全文获取类型
收费全文 | 1322篇 |
免费 | 45篇 |
国内免费 | 9篇 |
专业分类
化学 | 1064篇 |
晶体学 | 8篇 |
力学 | 16篇 |
数学 | 75篇 |
物理学 | 213篇 |
出版年
2022年 | 9篇 |
2021年 | 17篇 |
2020年 | 9篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 6篇 |
2016年 | 21篇 |
2015年 | 14篇 |
2014年 | 35篇 |
2013年 | 59篇 |
2012年 | 76篇 |
2011年 | 72篇 |
2010年 | 36篇 |
2009年 | 27篇 |
2008年 | 57篇 |
2007年 | 74篇 |
2006年 | 64篇 |
2005年 | 77篇 |
2004年 | 75篇 |
2003年 | 60篇 |
2002年 | 75篇 |
2001年 | 20篇 |
2000年 | 27篇 |
1999年 | 20篇 |
1998年 | 9篇 |
1997年 | 14篇 |
1996年 | 30篇 |
1995年 | 17篇 |
1994年 | 18篇 |
1993年 | 10篇 |
1992年 | 20篇 |
1991年 | 11篇 |
1990年 | 9篇 |
1989年 | 11篇 |
1988年 | 19篇 |
1987年 | 13篇 |
1986年 | 15篇 |
1985年 | 18篇 |
1984年 | 25篇 |
1983年 | 14篇 |
1982年 | 23篇 |
1981年 | 8篇 |
1980年 | 13篇 |
1979年 | 18篇 |
1978年 | 11篇 |
1977年 | 7篇 |
1976年 | 12篇 |
1975年 | 6篇 |
1974年 | 9篇 |
1967年 | 6篇 |
排序方式: 共有1376条查询结果,搜索用时 31 毫秒
101.
Ariaki Murata Ryota Akaike Tatsuya Kawahashi Ryo Tsuchiya Hiroyuki Takemoto Toshiyuki Ohnishi Yasushi Todoroki Nobuyuki Mase Mineyuki Yokoyama Kazuteru Takagi Peter Winterhalter Naoharu Watanabe 《Tetrahedron》2014
A flower-inducing compound, LDS1, was isolated from a free-floating aquatic plant, Lemna paucicostata. The chemical structure and the absolute stereochemistry of LDS1 were determined as (9R,13R,11E,15Z)-9,13-dihydroxy-10-oxooctadeca-11,15-dienoic acid for its most abundant diastereomer. LDS1 was enzymatically produced when the plant was exposed to drought stress, and induced flowering at a concentration of 10 nM. 相似文献
102.
The catalytic activities of the cationic synthetic flavin adduct 1 with various dendritic and non-dendritic 2,6-bis(acylamino)pyridines 2 were examined for the oxidation of organic sulfides with H2O2. The adduct of 5-ethyllumiflavinium perchlorate 1a with 2b–d bearing poly(benzyl ether) dendron units acts as an efficient organocatalyst for the oxidative transformation of sulfides to the corresponding sulfoxides under mild conditions. 相似文献
103.
104.
105.
106.
Quantitative Detection for Porphyromonas gingivalis in Tooth Pocket and Saliva by Portable Electrochemical DNA Sensor Linked with PCR
下载免费PDF全文
![点击此处可从《Electroanalysis》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Keiichiro Yamanaka Shinichi Sekine Takahiro Uenoyama Masahiro Wada Tomohiko Ikeuchi Masato Saito Yoshinori Yamaguchi Eiichi Tamiya 《Electroanalysis》2014,26(12):2686-2692
Here, a quantitative electrochemical analysis of periodontal bacteria in gingival crevicular fluid (GCF) and saliva by direct polymerase chain reaction (PCR) is presented. The electrochemical measurement was performed by mixing with PCR products and electrochemical indicator (bisbenzimidazole trihydrochloride). The peak current of indicator is reduced due to slower diffusion when the dye intercalates into the amplified DNA, and the degree of reduction in the peak current is correlates with the quantity of amplified DNA. Therefore, a quantitative analysis is possible by using our electrochemical method at the end point of PCR. In the GCF testing, The number of Porphyromonas gingivalis (Pg) detected by our electrochemical method at the end point of PCR were almost same compared with that were calculated by the conventional method of quantitative real? time PCR. In the saliva testing, the relationship between number of Pg in saliva and average pocket depth, and age‐dependence were also clearly observed. Since the saliva sample is obtained in a non‐invasive manner, this method is useful for the primary screening of periodontal disease. Moreover, our detection method is simple and uses a hand‐held potentiostat making it suitable for development of an on‐site periodontal diagnosis system. 相似文献
107.
Takayuki Suzuki Tomohiko Kitsukawa Yasushi Hirata Satomi Tanaka Naoya Iwasaki 《先进技术聚合物》2014,25(1):123-129
The copolymer of hydroxypropyl methacrylate (HPMA) and photochromic spiropyran methacrylate (SPMA) has been synthesized. The films of the copolymer (P(HPMA‐SPMA)) in a hydrated state showed reversible swelling–shrinking behavior in response to photoreversible isomerization and metal complexation of SPMA units in spite of covalently noncross‐linked copolymers. In addition, the protonated open form of the SPMA units of the copolymer was possibly stabilized thermodynamically by the HPMA units from ultraviolet–visible absorption measurement of the hydrated P(HPMA‐SPMA) film. On the other hand, the difference in color of the hydrated films between P(HPMA‐AABMA) and P(NIPMA‐AABMA), which was a copolymer of N‐isopropyl methacryl amide (NIPMA) and azobenzene methacrylate (AABMA) as a pH indicator, was suggestive of the interference of the proximal hydroxyl groups of the immobilized HPMA units with protonation of the AABMA units. The HPMA units of the copolymers also contributed to improvement of thermodynamic stability of the metal complexes with the SPMA units. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
108.
Ewelina Lipiec Dr. Ryo Sekine Dr. Jakub Bielecki Prof. Dr. Wojciech M. Kwiatek Assoc. Prof. Bayden R. Wood 《Angewandte Chemie (International ed. in English)》2014,53(1):169-172
DNA double strand breaks (DSBs) are deadly lesions that can lead to genetic defects and cell apoptosis. Techniques that directly detect DNA DSBs include scanning electron microscopy, atomic force microscopy (AFM), and fluorescence based approaches. While these techniques can be used to identify DSBs they provide no information on the molecular events occurring at the break. Tip‐enhanced Raman scattering (TERS) can provide molecular information from DNA at the nanoscale and in combination with AFM provides a new way to visualize and characterize the molecular structure of DSBs. DSBs result from cleavage at the 3’‐ and 5’‐bonds of deoxyribose upon exposure to UVC radiation based on the observation of P? O? H and methyl/methylene deformation modes enhanced in the TERS spectra. It is hypothesized that strand fragments are hydrogen‐terminated at the lesion, indicating the action of free radicals during photon exposure. 相似文献
109.
Dr. Masayuki Iwasaki Miki Iyanaga Yuta Tsuchiya Yugo Nishimura Wenjuan Li Prof. Dr. Zhiping Li Prof. Dr. Yasushi Nishihara 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(9):2459-2462
A catalytic variant of the direct thiolation of arenes, bearing directing groups, with disulfides or thiols has been developed under palladium and copper co‐catalysis. Both sulfenyl moieties of the disulfide could be incorporated into the thiolated products, therefore, the reactions reached completion with only half an equivalent of disulfide, with respect to the starting arene. Experimental evidence suggested that the reaction proceeds through a PdII/PdIV mechanism. 相似文献
110.
Jun Terao Yasushi Tsuji 《Journal of inclusion phenomena and macrocyclic chemistry》2014,80(3-4):165-175
A new method for the synthesis of an insulated π-conjugated molecule was developed via the sequential self-inclusion of π-conjugated guest branched permethylated α-cyclodextrin followed by the elongation of the π-conjugated unit. Covering a single π-conjugated wire by an α-cyclodextrin derivatives can suppress conductance fluctuation. The insulated π-conjugated molecules were utilized in the synthesis of highly conductive zigzag- and functionalized-insulated molecular wires. 相似文献