全文获取类型
收费全文 | 303篇 |
免费 | 6篇 |
国内免费 | 5篇 |
专业分类
化学 | 187篇 |
晶体学 | 1篇 |
力学 | 7篇 |
数学 | 44篇 |
物理学 | 75篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 3篇 |
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 6篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 9篇 |
2013年 | 17篇 |
2012年 | 12篇 |
2011年 | 19篇 |
2010年 | 13篇 |
2009年 | 10篇 |
2008年 | 18篇 |
2007年 | 26篇 |
2006年 | 17篇 |
2005年 | 17篇 |
2004年 | 12篇 |
2003年 | 9篇 |
2002年 | 13篇 |
2001年 | 13篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1997年 | 5篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1977年 | 2篇 |
1966年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有314条查询结果,搜索用时 15 毫秒
31.
Kanishka Perera Martin Schechter 《Proceedings of the American Mathematical Society》2001,129(8):2301-2308
We compute critical groups of zero for variational functionals arising from semilinear elliptic boundary value problems with jumping nonlinearities when the asymptotic limits of the nonlinearity fall in certain parts of Type (II) regions between curves of the Fucik spectrum.
32.
We study a central bank intervention (CBI) problem in the foreign exchange market when the exchange rate follows a jump-diffusion process and show that the optimal CBI policy is a control-band policy. Our main contribution is a rigorous proof of the existence and uniqueness of the optimal CBI policy. 相似文献
33.
S Matsuo N Sakaguchi E Obuchi K Nakano R C Perera T Watanabe T Matsuo H Wakita 《Analytical sciences》2001,17(1):149-153
Ni L- and Ti L-edge as well as Ti K-edge X-ray absorption experiments for TiO2 thin films and Ni-doped TiO2 thin films coated on glass plates were performed using synchrotron radiation to investigate the structures around Ni and Ti ions in the films. The obtained spectra were compared with the results of theoretical calculations. It has consequently been found that the spectral features were affected by a change in the oxidizing form of Ni ions due to hydrogen reduction, by the charge variation and/or slight orbital splitting of Ti ions, and by the magnitude of the interaction between the center Ti ion and neighboring Ti ions. 相似文献
34.
M. Ramos Suzarte N. Rodríguez J. P. Oliva N. Iznaga A. Perera A. Morales N. Gonzalez O. Torres T. Rodríguez 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(2):499-503
Monoclonal antibody ior egf/r3 is a IgG2a, recognizes the epidermal growth factor receptor. The aim of the present work was
to evaluate the diagnostic efficacy of the99mTc-labeled ior egf/r3 for the detection of epithelial tumors, its metastasis and its recurrences. The sensitivity by organs
was: brain 100%, diegestive tract 90%, head and neck 89%, lung 84% and breast 79%. The overall sensitivity, specificity, accuracy,
positive predictive value and negative predictive value of the immunoscintigraphic imaging were 84.1%, 100%, 86.5%, 100% and
52.4%, respectively. Immunoscintigraphy with99mTc-ior egf/r3 is useful for the diagnosis and follow-up of epithelial tumors. 相似文献
35.
Ky Ho Kanishka Perera Inbo Sim Marco Squassina 《Journal of Fixed Point Theory and Applications》2017,19(1):157-173
We study a class of fractional p-Laplacian problems with weights which are possibly singular on the boundary of the domain. We provide existence and multiplicity results as well as characterizations of critical groups and related applications. 相似文献
36.
Y.P.Y.P. Ariyasinghe T.R.C.K. Wijayarathna I.G.C.K. Kumara I.P.L. Jayarathna C.A. Thotawatthage W.S.S. Gunathilake G.K.R. Senadeera V.P.S. Perera 《Journal of photochemistry and photobiology. A, Chemistry》2011,217(1):249-252
For the first time in SnO2 based dye solar cells, here we report, efficiency exceeding 3% of the cells consisting with Indoline D-149 dye with unmodified SnO2 nano-crystallites. The cells sensitized with metal free D-149 dye together with liquid electrolyte comprising with 0.5 M tetrapropyl ammonium iodide and 0.05 M iodine in a mixture of acetonitrile and ethylene carbonate (1:4 by volume) delivered a short circuit current density of 10.4 mA cm?2 with an open circuit voltage of 530 mV under the illumination of 100 mW cm?2 (AM1.5) having an efficiency of 3.1%. As evident from the FTIR measurement, strong surface passivation of recombination centers of SnO2 crystallites due to the dual mode of attachment of dye molecules to the surface of SnO2 via both COOH and S–O direct bond might be the possible reason for this enhancement in these SnO2 based cells. 相似文献
37.
Hisao Yamashige Shuji Matsuo Tsutomu Kurisaki Rupert C C Perera Hisanobu Wakita 《Analytical sciences》2005,21(3):309-314
X-ray absorption near edge structure (XANES) measurements at the C, N, and Fe K absorption edges were performed for iron(III)-tetraphenylporphyrin (FeTPP), iron(III)-tetrakis(p-carboxyphenyl)porphyrin (FeTCPP), and iron(III)-tetrakis(p-sulfonatophenyl)porphyrin (FeTSPP). The spectral shapes differ in the Fe K XANES, but not in C and N K XANES among FeTPP, FeTCPP, and FeTSPP. Crosschecks of XANES data for C, N, and Fe K absorption edges in combination with discrete variational (DV)-Xalpha molecular orbital (MO) calculations indicate that each p-electron-withdrawing group on four meso-phenyl substitutes in an Fe(III)-porphyrin complex brings about a unique electron state through the complex because of the electron-withdrawal strength, itself. Consequently, they affect the positive charge of the center Fe(III) ion. 相似文献
38.
Hisao Yamashige Shuji Matsuo Tsutomu Kurisaki Rupert C C Perera Hisanobu Wakita 《Analytical sciences》2005,21(6):635-639
This study investigated the protonation of nitrogen atoms in porphyrins with meso-phenyl p-substituted by an electron-withdrawing group using N 1s X-ray photoelectron spectroscopy (XPS), the N K X-ray absorption near-edge structure (XANES), and the discrete variational (DV)-Xalpha molecular orbital (MO) method. Both tetraphenylporphyrin (TPP) and tetrakis(p-sulfonatophenyl)porphyrin (TSPP) have a single structure: the former has two protonated and two non-protonated N atoms in the porphine ring; the latter has four protonated N atoms in the porphine ring. In contrast, a combination of XPS, XANES, and DV-Xalpha MO calculations shows that tetrakis(p-carboxyphenyl)porphyrin (TCPP) has a dual structure: one structure has two protonated and two non-protonated N atoms; the other has four protonated N atoms. Furthermore, this result was also considered based on the protonation constants of N atoms in the porphyrins. The correlation between the strength of electron-withdrawing groups and protonation to N atoms in porphyrins can be described using the spectral patterns of the N 1s XPS and N K XANES spectra. 相似文献
39.
V. I. Molchanova R. G. Ovodova I. Perera Yu. S. Ovodov 《Chemistry of Natural Compounds》1982,18(6):639-642
A carbohydrate-protein biopolymer which has been called corallan has been isolated from the soft coralP. americana. It has been shown that corollan consists of a proteoglycan including a protein component and a polysaccharide component connected with one another by a fairly strong bond. The polysaccharide moiety is a sulfated glycuronoglycan containing residues of fucose, arabinose, galactose, glucose, and a uronic acid and, possibly, also of aminosugars. 相似文献
40.
J. H. Bradbury J. A. Elix M. C. S. Perera 《Journal of polymer science. Part A, Polymer chemistry》1988,26(2):615-626
Natural rubber was isomerized by two methods that involved either dehydrobromination of hydrobrominated natural rubber or heating natural rubber with butadiene sulfone. The 13C-NMR spectra of the methylene region of isomerized natural rubber was interpreted in terms of dyad arrangements for which assignments were made by calculating chemical shifts according to three different published methods. One method [Gronski, Murayama, Cantow, and Miyamoto, Polymer, 17 , 358 (1976)] gave the best overall agreement with the experimental chemical shifts; another [Sato, Ono, and Tanaka, Polymer, 18 , 580 (1977)] was better for C-1 and C-3 methylene carbon atoms; and still another [Khatchaturov, Dolinsky, Prozenko, Abramenko, and Kormer, Polymer 18 , 871 (1977)] gave results which deviated considerably from the other methods. From 13C-NMR intensity measurements it was shown that the elimination of HBr from hydrobrominated natural rubber occurred by a random process. Contrary to literature reports, it was found that the sulphur dioxide catalyzed isomerization of natural rubber was accompanied by a significant amount of double bond migration; a possible reaction scheme was proposed. 相似文献