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991.
992.
993.
Excess thermal expansion factor of non-polar mixtures is the order of 10–6 K–1 and within an experimental error. On the other hand, those of polar mixtures and aqueous solutions are very large and the order of 10–5 K–1, up to the order of 10–4 K–1 in an extreme case. The excess thermal expansion factors express well the excesses of entropy volume cross fluctuation and enthalpy volume cross fluctuation estimated from thermal expansion factor and molar volume. Those of aqueous solutions are, however, reduced by small molar volume of water.This revised version was published online in November 2005 with corrections to the Cover Date.  相似文献   
994.
A molecular-level, quantum-dynamical analysis of phonon-driven exciton dissociation in semiconducting polymers is presented, using a linear vibronic coupling model in conjunction with a recently developed hierarchical chain representation. Quantum-dynamical simulations in 20-30 dimensions are carried out using efficient multiconfigurational techniques. The decay of the exciton towards a charge-separated state is shown to be an ultrafast, coherent process of pronounced non-equilibrium character, which cannot be modeled by conventional kinetic equations. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
995.
Anomalous delay of phonons reflected from the surface of a superlattice   总被引:2,自引:0,他引:2  
We study theoretically the propagation of acoustic phonons in a superlattice (SL) with a free surface. A phonon incident normally on the SL from a substrate is perfectly reflected, but it comes back to the substrate either with a time delay or with a time advance. Specifically the time delay is enhanced considerably if the frequency of the incident phonon coincides with an eigenfrequency of the vibrational modes localized at the surface of the SL. This suggests the observability of the surface vibrational modes by a time-resolved phonon reflection experiment.  相似文献   
996.
PURPOSE: To acquire high-resolution magnetic resonance (MR) images, we developed a new blinking artifact reduced pulse (BARP) sequence with a surface coil specialized for microscopic imaging (47 mm in diameter). MATERIALS AND METHODS: To reduce eye movement, we ascertained that the subjects' eyes were kept open and fixated to the target in the 1.5-T MR gantry. To reduce motion artifacts from blinking, we inserted rest periods for blinking (1.5 s within every 5 s) during MR scanning (T2-weighted fast spin echo; repetition time, 5 s; echo time, 100 ms; echo train, 11; matrix, 256 x 128; field of view, 5 cm; 1-mm thickness x 30 slices). Three scans (100 s x 3) were performed for each normal subject, and they were added together after automatic adjustment for location to reduce quality loss caused by head motion. RESULTS: T2-weighted MR images were acquired with a high resolution and a high signal-to-noise ratio. Motion artifacts were reduced with BARP, as compared with those with random blinking. Intraocular structures such as the iris and ciliary muscles were clearly visualized. Because the whole eye can be covered with a 1-mm thickness by this method, three-dimensional maps can easily be generated from the obtained images. CONCLUSION: The application of BARP with a surface coil of the human eye might become a useful and widely adopted procedure for MR microimaging.  相似文献   
997.
We report on the first observation of hypernuclear γ transitions using germanium detectors. Using a large-acceptance Ge detector system, we observed two γ transitions in Λ7Li, the spin-flip transition at 689±4keV and the transition at 2050±2 keV (preliminary). The strength of the ΛN spin-spin interaction is derived from the energy of the former transition. As for the latter transition, B(E2) was measured to be 3.9±0.6±0.4 e2fm4 (preliminary), which indicates a shrinkage of the nuclear size of Λ7Li from 6Li and confirms “glue-like role” of Λ.  相似文献   
998.
Vector potentials are known to have a direct significance to quantum particles moving in the magnetic field. This is called the Aharonov–Bohm effect and is known as one of the most remarkable quantum phenomena. Here we study this quantum effect through the resonance problem. We consider the scattering system consisting of two scalar potentials and one magnetic field with supports at large separation in two dimensions. The system has trajectories oscillating between these supports. We give a sharp lower bound on the resonance widths as the distances between the three supports go to infinity. The bound is described in terms of the backward amplitude for scattering by each of the scalar potentials and by the magnetic field, and it also depends heavily on the magnetic flux of the field.  相似文献   
999.
The physical posture of even healthy university students is easy to collapse when walking with textbooks and other heavy loads during university attendance. Consequently, they may experience lower-back pain or knee pain. However, the resulting burden of this stress to the left and right lower-back has not previously been quantitatively analyzed.In this study, we employed a Relative Power Contribution (RPC) analysis approach to quantitatively investigate and compare the reciprocal contribution between the left and right lower-backs while walking with a bag and without a bag. Quantitative data were collected by two accelerometers installed on the subjects.Results for the subjects walking with and without a bag indicated that the contribution of the left and right lower-backs decreased by up to 21% (p<0.05). Some disorder occurs in the feedback relations of the movement in both lower-backs and as a result, it was understood to cause much discomfort in these areas.This analysis reveals the quantitative relations of left and right lower-backs, which are difficult to discern from the original data. The results can be useful for preventive healthcare for lower-back and knee pains.  相似文献   
1000.
We propose a conclusive difference observed between the excitation conditions required to observe porphyrins and copper-metallothioneins in cells and/or tissues using an ordinary fluorescence microscope. We have emphasized the importance of examining the spectral properties of the emissions to avoid any serious mistakes such as confusing porphyrins with copper-metallothioneins in the liver and kidneys. However, microspectrophotometry is not a conventional method for either histochemical, cytochemical, or pathological studies because microspectrophotometers are both expensive and difficult to operate. Therefore, we demonstrate a simple comparative method using ordinary excitation filter arrangements. When using our technique, it becomes possible to optically discriminate more accurately between the autofluorescence properties arising from porphyrins and those arising from copper-metallothioneins. We would like to name our simple technique “Triple Observation Method (TOM)”.  相似文献   
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