Velocity field after wave breaking

The velocity field in breaking water waves is considered in this paper. A numerical simulation describes in detail the transition from a primary overturning and consequent rebounding jets into a bore front, where the vorticity in the coherent large‐scale eddy structures devolves into turbulence. Spatial changes in the frequency spectra of the kinetic energy and the enstrophy are associated with the production, transport and dissipation of the Reynolds stress and the various wave and turbulent mixing length scales. Mean velocity fields and the wave and kinetic energy in a surf zone are evaluated. Fourier and wavelet spectral analysis is applied to study both the surface elevation and energy changes, and the distinction that must be made between spilling and plunging breakers is clarified in this paper. Copyright © 2002 John Wiley & Sons, Ltd.     

Temporal variation of electron density in a laser-perturbed discharge plasma and its relationship to the optogalvanic signal

By the method of microwave cavity resonance the authors have measured the temporal variation of the lctron density following the laser excitation of neon glow-discharge plasma, and the result is compared with the optogalvanic signal. It is found that the optogalvanic signal does not represent the change in the electron density; i.e., the time resolution is poor and the absolute magnitude is smaller by an order.     

Observation of methoxy species on the Si(111)(7 × 7) surface — A vibrational study

Chemisorption of methanol on the Si(111)(7 × 7) surface has been studied at ～ 300 K using high-resolution electron energy loss spectroscopy. Methanol reacts with the Si(111) surface to form the stable surface species SiOCH₃ and SiH. The methoxy species (CH₃O) is bonded to the Si surface with a covalent bond formed between its oxygen end and the dangling bond of the Si(111) surface atom. A structural model for methanol chemisorbed on the Si(111) surface is proposed.     

Iodobenzene-catalyzed alpha-acetoxylation of ketones. in situ generation of hypervalent (diacyloxyiodo)benzenes using m-chloroperbenzoic acid

Reported here for the first time is the iodobenzene-catalyzed alpha-oxidation of ketones, in which diacyloxy(phenyl)-lambda3-iodanes generated in situ act as real oxidants of ketones and m-chloroperbenzoic acid serves as a terminal oxidant. Oxidation of a ketone with m-chloroperbenzoic acid in acetic acid in the presence of a catalytic amount of iodobenzene, BF3.Et2O, and water at room temperature under argon affords an alpha-acetoxy ketone in good yield. p-Methyl- and p-chloroiodobenzene also serve as efficient catalysts in this direct oxidation. We found that when the reaction was carried out in the absence of a catalytic amount of iodobenzene, Baeyer-Villiger oxidation of a ketone took place. It is noted that use of water and BF3.Et2O is crucial to the success of this alpha-acetoxylation.     

Addition to electron deficient olefins of alpha-oxy carbon- centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- lambda(3)-iodane

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.     

BRS Transformation and color confinement

The condition of confinement of quarks and gluons in QCD is derived. It is shown that color confinement is realized when there exist massless scalar color-octet bound states of two Faddeev-Popov ghosts.     

The power of the likelihood ratio test for additional information in a multivariate linear model

Summary This paper deals with the likelihood ratio test for additional information in a multivariate linear model. It is shown that the power of the likelihood ratio test procedure has a monotonicity property. Asymptotic approximations for the power are also obtained.     

Circumventing air bubbles in microfluidic systems and quantitative continuous-flow PCR applications

Polymerase chain reaction (PCR) is an essential part of research based on genomics or cell analysis. The development of a microfluidic device that would be suitable for high-temperature-based reactions therefore becomes an important contribution towards the integration of micro-total analysis systems (μTAS). However, problems associated with the generation of air bubbles in the microchannels before the introduction of the assay liquid, which we call the “initial start-up” in this study, made the flow irregular and unstable. In this report, we have tried to address these problems by adapting a novel liquid-flow method for high-temperature-based reactions. A PDMS-based microfluidic device was fabricated by soft-lithography techniques and placed on a cartridge heater. The generation of the air bubbles was prevented by introducing the fluorinated oil, an inert and highly viscous liquid, as the cap just before the introduction of the sample solutions into the microchannels. The technique was applied for continuous-flow PCR, which could perform PCR on-chip in a microfluidic system. For the evaluation of practical accuracy, plasmid DNA that serves as a reference molecule for the quantification of genetically modified (GM) maize was used as the template DNA for continuous-flow PCR. After PCR, the products were collected in a vial and analyzed by gel electrophoresis to confirm the accuracy of the results. Additionally, quantitative continuous-flow PCR was performed using TaqMan technology on our PCR device. A laser detection system was also used for the quantitative PCR method. We observed a linear relationship between the threshold cycle (Ct) and the initial DNA concentration. These results showed that it would be possible to quantify the initial copies of the template DNA on our microfluidic device. Accurate quantitative DNA analysis in microfluidic systems is required for the integration of PCR with μTAS, thus we anticipate that our device would have promising potential for applications in a wide range of research.