全文获取类型
收费全文 | 1134篇 |
免费 | 22篇 |
国内免费 | 1篇 |
专业分类
化学 | 763篇 |
晶体学 | 12篇 |
力学 | 12篇 |
数学 | 67篇 |
物理学 | 303篇 |
出版年
2019年 | 12篇 |
2018年 | 11篇 |
2016年 | 10篇 |
2015年 | 15篇 |
2014年 | 19篇 |
2013年 | 46篇 |
2012年 | 39篇 |
2011年 | 41篇 |
2010年 | 28篇 |
2009年 | 27篇 |
2008年 | 43篇 |
2007年 | 40篇 |
2006年 | 41篇 |
2005年 | 51篇 |
2004年 | 38篇 |
2003年 | 37篇 |
2002年 | 42篇 |
2001年 | 21篇 |
2000年 | 19篇 |
1999年 | 20篇 |
1998年 | 17篇 |
1997年 | 14篇 |
1996年 | 17篇 |
1995年 | 15篇 |
1994年 | 20篇 |
1993年 | 16篇 |
1992年 | 27篇 |
1991年 | 14篇 |
1990年 | 11篇 |
1989年 | 15篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 18篇 |
1985年 | 14篇 |
1984年 | 25篇 |
1983年 | 16篇 |
1982年 | 18篇 |
1981年 | 19篇 |
1980年 | 15篇 |
1979年 | 21篇 |
1978年 | 8篇 |
1977年 | 18篇 |
1976年 | 18篇 |
1975年 | 23篇 |
1974年 | 21篇 |
1973年 | 17篇 |
1972年 | 18篇 |
1971年 | 10篇 |
1966年 | 9篇 |
1965年 | 12篇 |
排序方式: 共有1157条查询结果,搜索用时 15 毫秒
91.
Summary The chromatographic efficiency and stability of a new octadecyl-bonded polymer (ODP) gel, developed for reversed phase liquid
chromatography (RPLC) by substitution of stearate ester groups for the hydroxyl groups of vinyl alcohol copolymer particles,
were investigated and compared with those of conventional gels. The efficiency of the column packed with the ODP gel was practically
unaffected by repeated alternating passages of distilled water and acetonitrile, apparently because the gel volume was affected
similarly by both solvents. Like conventional ODS columns, the ODP column demonstrated a close correlation between log k’
(capacity factor) and carbon atom number in alkyl alcohols in accordance with Martin’s rule and H ∼ 4 dp, thus indicating
a high column efficiency for these alcohols. The capacity factor of the ODP column for pyridine with acidic eluent was smaller
than that of ODS columns, and the pyridine peak was sharp and symmetrical. 相似文献
92.
93.
94.
Koichi Ishibashi Hirohito Tsue Hiroki Takahashi Rui Tamura 《Tetrahedron: Asymmetry》2009,20(3):375-380
The first inherently chiral azacalix[4]arene has been prepared by introducing three benzyl groups onto the nitrogen bridges. The highly enantioenriched compound was easily obtained via a moderately enantioselective cyclization followed by a simple crystallization procedure. NMR and X-ray crystallographic studies revealed that easy access to the enantiomer was permitted by the non-racemizable 1,3-alternate conformation in solution, up to 110 °C, as well as by the preferential crystallization of a racemic compound. 相似文献
95.
T. Matsushima N. Nakajima M. Tamura T. Sueta 《International Journal of Infrared and Millimeter Waves》1986,7(10):1585-1589
A method of expanding the tuning range of the CW CO2 waveguide laser making use of a Fabry-Perot type light modulator is proposed. A preliminary experiment has been done to confirm the workability of the proposed scheme. 相似文献
96.
Yutaka Nishigaichi Ken-ichi Tamura Narifumi Ueda Hidetoshi Iwamoto Akio Takuwa 《Tetrahedron letters》2008,49(13):2124-2127
Using a single allyltin reagent with a chiral nitrogen functionality, binary and remote asymmetric induction was realized toward various aldehydes. Either syn- or anti-1,4-amino-alcohols were selectively obtained with the use of Yb(OTf)3 or SnCl4, respectively. The structures of both diastereomers were identified by means of X-ray analysis. 相似文献
97.
Satoru Tamura 《Tetrahedron letters》2010,51(11):1523-5786
Falcarindiol (1) was isolated as an algicidal principle against the harmful red tide dinoflagellate, Heterocapsa circularisquama, from Notopterygii Rhizoma through bioassay-guided separation. In order to determine the ambiguous absolute structure of this active principle, all three stereoisomers as well as falcarindiol (1) were synthesized. As a result of intensive analysis of their physicochemical properties, the configuration of 1 was revealed to be 3R,8S. On the other hand, (3S,8S)- and (3S,8R)-isomers were found to exhibit more potent algicidal activity than (3R,8S)-falcarindiol (1) isolated from Notopterygii Rhizoma. In addition, the diyne moiety of 1 was established as the crucial structural requirement for algicidal potency. 相似文献
98.
Tavrov A Korablev O Ksanfomaliti L Rodin A Frolov P Nishikwa J Tamura M Kurokawa T Takeda M 《Optics letters》2011,36(11):1972-1974
To suppress starlight for direct exoplanet observation, we propose a common-path achromatic rotational-shearing coronagraph (CP-ARC), which is an interferocoronagraph with an angular-adjustable field rotator. The CP-ARC aims to maintain unwanted detection of stellar light, which can be suppressed incompletely by interference because of the finite diameter of the star. Compared to the previous interferocoronagraph, which had a nonadjustable 180° field rotation, the proposed CP-ARC can improve the coronagraphic contrast by several orders if the CP-ARC is combined with medium or large telescopes where the companion-star separation is optically resolved by more than a few Airy radii. The CP-ARC is made robust against mechanical disturbances due to the common-path interferometer principle. 相似文献
99.
[structure: see text] The synthesis of (-)-aphanorphine was achieved by using Bu(3)SnH-mediated aryl radical cyclization of 1-benzyloxycarbonyl-2-(2-bromo-4-methoxyphenylmethyl)-2-methoxycarbonyl-4-(phenylthiomethylene)pyrrolidine, leading to exclusive formation of the 6-exo cyclization product. 相似文献
100.
Observation of insulating–insulating monoclinic structural transition in macro‐sized VO2 single crystals [Phys. Status Solidi RRL 5, No. 3, R107–R109 (2011)]
下载免费PDF全文
![点击此处可从《固体物理学:研究快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Bongjin Simon Mun Kai Chen Youngchul Leem Catherine Dejoie Nobumichi Tamura Martin Kunz Zhi Liu Michael E. Grass Changwoo Park Joonseok Yoon Y. Yvette Lee Honglyoul Ju 《固体物理学:研究快报》2015,9(3):206-206
In our article, we reported the observation of monoclinic M2 to M1 structural phase transition in VO2 single crystal near the temperature of ~49 °C. However, the re‐examination of Laue patterns reveals that previously defined monoclinic M1 and M2 phases can be interpreted as monoclinic M2 and triclinic T phases instead. Careful experimental geometry calibration and further refinement of the lattice parameter ratios and angles show that monoclinic M2 and triclinic T phases fit better with the experimental data. On the other hand, our previous misidentification of the insulating phases does NOT affect the conclusions of our article. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献