β－环糊精对Pb（Ⅱ）－四（－3溴－4－磺酸基苯基）卟啉显色反应增敏作用的研究

本文研究了β－环糊槽（β－ＣＤ）对Ｐｂ（Ⅱ）－四（－３溴－４－磺酸基苯基）卟啉（ｍ－Ｂｒ－ＴｐｐＳ４）显色体系的增敏作用，提出了高灵敏度测定痕量铅的分光光度新方法。显色体系的表观摩尔吸光系数为２．５×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。铅在０－１０μｇ／２５ｍＬ范围内符合比耳定律。稳定性好，操作简便，快速。本方法适用于人发和白酒等试样中铅的测定。回收率在９４％－１０３％。     

衍射光学元件的解析分析方法

从波动光学传播的菲涅尔衍射出发，探讨一次光学转换形成任意要求的图形的问题。导得两平行传播平面的函数关系，从而在确定像面分布的条件下可以逆求出原始面的振幅与倍相分布。文中给出了几个实例，充分表明这是有实用价值的一种衍射光学元件设计方法。     

Laser-induced etching of polycrystalline Al2O3TiC in KOH aqueous solution

Laser-induced etching of polycrystalline Al₂O₃TiC material by a tightly-focused cw Ar ion laser has been investigated in a KOH solution with different concentrations. It is found that the KOH concentration can strongly affect the etching quality where low KOH concentration can result in rough and irregular patterns. Laser-induced etching of polycrystalline Al₂O₃TiC in a KOH solution is found to be a photothermal reaction in which a threshold laser power exists. With an appropriate set of etching parameters, well-defined grooves can be obtained with clean side walls and with an etching rate up to several hundred micrometers per second. The etching behavior is also found to depend on laser scanning direction. It is also found that the grains in the polycrystalline Al₂O₃TiC material play an important role in the etching dynamics and etching quality. This etching process is believed to be applicable to the formation of a slider surface of magnetic heads in the future.     

Study of synthetic diamonds by dynamic nuclear polarization-enhanced13C nuclear magnetic resonance spectroscopy

Four I_b-type synthetic diamond crystals were studied by dynamic nuclear polarization (DNP)-enhanced high resolution solid state¹³C nuclear magnetic resonance (NMR) spectroscopy. The home built DNP magic-angle-spinning (MAS) NMR spectrometer operates at a field strength of 1.9 T and the highest DNP enhancement factor of synthetic diamonds came near to 10³. Comparing with I_b-type natural diamonds, the¹³C NMR linewidths of synthetic diamonds in static spectra are broader. The¹³C spin-lattice relaxation time and DNP polarization time of synthetic diamond are shorter than those of I_b-type natural diamond. From the hyperfine structure of the DNP enhancement curve, four kinds of nitrogen-centred free radicals could be identified in synthetic diamond.     

傅里叶红外光谱法鉴别部分胡椒属生药的研究

利用共有峰率和变异峰率双指标,以胡椒属七种药用植物的红外指纹图谱为依据,计算出所测样品的共有峰率和变异峰率。建立了胡椒属七种药用植物共有峰率和变异峰率双指标序列,结果揭示了胡椒属七种药用植物的亲缘关系。中药海风藤与石南藤、大叶蒟根茎的共有峰率均在77%以上,变异峰率均在30%以下,此三种胡椒属药用植物亲缘关系较近;海风藤与胡椒根茎、十八症根的共有峰率在61%左右,亲缘关系稍远;海风藤与蒌叶根茎的共有峰率仅为44%。亲缘关系较远。利用红外二阶导数谱图,可以鉴别中药海风藤及其伪品石南藤、十八症根、大叶蒟根茎、胡椒根茎等品种。傅里叶红外光谱法可以对样品进行无损处理,不需要对药材进行复杂的提取分离过程即可提供化合物的官能团、类别、氢键等信息。该法能从整体水平分析谱图特征峰,具有分析速度快,重现性好,非破坏性和样品量小,制样简单,专属性强,节约成本,保护环境等优点。可以解决中药海风藤因资源短缺,伪品较多,鉴别困难等问题,也可为临床用药的安全、有效提供保障。傅里叶红外光谱法为胡椒属药用植物亲缘关系的探讨和真伪鉴别提供了一种新方法。符合中药向综合分析和整体分析发展的趋势。     

An alternative phase modulator half-wave voltage measurement based on photonic link

We measure the half-wave voltage of LiNbO 3 phase modulators in a 26-GHz wideband frequency range, and then analyze it by the phase modulation photonic peak gain linked to the interferometric demodulation. The optical interferometer is constructed with two 50:50 couplers and two fiber arms with a 1-m difference in fiber length. The photonic link gain peaks are frequency dependent, as indicated by the differential time delay in the interferometer. The procedure described is a new and practical half-wave voltage measurement method that can accurately predict the nonlinear frequency characteristics of the phase modulator. Moreover, the method can be applied to various types of LiNbO 3 phase modulators.     

Two-dimensional particle-in-cell plasma source ion implantation of a prolate spheroid target

A two-dimensional particle-in-cell simulation is used to study the time-dependent evolution of the sheath surrounding a prolate spheroid target during a high voltage pulse in plasma source ion implantation. Our study shows that the potential contour lines pack more closely in the plasma sheath near the vertex of the major axis, i.e. where a thinner sheath is formed, and a non-uniform total ion dose distribution is incident along the surface of the prolate spheroid target due to the focusing of ions by the potential structure. Ion focusing takes place not only at the vertex of the major axis, where dense potential contour lines exist, but also at the vertex of the minor axis, where sparse contour lines exist. This results in two peaks of the received ion dose, locating at the vertices of the major and minor axes of the prolate spheroid target, and an ion dose valley, staying always between the vertices, rather than at the vertex of the minor axis.     

基于多项式模型法的低端数码相机的颜色特性化

近年来随着数字技术,以及彩色数字图像输入输出设备的不断发展和广泛使用,颜色在不同的设备之间精确的传递或再现成为该领域的重要课题。本论文以彩色数码相机特性化为研究内容,采用多项式转换方法,研究了多项式回归模型不同系数矩阵、不同训练样本对数码相机特性化精度的影响,得出了系数矩阵为11×3多项式模型时误差较小(2.874ΔE*ab)的结论,达到了实用水平。     

Structure and Properties of Ultradrawn Polylactide/Thermoplastic Polyurethane Elastomer Blends

Highly oriented self-reinforced 80/20 blends of polylactide (PLA)/thermoplastic polyurethane elastomer (TPU) were successfully fabricated through solid hot stretching technology. Different from the isotropic sample, stress rose rapidly in a low strain region, and exhibited strain hardening for the drawn samples of the PLA/TPU blend. Superior mechanical properties of the blend, with the notched Charpy impact strength 150 KJ/m², and tensile strength 197 MPa, were achieved. With increasing hot stretch ratio, the storage modulus increased, the glass transition temperatures of the PLA-rich phase and TPU-rich phase in the blends moved to higher temperatures, and the melting temperature and crystallinity of the blend increased, indicating the stress-induced crystallization of the blend during drawing. The longitudinal fracture surfaces of the blends at different stretch ratios exhibited orderly arranged fibrillar bundle structure, which contributed to the significantly higher strength and toughness of the blend.     

Amphoteric refraction exhibited by anisotropic crystals

Amphoteric refraction of light ray at the interface between isotropic materials and anisotropic materials is analyzed. Depending on the incident angle, the refractive light ray can either refract positively or negatively. This amphoteric refraction phenomenon can be quite prevalent when the difference of the two principal refractive indices is large. The reflectance under various incident angles has also been calculated, and an experimental demonstration with a calcite crystal in air is presented.