全文获取类型
收费全文 | 1169篇 |
免费 | 13篇 |
国内免费 | 13篇 |
专业分类
化学 | 863篇 |
晶体学 | 16篇 |
力学 | 11篇 |
数学 | 74篇 |
物理学 | 231篇 |
出版年
2022年 | 4篇 |
2021年 | 5篇 |
2019年 | 13篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 15篇 |
2015年 | 14篇 |
2014年 | 17篇 |
2013年 | 81篇 |
2012年 | 41篇 |
2011年 | 50篇 |
2010年 | 36篇 |
2009年 | 34篇 |
2008年 | 61篇 |
2007年 | 68篇 |
2006年 | 64篇 |
2005年 | 57篇 |
2004年 | 48篇 |
2003年 | 56篇 |
2002年 | 59篇 |
2001年 | 18篇 |
2000年 | 28篇 |
1999年 | 11篇 |
1998年 | 21篇 |
1997年 | 16篇 |
1996年 | 18篇 |
1995年 | 15篇 |
1994年 | 21篇 |
1993年 | 13篇 |
1992年 | 19篇 |
1991年 | 8篇 |
1990年 | 13篇 |
1989年 | 8篇 |
1988年 | 19篇 |
1987年 | 5篇 |
1986年 | 10篇 |
1985年 | 14篇 |
1984年 | 15篇 |
1983年 | 17篇 |
1982年 | 22篇 |
1981年 | 21篇 |
1980年 | 7篇 |
1979年 | 21篇 |
1978年 | 11篇 |
1977年 | 19篇 |
1976年 | 12篇 |
1975年 | 16篇 |
1974年 | 18篇 |
1973年 | 9篇 |
1972年 | 5篇 |
排序方式: 共有1195条查询结果,搜索用时 15 毫秒
91.
Spirodienones bearing the 1-azaspiro[4.5]decane ring system have been synthesized from N-methoxy-(4-halogenophenyl)amides by the intramolecular ipso attack of a nitrenium ion generated with [hydroxy(tosyloxy)iodo]benzene in trifluoroethanol. 相似文献
92.
Yasuo Kokubun 《光学学报》2003,23(Z1)
In this review, the recent progress in the development of vertically coupled micro-ring resonator filters is summarized and the potential applications of the filters leading to the development of VLSI photonics are described. 相似文献
93.
Powell AB Suzuki Y Ueda M Bielawski CW Cowley AH 《Journal of the American Chemical Society》2011,133(14):5218-5220
We report the synthesis and catalytic activity of a polymeric imidazolium salt. In contrast to the well-known resin-supported N-heterocyclic carbenes (NHCs), the material described herein affords a polymer with NHCs orthogonally positioned along a main chain upon generation in situ. The unique structural characteristics of the corresponding poly(NHC)s enabled the materials to display catalytic activities that were similar or superior to those displayed by monomeric analogues. Moreover, the new catalyst was successfully recovered and reused with minimal loss of performance over several cycles. 相似文献
94.
Masami Sawada Yasuo Okumura Hitoshi Yamada Yoshio Takai Shigetoshi Takahashi Takahiro Kaneda Keiji Hirose Soichi Misumi 《Journal of mass spectrometry : JMS》1993,28(12):1525-1528
Using fast atom bombardment (FAB) mass spectrometry (MS), cross-chiral relationships were confirmed for the first time for the diasteromeric host-guest complexations between the chiral crown ether host (1) and the chiral organic ammonium ion guest (2) on the basis of the relative peak intensities (RPI). Both host–guest combinations (R, R, R, R) – 1, (R) – 2 and (S, S, S, S) – 1, (S) – 2 obviously provided larger RPI values than the combination of both (R, R, R, R) – 1, (S) – 2 and (S, S, S, S) – 1, (R) – 2 by a factor of 1.6 as an averaged value: 1.87 (n = 4)/1.16 (n = 4) = 1.6. These results are consistent with the expected stabilities of the host-guest complexations by CPK model examinations. Successfully observed cross-chiral examinations strongly suggest a potentially useful FABMS/RPI methodology for rapidly searching newly designed and synthesized crown ether-like host compounds with a higher degree of enantioselectivity. 相似文献
95.
Dr. Tatsuki Kurokawa Dr. Shigeki Kiyonaka Dr. Eiji Nakata Dr. Masayuki Endo Shohei Koyama Emiko Mori Nam Ha Tran Huyen Dinh Dr. Yuki Suzuki Kumi Hidaka Dr. Masaaki Kawata Dr. Chikara Sato Prof. Hiroshi Sugiyama Prof. Takashi Morii Prof. Yasuo Mori 《Angewandte Chemie (International ed. in English)》2018,57(10):2586-2591
In native systems, scaffolding proteins play important roles in assembling proteins into complexes to transduce signals. This concept is yet to be applied to the assembly of functional transmembrane protein complexes in artificial systems. To address this issue, DNA origami has the potential to serve as scaffolds that arrange proteins at specific positions in complexes. Herein, we report that Kir3 K+ channel proteins are assembled through zinc‐finger protein (ZFP)‐adaptors at specific locations on DNA origami scaffolds. Specific binding of the ZFP‐fused Kir3 channels and ZFP‐based adaptors on DNA origami were confirmed by atomic force microscopy and gel electrophoresis. Furthermore, the DNA origami with ZFP binding sites nearly tripled the K+ channel current activity elicited by heterotetrameric Kir3 channels in HEK293T cells. Thus, our method provides a useful template to control the oligomerization states of membrane protein complexes in vitro and in living cells. 相似文献
96.
We report a Rietveld refinement analysis and X-ray absorption study on a green-color Cl(-)-intercalated alpha-type cobalt hydroxide phase. The refinement clearly demonstrated that one-fifth to one-sixth of the Co(II) at octahedral sites was replaced by pairs of tetrahedrally coordinated Co(II) on each side of the hydroxide plane, represented by a structural formula of [Co(octa)(0.828)Co(tetra)(0.348)(OH)2](0.348+)Cl(0.348).0.456H2O. X-ray absorption spectroscopy also indicated that the divalent cobalt were in local neighboring environments of both octahedral and tetrahedral coordination. Furthermore, UV-vis spectroscopic measurements elucidate the typical green/blue color of an alpha-type cobalt hydroxide. 相似文献
97.
98.
99.
Experiments have been conducted to investigate an effect of inlet restriction on the thermal-hydraulic stability. A Test
facility used in this study was designed and constructed to have non-dimensional values that are nearly equal to those of
natural circulation BWR. Experimental results showed that driving force of the natural circulation at the stability boundary
was described as a function of heat flux and inlet subcooling independent of inlet restriction. In order to extend experimental
database regarding thermal-hydraulic stability to different inlet restriction, numerical analysis was carried out based on
the homogeneous flow model. Stability maps in reference to the core inlet subcooling and heat flux were presented for various
inlet restrictions using the above-mentioned function. Instability region during the inlet subcooling shifted to the higher
inlet subcooling with increasing inlet restriction and became larger with increasing heat flux.
Received on 17 January 2000 相似文献
100.
Yasuo Iida 《Fresenius' Journal of Analytical Chemistry》1987,328(7):547-552
Summary A new multiwavelength data-analysis method for the determination of multicomponent mixtures, the repetitive spectral subtraction method (RSSM), is proposed. In RSSM, spectral data are obtained at evenly spaced wavelengths in the range of interest, and the analysis of the spectrum is performed as repetitive determination-subtraction cycle. In the determination step, the series of data in the narrow wavelength range is used, which is specified as to include the most characteristic or the largest peak for each component. Assuming a linear background, the target component, which can be a small group of components, is simultaneously determined together with co-existing components. In the next subtraction step, the calculated contribution of the component is subtracted from the spectral data in the whole measured wavelength range, and the component is assigned as determined and is excluded from the following analysis. This determination-subtraction cycle is repeated until all the components are determined.With RSSM, a mixture of many components can be precisely determined by the use of most information contained in the spectrum. The accuracy of determination can be improved by automatic estimation of the background and the gradual decrease of interferences. In order to demonstrate the usefulness of RSSM, the 8 rare earth elements (Pr, Nd, Sm, Eu, Dy, Ho, Er, Tm) in the model mixtures were determined by spectrophotometry, and the results were compared with those of the usual correction factor method and the derivative method. Furthermore, the 8 rare earth elements were determined in ores, monazite and xenotime.
Spektralphotometrische Bestimmung von Seltenen Erden mit Hilfe eines Verfahrens der wiederholten Subtraktion相似文献