 4-nitro group are small. Hydrogen bonding, dipole moments and total atomic charges arc calculated. 相似文献
865.
The determination of the enantiomeric purity of 2 or 3-substituted cyclanones, particularly cyclohexanones, is conveniently achieved by derivatisation into cyclic aminals with commercially available (R, R)-1,2-diphenylethylenediamine. The derivatisation procedure is directly done into the NMR tube, instantaneously, and 13C NMR allows an accurate measure of the ee. 相似文献
866.
B. M. Dzhagarov N. N. Kruk N. V. Konovalova A. A. Solodunov I. I. Stepuro 《Journal of Applied Spectroscopy》1995,62(2):285-289
Presented at the XV IUPAC Symposium on Photochemistry, Prague, July 17–22, 1994. 相似文献
867.
868.
M. E. Movsesyan A. V. Papoyan C. B. Shmavonyan 《Journal of Russian Laser Research》1995,16(2):172-177
The results of the experimental investigation of the radiation amplification due to the stimulated four-photon parametric process in potassium vapor are reported. Two cells with active medium (an oscillatoramplifier system) are used in the experiments. The dominating role of IR radiation 6S → 5P (3.66 µm) in the amplification of violet radiation 5P → 4S (0.4 µm) generated due to the parametric process at two-photon excitation 4S → 6S is shown. This role is conditioned by optically pumped stimulated emission (OPSE). Optical conditions for the amplification of a seed radiation are determined in accordance with their intensity and the buffer gas (He) pressure. The problem of the image conversion from the IR to a visible one with quantum efficiency above 100% is discussed. 相似文献
869.
The article is concerned with a characterization of quasi-symmetric (QS) designs with intersection numbers 0 and y. It uses the idea of a good block. Such a block G has the property that for any block B with |G ∩ B| = y, every point is on a block containing G ∩ B. It is proved that if a QS design II with intersection numbers 0 and y has a good block, then II must (i) be affine, symmetric, a linear space or (ii) have one of two possible exceptional parameter sets. Only one example is known in case (ii). If all blocks of II are good and II is not a linear space, then it is a projective or affine geometry or it is an extension (in a more general sense than usual) of a projective plane of order y2 or y3+ y. © 1995 John Wiley & Sons, Inc. 相似文献
870.
B R Sitaram 《Pramana》1995,44(4):295-302
The invariants of chaotic bounded Hamiltonian systems and their relation to the solutions of the first variational equations
of the equations of motion are studied. We show that these invariants are characterized by the fact that they either lose
the property of differentiability as functions on phase space or that a certain formal power series defined in terms of the
derivatives of the invariants has zero radius of convergence. For a specific example, we show that the former possibility
appears to apply. 相似文献