全文获取类型
收费全文 | 285篇 |
免费 | 2篇 |
专业分类
化学 | 186篇 |
晶体学 | 7篇 |
力学 | 2篇 |
数学 | 5篇 |
物理学 | 87篇 |
出版年
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2018年 | 3篇 |
2016年 | 4篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 14篇 |
2012年 | 13篇 |
2011年 | 22篇 |
2010年 | 14篇 |
2009年 | 4篇 |
2008年 | 23篇 |
2007年 | 17篇 |
2006年 | 24篇 |
2005年 | 12篇 |
2004年 | 15篇 |
2003年 | 4篇 |
2002年 | 12篇 |
2001年 | 5篇 |
2000年 | 8篇 |
1999年 | 5篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 7篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有287条查询结果,搜索用时 15 毫秒
171.
Yoshihiro Yamauchi Takanori Okamoto Hiroshi Murayama Akira Nagara Tadashi Kashihara Masasi Yoshida Tetsuji Yasui Koichi Nakanishi 《Applied biochemistry and biotechnology》1995,53(3):245-259
A multistage bioreactor system for rapid beer fermentation was developed. The main fermentation process, which conventionally
requires 7 d, could be shortened to 2 d by this system. The concentration of esters and higher alcohols are major factors
in brewery fermentation, their production being closely related to the yeast growth phase. Yeast metabolism was successfully
subdivided into a growth and a restricted phase through a combination of a continuous stirredtank reactor (CSTR) and an immobilized
yeast packed-bed reactor (PBR). Production of higher alcohols was high in the CSTR because of its association with the level
of biosynthetic activityde novo. A small amount was also produced in the PBR, however, possibly a result of an overflow in carbohydrate metabolism. Ester
formation mainly occurred in the PBR, a linear increase in the level of ester being observed with flow through the PBR. The
reactor system control strategy was to maximize the level of both higher alcohol and ester formation. The CSTR/PBR control
range, based on extract consumption, was varied between 1:1 and 1:2. A ratio of 1:1 tended to create a flat beer, whereas
a ratio 1:2 gave a beer of richer quality. Amino acid uptake by the yeast directly contributed to a reduction in the wort
pH, whereas no relation could be observed between the level of organic acid production and pH. 相似文献
172.
Hidetsura Cho Yoshio NishimuraYoshizumi Yasui Masahiko Yamaguchi 《Tetrahedron letters》2012,53(9):1177-1179
Construction of a dihydropyrimidine ring was developed that involved the cyclization of 1,3-diaza-1,3-butadienes having an N-protecting group (N-Cbz, N-Boc, N-alkyl, or N-benzyl) with α,β-unsaturated carbonyl compounds such as ethyl acrylate and p-chlorophenyl vinyl ketone. Consequently, 4-dimethylamino-2-phenyl-1,4,5,6-tetrahydropyrimidines were synthesized in good yields. Subsequently, the β-elimination of the dimethylamino group was carried out with MeI or SiO2 to afford various N-protecting-2,5-disubstituted-1,6-dihydropyrimidines in good yields. Remarkably, the use of 4-chlorophenyl vinyl ketone directly provided the dihydropyrimidine without the tetrahydropyrimidine intermediate in excellent yield. 相似文献
173.
Yukinori Yasui Yuki Kitazumi Hiroyuki Mizunuma Naoya Nishi Takashi Kakiuchi 《Electrochemistry communications》2010,12(11):1479-1482
The ultraslow relaxation, on the order of a few seconds or longer, of the structure of the electrical double layer in response to the change in the phase-boundary potential across the ionic liquid (IL)|water(W) interface, which was recently reported for trioctylmethylammonium bis(nonafluorobutanesulfonyl)amide, has been confirmed in two new hydrophobic ionic liquids, trihexyltetradecylphosphonium bis(nonafluorobutanesulfonyl)amide and trihexyltetradecylphosphonium tetrakis(pentafluorophenyl)borate. A comparison of the degree of the hysteresis in electrocapillary curves for these ILs with those for trioctylmethylammonium bis(nonafluorobutanesulfonyl)amide demonstrates that the degree of the hysteresis is not correlated with the viscosity of these ILs. The ultraslow relaxation of the electrical double layer seems to be a general feature of ILs at electrified interfaces. 相似文献
174.
175.
Manickam Sivakumar Atsuya Towata Kyuichi Yasui Toru Tuziuti Teruyuki Kozuka Masahiko Tsujimoto Ziyi Zhong Yasuo Iida 《Ultrasonics sonochemistry》2010,17(1):213-218
Fine particles of rutile TiO2 supporting nanosized particles of Pt were prepared by a simultaneous in situ sonochemical reduction and deposition method using a standing wave sonochemical reactor (SWSR). The mean diameter of sonochemically obtained Pt particles are of 2 nm. Following this sonochemical technique, rutile TiO2 was also deposited with different weight percentages of Pt. Catalytic function of the prepared composite catalysts were tested by the oxidation of CO to CO2. From the catalytic activity results, it has been found out that the catalysts prepared by the sonochemical method exhibited higher catalytic activity for CO oxidation, probably attributed to the higher Pt particle distribution achieved under sonication. Transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), and diffuse reflectance spectroscopy (DRS) were employed to characterize the resulting material. 相似文献
176.
177.
178.
Yamada S Yasui M Nogami T Ishida T 《Dalton transactions (Cambridge, England : 2003)》2006,(13):1622-1626
Complexation of 3-nitronyl-nitroxide-substituted pyrazolate (pzNN) and 3-imino-nitroxide-substituted pyrazolate (pzIN) with nickel(II) gave [Ni3(pzNN)6] and [Ni3(pzIN)6], respectively. They were practically isomorphous and characterized as a linear trinuclear structure with neighboring nickel ions triply bridged by pyrazolate moieties. The space groups were P2(1)/n but the molecules have a pseudo three-fold axis. We found polymorphs in the crystals of [Ni3(pzIN)6] depending on the solvate molecules; another space group was a cubic Pa3[combining macron]. The opposite chirality around the inversion center at the central nickel(II) ion leads to a meso-helical symmetry in the whole molecule. The radical oxygen atoms participate in the 6-membered chelation at the terminal nickel(II) ions. Antiferromagnetic couplings were observed in both complexes, which are ascribable to interactions between the nickel and radical spins and between the nickel spins across the pyrazolate bridges. 相似文献
179.
Shinro Yasui Kenji Itoh Atsuyoshi Ohno Norihiro Tokitoh 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8-9):2001-2002
When trivalent phosphorus compounds (Z 3 P) reacted with viologens, either a single-electron transfer (SET) or a polar reaction takes place, depending on the kind of substituents of viologens. 相似文献
180.
[reaction: see text] The 9,10-dicyanoanthracene (DCA)-sensitized photoreaction of triarylphosphines (1) was carried out in acetonitrile under aerobic conditions. Phosphine 1 was oxidized to the corresponding phosphine oxide with no appreciable side reactions. Product analysis and laser flash photolysis experiments suggest that the radical cation of 1 formed by the electron transfer from 1 to DCA in the singlet excited state ((1)DCA) reacts with O(2) to eventually afford the phosphine oxide. 相似文献