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981.
L. Chekli B. Bayatsarmadi R. Sekine B. Sarkar A. Maoz Shen K.G. Scheckel W. Skinner R. Naidu H.K. Shon E. Lombi E. Donner 《Analytica chimica acta》2016
Zero-valent iron nanoparticles (nZVI) have been widely tested as they are showing significant promise for environmental remediation. However, many recent studies have demonstrated that their mobility and reactivity in subsurface environments are significantly affected by their tendency to aggregate. Both the mobility and reactivity of nZVI mainly depends on properties such as particle size, surface chemistry and bulk composition. In order to ensure efficient remediation, it is crucial to accurately assess and understand the implications of these properties before deploying these materials into contaminated environments. Many analytical techniques are now available to determine these parameters and this paper provides a critical review of their usefulness and limitations for nZVI characterisation. These analytical techniques include microscopy and light scattering techniques for the determination of particle size, size distribution and aggregation state, and X-ray techniques for the characterisation of surface chemistry and bulk composition. Example characterisation data derived from commercial nZVI materials is used to further illustrate method strengths and limitations. Finally, some important challenges with respect to the characterisation of nZVI in groundwater samples are discussed. 相似文献
982.
983.
Takuro Hosomi Dr. Hiroshi Masai Prof. Dr. Tetsuaki Fujihara Prof. Dr. Yasushi Tsuji Prof. Dr. Jun Terao 《Angewandte Chemie (International ed. in English)》2016,55(43):13427-13431
We report the synthesis of an insulated π‐conjugated polymer containing 2,2′‐bipyridine moieties as metal coordination sites. Metal coordination to the polymer enabled easy and reversible tuning of the luminescent color without changes to the main chain skeleton. The permethylated α‐cyclodextrin (PM α‐CD)‐based insulation structure allowed the metalated polymers to demonstrate efficient emission even in the solid state, with identical spectral shapes to the dilute solutions. In addition, the coordination ability of the metal‐free polymer was maintained in the solid state, resulting in reversible changes in the luminescent color in response to the metal ions. The synthesized polymer is expected to be suitable for application in recyclable luminescent sensors to distinguish different metal ions. 相似文献
984.
To clarify the applicability of locally reacting boundary conditions in wave-based numerical analyses of sound fields in rooms, we numerically analyzed a non-diffuse sound field in a room with unevenly distributed sound absorbing surfaces and investigated the differences between the extended and local reactions. Each absorbing surface was a porous material layer backed by a rigid wall. Simulations were performed by the fast multipole boundary element method, a highly efficient boundary element method using the fast multipole method. At low frequencies, the extended and local reactions yielded similar reverberation decay curves because of the influence of the room. However, when the random incidence absorption coefficients were small at low frequencies or frequencies were high, the difference was greater than expected from the corresponding Eyring decay lines. We conclude at high frequencies, the locally reacting boundary conditions lead to a longer reverberation time than that expected from the absorption coefficient differences between the extended and local reactions. These differences were similar in sound-pressure-level and sound-intensity-level distributions, and in the oblique incidence absorption coefficient of the absorbing surfaces, but were increased at low frequencies. 相似文献
985.
Yasushi Koyama Ichiro Takatsuka Mariko Kanaji Koichi Tomimoto Mariko Kito Toshio Shimamura Jinpei Yamashita Kayoko Saiki Kiyoshi Tsukida 《Photochemistry and photobiology》1990,51(1):119-128
Abstract— Carotenoids extracted from the reaction center (RC), the light-harvesting complex (LH), and the chromatophore membrane of Rhodospirillum rubrum SI were analyzed by high-performance liquid chromatography. The chemical structures and the configurations of major components were determined by means of mass, Raman, electronic absorption and 1 H-NMR spectroscopy. The results indicated: (1) 15- cis -spirilloxanthin is bound to RC; (2) both all-frans-spirilloxanthin and aII-(ran.s-3,4-dihydrospirilloxanthin are bound to LH and (3) 13-cK-spirilloxanthin is additionally present in the chromatophore membrane. The natural selection of the carotenoid configurations, i.e. 15-ris by RC and aW-trans by LH, is discussed in relation to the physiological functions and the photophysical properties of isomeric carotenoids. 相似文献
986.
[reaction: see text] Asymmetric amination of 2,3-allenyl phosphates with nitrogen nucleophiles such as amines, hydroxylamines, and imides can be performed efficiently using a combination of zerovalent palladium complexes and SEGPHOS or MeOBIPHEP ligand, affording the corresponding optically active 1-aminated derivatives with enantiomeric excess of up to 97% ee. 相似文献
987.
Kobayashi K Fukuhara H Kawamoto I Hata T Sekine A Uekusa H Ohashi Y 《Chemical & pharmaceutical bulletin》2002,50(12):1570-1573
The characterizations of the anhydrate (A-form), monohydrate (B1-form), and dihydrate (B2-form) of CS-834 were investigated by powder X-ray diffraction, differential scanning calorimetry (DSC), thermogravimetry-differential thermal analysis (TG-DTA), infrared spectroscopy, and Karl Fischer moisture titration. The typical DSC curve of the B2-form showed five endothermic peaks at 35.0, 46.4, 56.2, 99.2, and 190.4 degrees C and an exothermic peak at 123.4 degrees C. In TG-DTA analysis, the three peaks at 35.0, 46.4, and 56.2 degrees C had a total weight loss of 7.3%, corresponding to the release of two water molecules. From morphological observation under thermomicroscopy, the endothermic peak at 99.2 degrees C was attributed to the melting of the dehydrous crystals (B0-form) and the exothermic peak at 123.4 degrees C to the recrystallization to the A-form crystals. The endothermic peak at 190.4 degrees C was due to the melting of the A-form crystals. After incubation for 6.0 h at 35, 50, 60, and 80 degrees C, the powder X-ray diffraction patterns of the B2-form indicated that it was converted into the A-form via the B1-form and B0-form. Thus CS-834 exists in homologous hydrous crystal forms in multiple-phase transformations with the dehydration of two water molecules. 相似文献
988.
Efficient in-gel digestion procedure using 5-cyclohexyl-1-pentyl-beta-D-maltoside as an additive for gel-based membrane proteomics 总被引:2,自引:0,他引:2
Katayama H Tabata T Ishihama Y Sato T Oda Y Nagasu T 《Rapid communications in mass spectrometry : RCM》2004,18(20):2388-2394
A cycloalkyl aliphatic saccharide, 5-cyclohexyl-1-pentyl-beta-D-maltoside (CYMAL-5), was evaluated as a novel additive in a high-throughput in-gel protein digestion system using 96-well plates. Addition of 0.1% CYMAL-5 (final concentration) during trypsin treatment was compatible with both matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) and liquid chromatography/tandem mass spectrometry (LC/MS/MS) analysis, and gave a better digestion efficiency than n-octylglucoside, which we previously reported. In-gel reduction and alkylation of Cys residues under denaturing conditions also improved the sequence coverage of peptides. In-gel tryptic digestion with the optimum combination of 0.5 mm thick gels, negative staining, alkylation under denaturing conditions (6 M guanidine hydrochloride), and digestion in the presence of CYMAL-5, gave excellent performance especially for membrane protein analysis, where recovery of hydrophobic peptides was markedly enhanced. The new protocol is simple and convenient, and should be widely applicable to gel-based proteomics. 相似文献
989.
Akihiro Ohkubo Katsufumi Aoki Yuichi Sato Kohji Seio Mitsuo Sekine 《Tetrahedron letters》2005,46(51):8953-8957
A set of diastereomeric TpT phosphoramidite building blocks, 1-f and 1-s, containing an alkaline-labile hydroxymethylphosphonate (HMP) linkage were synthesized. Dodecadeoxynucleotides incorporating the HMP bond were also synthesized by use of each stereochemically pure dimer block under mild conditions in the N-unprotected phosphoramidite method. Moreover, it turned out that HMP-oligonucleotides derived from a fast-eluted dimer block exhibit higher affinity for DNA single and double strands than those containing a slow-eluted one. 相似文献
990.
Shinsuke Nishida Yasushi Morita Tomohiro Ohba Kazunobu Sato Kazuhiro Nakasuji 《Tetrahedron》2007,63(32):7690-7695
3-Oxophenalenoxyl derivatives, neutral π-radicals having two oxygen atoms at 1,3-position on a phenalenyl skeleton, possess most of their spin densities at the two oxygen atoms and the 2-position, featuring in easy dimerization at the 2-position. For the decrease in spin density at the 2-position by invoking spin-delocalization into the 2-substituted π-systems, we have designed 2-thienyl-3-hydroxyphenalenone derivatives as synthetic precursors of neutral π-radicals, and conducted their oxidation reactions by using a variety of oxidants. The chemical structures of the dimer obtained were unambiguously determined by FABMS, IR, and NMR spectra with help of density functional theory calculations, showing the formation of the bonds on the thienyl moieties. These observations and DFT calculations illustrate the occurrence of a considerable amount of spin-delocalization into the 2-substituted-thienyl moieties from the 3-oxophenalenoxyl skeletons. 相似文献