全文获取类型
收费全文 | 476篇 |
免费 | 6篇 |
国内免费 | 4篇 |
专业分类
化学 | 333篇 |
晶体学 | 13篇 |
力学 | 10篇 |
数学 | 20篇 |
物理学 | 110篇 |
出版年
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2016年 | 3篇 |
2015年 | 9篇 |
2014年 | 7篇 |
2013年 | 25篇 |
2012年 | 33篇 |
2011年 | 29篇 |
2010年 | 27篇 |
2009年 | 18篇 |
2008年 | 25篇 |
2007年 | 20篇 |
2006年 | 20篇 |
2005年 | 34篇 |
2004年 | 22篇 |
2003年 | 22篇 |
2002年 | 29篇 |
2001年 | 8篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 10篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 3篇 |
1978年 | 8篇 |
1977年 | 4篇 |
1976年 | 1篇 |
1975年 | 4篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1968年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有486条查询结果,搜索用时 500 毫秒
41.
Yoshinori Miyazaki Nobuyoshi Asai Yasushi Kikuchi DongSheng Cai Yasuhiko Ikebe. 《Mathematics of Computation》2004,73(246):719-730
In this paper, it is first given as a necessary and sufficient condition that infinite matrices of a certain type have double eigenvalues. The computation of such double eigenvalues is enabled by the Newton method of two variables. The three-term recurrence relations obtained from its eigenvalue problem (EVP) subsume the well-known relations of (A) the zeros of ; (B) the zeros of ; (C) the EVP of the Mathieu differential equation; and (D) the EVP of the spheroidal wave equation. The results of experiments are shown for the three cases (A)-(C) for the computation of their ``double pairs'.
42.
Murakami T Nishikiori T Nohira T Ito Y 《Journal of the American Chemical Society》2003,125(2):334-335
Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber-Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodically oxidized and reacts with hydrogen to produce ammonia at the anode. 相似文献
43.
44.
In the traditional design of reliability tests for assuring the mean time to failure (MTTF) in Weibull distribution with shape and scale parameters, it has been assumed that the shape parameter in the acceptable and rejectable populations is the same fixed number. For the purpose of expanding applicability of the reliability testing, Hisada and Arizono have developed a reliability sampling scheme for assuring MTTF in the Weibull distribution under the conditions that shape parameters in the both populations do not necessarily coincide, and are specified as interval values, respectively. Then, their reliability test is designed using the complete lifetime data. In general, the reliability testing based on the complete lifetime data requires the long testing time. As a consequence, the testing cost becomes sometimes expensive. In this paper, for the purpose of an economical plan of the reliability test, we consider the sudden death procedure for assuring MTTF in Weibull distribution with variational shape parameter. 相似文献
45.
Tatsuya Suzuki Yasuhiko Fujii Wu Yan Hitoshi Mimura Shin-ichi Koyama Masaki Ozawa 《Journal of Radioanalytical and Nuclear Chemistry》2009,282(2):641-644
We investigated the adsorption behaviors of technetium and rhenium on tertiary pyridine resin in hydrochloric acid solution.
Technetium has a little larger distribution coefficient in higher concentration of hydrochloric acid region than rhenium.
However, the tendency of adsorption behavior of technetium and rhenium is similar. We concluded that the rhenium can be used
as the substitute for technetium. Adsorption behaviors of platinum group elements were also investigated. The separation of
technetium from platinum group elements is discussed. 相似文献
46.
本文利用广义逆矩阵,提出了解决非线性屈曲问题的广义增量法。并用该法分析了非线性荷载-位移关系曲线(其中包括极值点)。最后,给出一数值算例—三维扁平桁架结构的弹塑性屈曲分析,证明了本文方法的正确性和实用性。 相似文献
47.
Aubert T Ledneva AY Grasset F Kimoto K Naumov NG Molard Y Saito N Haneda H Cordier S 《Langmuir : the ACS journal of surfaces and colloids》2010,26(23):18512-18518
Metal atom clusters constitute very promising candidates as luminophores for applications in biotechnology because they are nanosized entities offering robust luminescence in the near-infrared field (NIR). However, they cannot be used as prepared for biological applications because of potential toxic effects and quenching of the clusters' luminescence in aqueous media, and they therefore need to be dispersed in a biocompatible matrix. We describe herein the encapsulation of octahedral rhenium clusters, denoted as A(4)[Re(6)Q(8)L(6)] (A = Cs or K, Q = S or Se, and L = OH or CN), in silica nanoparticles by a water-in-oil microemulsion process, paying particular attention to the clusters' stability. The obtained A(4)[Re(6)Q(8)L(6)]@SiO(2) nanoparticles are 30 nm in size with good monodispersity and a perfectly spherical shape, as shown by scanning electron microscopy (SEM). The presence of cluster units inside the silica matrix was evidenced by scanning transmission electron microscopy in annular dark-field mode (ADF-STEM). From the point of view of their optical properties, the A(4)[Re(6)Q(8)L(6)]@SiO(2) nanoparticles show red and NIR emission under UV excitation, even when dispersed in water. The evolution of the structural and luminescence properties of clusters before and after encapsulation was followed by Raman and photoluminescence spectroscopy. 相似文献
48.
Shimizu M Sakakura M Kanehira S Nishi M Shimotsuma Y Hirao K Miura K 《Optics letters》2011,36(11):2161-2163
We report on the formation mechanism of element distribution in glass under high-repetition-rate femtosecond laser irradiation. We simultaneously focused two beams of femtosecond laser pulses inside a glass and confirmed the formation of characteristically shaped element distributions. The results of the numerical simulation in which we considered concentration- and temperature-gradient-driven diffusions were in excellent qualitative agreement with the experimental results, indicating that the main driving force is the sharp temperature gradient. Since the composition of a glass affects its refractive index, absorption, and luminescence property, the results in this study provide a framework to fabricate a functional optical device such as optical circuits with a high-repetition-rate femtosecond laser. 相似文献
49.
Shin-ichiro Hayashi Munenori Yoshioka Shuji Usui Kiyofumi Haneda Takahiro Kondo Kim B. McAuley Takahiro Tominaga 《Radiation Physics and Chemistry》2010,79(7):803-808
In radiotherapy treatment, polymer gel dosimetry can be used for verifying three-dimensional (3D) dose distributions. Gelatin is generally used as a gelling agent in the dosimeters. In this paper, another role of gelatin in a methacrylic-acid-based gel dosimeter (MAGAT) is investigated. Temperature increases due to exothermic polymerization in the irradiated gel are measured directly. Dose–R2 responses are also obtained using MRI. It is shown that no appreciable increases in either temperature or R2 are observed in MAGAT dosimeters made without gelatin, and that significant temperature and R2 increases are observed when very low gelatin concentrations are used. These results indicate that gelatin is an important enabler for radiation-induced free-radical polymerization in methacrylic-acid-based gels. When gelatin is replaced by amino acids, changes in temperature are observed, along with small changes in R2. The resulting dosimeter solutions remain transparent because the polymer does not precipitate as it does in regular MAGAT dosimeters containing gelatin. When the amino acids are replaced by acids without amino groups, no temperature or R2 changes are observed, indicating that no polymer forms. These results show that amino groups (and possibly other functional groups) on the gelatin catalyze the radiation-induced free-radical polymerization that occurs in MAGAT dosimeters. 相似文献
50.
A new approach to reduce the reverse current of Ge pin photodiodes on Si is presented, in which an i-Si layer is inserted between Ge and top Si layers to reduce the electric field in the Ge layer. Without post- growth annealing, the reverse current density is reduced to -10 mA/cm^2 at -1 V, i.e., over one order of magnitude lower than that of the reference photodiode without i-Si layer. However, the responsivity of the photodiodes is not severely compromised. This lowered-reverse-current is explained by band-pinning at the i-Si/i-Ge interface. Barrier lowering mechanism induced by E-field is also discussed. The presented "non-thermal" approach to reduce reverse current should accelerate electronics-photonics convergence by using Oe on the Si complementary metal oxide semiconductor (CMOS) platform. 相似文献