全文获取类型
收费全文 | 1323篇 |
免费 | 45篇 |
国内免费 | 9篇 |
专业分类
化学 | 1065篇 |
晶体学 | 8篇 |
力学 | 16篇 |
数学 | 75篇 |
物理学 | 213篇 |
出版年
2022年 | 9篇 |
2021年 | 17篇 |
2020年 | 9篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 6篇 |
2016年 | 21篇 |
2015年 | 14篇 |
2014年 | 35篇 |
2013年 | 59篇 |
2012年 | 76篇 |
2011年 | 72篇 |
2010年 | 36篇 |
2009年 | 27篇 |
2008年 | 57篇 |
2007年 | 74篇 |
2006年 | 64篇 |
2005年 | 77篇 |
2004年 | 75篇 |
2003年 | 60篇 |
2002年 | 75篇 |
2001年 | 20篇 |
2000年 | 27篇 |
1999年 | 20篇 |
1998年 | 9篇 |
1997年 | 14篇 |
1996年 | 30篇 |
1995年 | 17篇 |
1994年 | 18篇 |
1993年 | 10篇 |
1992年 | 20篇 |
1991年 | 11篇 |
1990年 | 9篇 |
1989年 | 11篇 |
1988年 | 19篇 |
1987年 | 13篇 |
1986年 | 15篇 |
1985年 | 18篇 |
1984年 | 25篇 |
1983年 | 14篇 |
1982年 | 23篇 |
1981年 | 8篇 |
1980年 | 13篇 |
1979年 | 18篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1976年 | 12篇 |
1975年 | 6篇 |
1974年 | 9篇 |
1967年 | 6篇 |
排序方式: 共有1377条查询结果,搜索用时 31 毫秒
141.
Measurement Accuracy in Phase-Shifting Point Diffraction Interferometer with Two Optical Fibers 总被引:1,自引:0,他引:1
Toshiaki Matsuura Satoru Okagaki Takaaki Nakamura Yasushi Oshikane Haruyuki Inoue Motohiro Nakano Toshihiko Kataoka 《Optical Review》2007,14(6):401-405
A phase-shifting point diffraction interferometer (PS/PDI) with point sources of two single mode optical fibers has been developed,
which will be appropriate for the surface figure measurement of large aperture optics on a sub-nanometer scale. To reduce
the measurement error factors, a fiber optic plate (FOP) is used as a projection plane for interference pattern. Errors caused
by imperfection of optical alignment, such as position of point sources and tilt of FOP, are minimized by analyzing the measured
phase data with an original method. Measurement accuracy in the PS/ PDI is estimated with the interference pattern produced
by the two optical fiber sources. If inhomogeneity of the FOP and a systematic error of the PS/PDI are eliminated, the measurement
accuracy of the present system is estimated to be less than 4nm P-V and 0.7nm rms, respectively, at a measurement wavelength
of 632.8 nm. 相似文献
142.
Yasushi Ishido Arihiro Kanazawa Shokyoku Kanaoka Sadahito Aoshima 《Journal of polymer science. Part A, Polymer chemistry》2013,51(21):4684-4693
Side group structures of aldehydes were demonstrated to have decisive effects on cationic copolymerizations with alkyl vinyl ether (VE). Alternating copolymerizations of isobutyl VE (IBVE) and plant‐derived aldehydes with acyclic side chains such as trans‐2,cis‐6‐nonadienal, trans‐2‐nonenal, and citral proceeded under appropriate reaction conditions with the EtSO3H/GaCl3 initiating system. In addition, some aldehydes copolymerized in a well‐controlled fashion to yield alternating copolymers with controlled molecular weights and narrow molecular weight distributions. Quantitative and selective acid hydrolysis of the resulting alternating copolymers, based on the acetal structures in the main chains, was also achieved to give other conjugated aldehydes as nearly sole degradation products. Copolymerization results of IBVE and various plant‐derived aldehydes with acyclic or cyclic side groups suggested that electron‐donating ability and bulkiness of the side groups were most likely responsible for the alternating and/or controlled copolymerization behaviors. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4684–4693 相似文献
143.
Yasushi Numata 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(6):1043-1049
Raman spectroscopy was used for rapid and in situ measurements of alcohols in alcohol-water binary systems. An external standard was used to eliminate factors such as laser power or instrumental effects. Band ratios between the Raman bands of the target molecule and that of acetonitrile as external standard were calculated and found to be proportional to the mass fraction of alcohol. Better linearity was achieved as compared with that in the calibration curve obtained by plotting the Raman intensity alone. The equations of the calibration curves were y=0.2747x with R2 of 0.9996 and y=0.2189x+1.340×10−3 with an R2 of 1.000 in methanol-water and in ethanol-water binary systems, with y and x denoting the Raman intensity ratio and the mass fraction of alcohol, respectively. 相似文献
144.
145.
John A. Ford Yasushi Narushima Hiroshi Yabe 《Computational Optimization and Applications》2008,40(2):191-216
Conjugate gradient methods are appealing for large scale nonlinear optimization problems, because they avoid the storage of
matrices. Recently, seeking fast convergence of these methods, Dai and Liao (Appl. Math. Optim. 43:87–101, 2001) proposed a conjugate gradient method based on the secant condition of quasi-Newton methods, and later Yabe and Takano (Comput.
Optim. Appl. 28:203–225, 2004) proposed another conjugate gradient method based on the modified secant condition. In this paper, we make use of a multi-step
secant condition given by Ford and Moghrabi (Optim. Methods Softw. 2:357–370, 1993; J. Comput. Appl. Math. 50:305–323, 1994) and propose two new conjugate gradient methods based on this condition. The methods are shown to be globally convergent
under certain assumptions. Numerical results are reported. 相似文献
146.
M. Okumura L. Tong Kaoru Fujinaga Yasushi Seike 《Analytical and bioanalytical chemistry》2001,370(1):104-107
A simple and rapid in situ preconcentration method for the determination of phosphate in environmental waters has been developed for field analysis. This method is based on solid-phase extraction on a zirconium-loaded Sep-Pack Accell CM cartridge (Zr-SP) and is applicable to studies in which sampling is performed by use of a graduated syringe to prevent contamination and to ensure easy operation at sampling sites. The Zr-SP cartridge was prepared by passing 0.1 mol L–1 zirconium solution through a Sep-Pak Accell CM cartridge, packed with cation exchange sorbent based on a silica matrix. The adsorption of phosphate and its desorption depend only on the pH of the solution. A water sample containing phosphate was adjusted to pH 2 and passed through the Zr-SP cartridge to collect it. The retained phosphate was quantitatively eluted with 0.5 mol L–1 sodium hydroxide solution. The phosphate retained in the Zr-SP cartridge was stable for at least one month. The established preconcentration method was successfully applied to brackish lake waters to investigate seasonal changes in the distribution and behavior of phosphate in a brackish lake. 相似文献
147.
148.
Atsushi Taguchi Shintaro Fujii Taro Ichimura Prabhat Verma Yasushi Inouye Satoshi Kawata 《Chemical physics letters》2008,462(1-3):92-95
We have found that the shape of silver nanocrystals is conveniently controlled by injection of oxygen gas during the polyol reduction of silver ions. The presence of oxygen effectively promotes the oxidative etching of multiple twined particles. Adjusting the flow rate of the oxygen gas yields uniformly-sized silver nanocubes, right bipyramids, nanowires, and spherical nanoparticles depending on the injection rate of the oxygen gas. Electron diffraction and high resolution TEM observations of the synthesized nanocrystals show our nanocrystals do consist of silver, not of silver oxide. SERS activities of the synthesized nanocrystals were also examined. 相似文献
149.
Takashi Fukasawa Takao Orii Masayo Tanaka Noriko Suzuki Yasushi Kanzaki 《Chemical & pharmaceutical bulletin》2008,56(8):1177-1180
There are many reports that the drug-induced taste disorder is ascribable to the chelate reaction of a drug with zinc ion and the following zinc deficiency. As a quantitative measure of the chelating ability of drugs with zinc ions, the chelating ability was estimated from the electrode potential change of the Zn2+/Zn(Hg) system during the addition of a drug. The electrode potential was measured in a water-N,N-dimethylformamide mixed solution and in an aqueous solution depending on the solubility of the drugs. The observed electrode potential change showed a positive correlation to the frequency of the drug-induced taste disorder that was supplied from the manufacturer of the original drug. The regression analysis was carried out assuming that the frequency of the taste disorder and the electrode potential change was linear. The F-values, p-values, and R2-values were 4.29, 0.13, 0.589, and 4.15, 0.13, 0.580, respectively. The positive correlation between the drug-induced taste disorder and the electrode potential change appeared evident if the uncertainty in the frequency of the taste disorder was taken into consideration. Thus the assumption of the zinc ion chelating mechanism on the drug-induced disorder was also evident except for cisplatin. The frequency of the drug-induced taste disorder of bezafibrate was estimated to be 0.4--0.5 from the regression analysis. 相似文献
150.
Koshi Imami Naoyuki Sugiyama Yutaka Kyono Masaru Tomita Yasushi Ishihama 《Analytical sciences》2008,24(1):161-166
We have developed an on-line automated system for phosphoproteome analysis using titania-based phosphopeptide enrichment followed by nanoLC-MS/MS. Titania beads were prepared by calcination of commercial chromatographic titania beads at 800 degrees C to convert the crystalline structure. The obtained rutile-form titania exhibited higher selectivity in phosphopeptide enrichment than commercial titania, even in the absence of a competitive chelating reagent for non-phosphopeptides. For phosphoproteome analysis of human cervical cancer HeLa cells, tryptic digests of the cell extracts were directly injected into this on-line system, and 696 non-redundant phosphopeptides with 671 unambiguously determined phosphorylation sites, derived from 512 phosphoproteins, were successfully identified. This is the first successful application of an on-line automated phosphoproteome analysis system to complex biological samples. 相似文献