照相光谱增感染料在溴化银沉淀表面的吸附及吸附热测量

用离心分离法得到25℃菁染料Ⅱ和Ⅲ分别在几种溶剂的溴化银分散系中的吸附等温线;记录了染料溶液的吸收光谱和吸附态染料的反射光谱。采用精密量热技术得到25±0.01℃溴化银从DMF-水溶液中吸附染料Ⅱ等位摩尔吸附热为-(3.18±0.09)KJ/mol(θ=0.87)。还对从DMF溶液中吸附染料Ⅱ的体系绘制了以单位溴化银表面的吸附热表示的吸附等温线,表明用精密量热技术可以研究染料的吸附过程。     

二(2-乙基已基)磷酸(HDEHP)萃取钴(Ⅱ)、镁的研究

本文在25±1℃时考察了HDEHP-煤油/0.1MNaCl体系对Co(Ⅱ)、Mg的萃取.     

Inocalophyllins A,B and their methyl esters from the seeds of Calophyllum inophyllum

Fractionation of the ethanolic extract of the seeds of Calophyllum inophyllum L. has resulted in the isolation of four novel pyranocoumarin derivatives, designated as inocalophyllins A (1), B (2) and their methyl esters (3, 4) in addition to the known calophyllolide. The structures of these compounds have been determined on the basis of spectroscopic analysis including MS, heteronuclear single quantum coherence (HSQC), heteronuclear multiple bond connectivity (HMBC) and two dimensional incredible natural abundance double quantum transfer experiment (2D-INADEQUATE). Two new methylated products, 5 and 6 were also prepared by methylation of compounds 1 and 2, respectively.     

HAD: an automated database tool for analyzing screening hits in drug discovery

Collecting, organizing, and reviewing chemical information associated with screening hits are human time-consuming. The task depends highly on the individual, and human errors may result in missing leads or wasting resources. To overcome these hurdles, we have developed a decision support system, Hits Analysis Database (HAD). HAD is a software tool that automatically generates an ISIS database file containing compound structures, biological activities, calculated properties such as clogP, hazard fragment labels, structure classifications, etc. All data are processed by available software and packed into a single SD file. In addition to search capabilities, HAD provides an overview of structural classes and associated activity statistics. Chemical structures can be organized by maximum common substructure clustering. The ease of use and customized features make HAD a chief tool in lead selection processes.     

Electronic stability of magnetic Fe/Co superlattices with monatomic layer alternation

We report a surprising observation that the growth of the [Fe(1 ML)/Co(1 ML)](n) superlattice of L1(0) structure on Cu(100) is stable only up to six atomic layers (n=3), which cannot be rationalized by stress arguments. Instead, first-principles calculations reveal a transition from the L1(0) to the B2 structure due to the effect of dimensionality on the stability of the electronic structure of the superlattice. Whereas the majority-spin electrons are energetically insensitive to the layer thickness, the minority-spin electrons induce the transition at n=3.     

Si-based nanoscale SiO2 islands and light-emitting source array

A SiO₂ nanoscale island array was fabricated on a Si substrate by using anodic porous alumina as a mask. Transmission electron microscopy observation and the atomic force microscopy pattern show that the arrangement of SiO₂ islands has a quasi-hexagonal symmetry. Ge ions with a dose of 1×10¹⁷ cm^-2 were subsequently implanted into the SiO₂ island array to form Ge-related light-emitting centers. The photoluminescence (PL) spectra of as-implanted and annealed samples show three PL bands at 370, 400 and 415 nm. Their intensities reach maximums in the sample with an annealing temperature of 700 °C. Spectral analysis suggests that the 370 and 415 nm PL bands arise from Ge-Ge and Ge-Si defect centers, while the 400 nm PL is related to GeO color centers in the SiO₂ islands. The existence of these PL bands indicates the formation of a Si-based nanoscale light source array. PACS 78.55.Mb; 42.72.Bj; 68.65.+g     

Interplay between anisotropic strain relaxation and uniaxial interface magnetic anisotropy in epitaxial Fe films on (001) GaAs

Grazing incidence x-ray diffraction study of Fe epitaxial ultrathin films (1.5-13 nm) on GaAs (001) reveals an anisotropy of both domain shape and strain, with [110] and [1-10] as the principal directions. It is shown that the observed thickness-dependent strain anisotropy, together with a uniaxial interface term, can provide an unambiguous explanation to the usual in-plane magnetic anisotropy and its thickness dependence observed in this magnetic thin-film system.     

Ion-implanted Nd:YVO(4) planar waveguide: refractive-index characterization and propagation mode reduction

We report for what is believed to be the first time planar waveguide formation and propagation mode reduction in Nd:YVO(4) crystal, which were achieved by 3.0-MeV silicon-ion implantation followed by annealing under specific conditions. After the implantation, an enhanced refractive-index region was formed with a width of ~2microm beneath the sample surface to act as a waveguide structure. We found that there were four propagation modes for the as-implanted Nd:YVO(4) waveguide, whereas after annealing at 240-360 degrees C for several hours the number of modes could be reduced to three, two, and one. After annealing at 400 degrees C for 1 h the monomode waveguide was destroyed completely, and no mode was observed in the sample.     

Calculation of triaxial superdeformation in <Superscript>174</Superscript>Hf

A two-dimensional Total Routhian Surface (TRS) calculation with the fixed hexadecapole deformation ε4 = 0.03 was carried out for several configurations of 174Hf. Results indicate that the shell corrections have an important contribution to the formation of triaxial superdeformation in 174Hf and some possible configuration assignments are made to the 4 TSD bands experimentally found in 174Hf.