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31.
The extraction behaviour of twelve metals as function of the concentration of nitric or hydrochloric acid is described; bis(2-ethylhexyl)phosphoric acid (BEHPA) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester are used as the extractants with 3:1 (w/w) biphenyl/ naphthalene (m.p. 52°C) as the molten solvent which is easily separated by cooling to room temperature. Scandium (III) and zirconium (IV) can be separated from uranium (VI), rare earth metals and some transition metals with BEHPA. The extraction behaviour of iron with both extractants is described in detail. 相似文献
32.
Tai-Ichi Shibuya Yasumasa J. I'haya Vincent McKoy 《International journal of quantum chemistry》1975,9(3):505-516
Dynamical screening in π-electron systems is studied by the equations of motion method. By using a partitioning technique on the equations of motion we can obtain simple expressions for the effect of dynamical screening directly on the transition energies and transition moments in π-electron systems. These results are used to study the effect of such screening in the N → V transition in ethylene. This procedure can be used to extend the equations-of-motion method to larger π-electron systems. 相似文献
33.
Bond angles of several free radicals have been estimated using the point charge model together with ESR data and compared with those derived by Coulson's equation and the INDO method. The model is found to work well in predicting bond angles for most radicals just like the INDO method. Some relationships between the model and the INDO method are discussed. 相似文献
34.
L-Daunosamine, the carbohydrate component of a group of important anticancer anthracycline antibiotics, has been efficiently prepared from L-lactic acid in a completely stereoselective manner through direct C-acylation using diphenyl phosphorazidate (DPPA). 相似文献
35.
The cyclic peptide proposed for the structure of the powerful cell growth inhibitory dolastatin 3, its diastereomers, and their isomers on the reverse order have been synthesized by the use of diphenyl phosphorazidate(DPPA) and diethyl phosphorocyanidate(DEPC). Their physicochemical and biological properties have shown that the proposed structure is untenable. 相似文献
36.
37.
Aoto T Ito K Hikosaka Y Shibasaki A Hirayama R Yamamono N Miyoshi E 《The Journal of chemical physics》2006,124(23):234306
The N2(+) states lying in the ionization region of 26-45 eV and the dissociation dynamics are investigated by high-resolution threshold photoelectron spectroscopy and threshold photoelectron-photoion coincidence spectroscopy. The threshold photoelectron spectrum exhibits several broad bands as well as sharp peaks. The band features are assigned to the N2(+) states associated with the removal of an inner-valence electron, by a comparison with a configuration interaction calculation. In contrast, most of the sharp peaks on the threshold photoelectron spectrum are allocated to ionic Rydberg states converging to N2(2+). Dissociation products formed from the inner-valence N2(+) states are determined by threshold photoelectron-photoion coincidence spectroscopy. The dissociation dynamics of the inner-valence ionic states is discussed with reference to the potential energy curves calculated. 相似文献
38.
Yasumasa Matsumoto 《Tetrahedron letters》2010,51(2):404-12975
Chiral C2-symmetric N-heterocyclic carbenes (NHCs) were tested for their stereocontrolling abilities in gold(I)-catalyzed asymmetric cyclization of 1,6-enynes giving the corresponding cyclopentane derivatives with moderate enantioselectivity of up to 59%. 相似文献
39.
The enantiomers of (11Z,19Z)-3-acetoxy-11,19-octacosadien-1-ol were synthesized from the enantiomers of 3,4-epoxy-1-butanol PMB ether. Its racemate was also synthesized. Its (S)-isomer and racemate were shown to possess the same pheromone activity as CH503, a long-lived inhibitor of male courtship in Drosophila melanogaster, although the racemate was less active. 相似文献
40.
A new geometrical criterion for the transition to spatio-temporal chaos (STC) arising in the Gray–Scott model is presented. This is based on the inter-relationship of global bifurcating branches of ordered patterns with respect to supply and removal rates contained in the model. This viewpoint not only gives us a new criterion for the onset of STC but also clarifies how the orbit itinerates among several ordered patterns in infinite-dimensional space. Moreover, the geometrical characterization gives us a universal viewpoint about the onset and termination of STC. There are at least two different mechanisms that cause re-injection dynamics and drive the STC: one is a generalized heteroclinic cycle consisting of self-replication and self-destruction processes, and the other involves annihilation of colliding waves instead of self-destruction. 相似文献