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21.
In this report, we describe the noncatalytic and template-free synthesis of zinc nitride (Zn3N2) novel microstructures with hollow interiors via simple nitridation reaction of zinc powder at optimum temperature of 600° C for 120 min in ammonia gas environment under atmospheric pressure. Hollow microstructures obtained were mostly of spherical shape with diameters in the range 8–35 μm and with open mouth on the surface. The growth mechanism has been proposed for the elucidation of hollow structures formation. Crystal structure and phase purity of the product were investigated by X-ray diffraction (XRD) characterization and energy dispersive X-ray spectroscopy (EDS) analysis confirmed the chemical composition of the product. Morphology of the as-prepared product was investigated using scanning electron microscopy (SEM). Ultraviolet–visible–near infrared (UV–vis–NIR) spectrophotometry was used to study the transmittance behaviour of zinc nitride microstructures and thereby an indirect optical band gap of 2.81 eV was calculated using Davis–Mott model. Room temperature photoluminescence (PL) studies exhibited two prominent peaks of the product; one very strong peak near band edge UV emission (395 nm) and other comparatively suppressed and broad peak at orange luminescence emission (670 nm). 相似文献
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Perveen R Jamil Y Ashraf M Ali Q Iqbal M Ahmad MR 《Photochemistry and photobiology》2011,87(6):1453-1463
The water-soaked seeds of sunflower were exposed to low power continuous wave He-Ne laser irradiation of energies 0, 100, 300 and 500 mJ to evaluate the effect on various biochemical, physiological, growth and yield parameters of sunflower. The experiments which consisted of four replicates arranged in a completely randomized design (CRD) were carried out under the greenhouse conditions. The physiological attributes like, photosynthetic rate (A), transpiration rate (E), intrinsic CO(2) concentration (C(i) ), stomatal conductance (g(s)), chlorophyll a and b contents, relative membrane permeability and leaf water (ψ(w)), osmotic (ψ(s)) and turgor (ψ(p)) potentials, relative water contents and leaf area increased significantly as compared to control due to He-Ne treatment of seeds. The activities of superoxide dismutase, peroxidase and catalases and contents of total soluble proteins, malondialdehyde, proline and leaf total phenolic also increased due to laser treatment. Significant increase in growth parameters of sunflower like shoot fresh and dry masses, root fresh and dry masses, root and shoot lengths, number of leaves per plant and stem diameter has also been observed. The contents of K, Ca and Mg in shoot and root were also increased and an overall increase of up to 28.12% was observed due to laser treatment. 相似文献
25.
N. Siddique S. Waheed M. Daud A. Rahman S. Ahmad 《Journal of Radioanalytical and Nuclear Chemistry》2007,274(1):181-186
Detailed investigations have been carried out on the well-known method of spectrophotometric determination of boron particularly
in uranium compounds as boron-curcumin complex after extraction into 2-ethyl hexane 1,3-diol (EHD) to understand a number
of parameters, which have not been addressed earlier in the literature. These include (i) effect of different acid media on
analytical results of boron which are employed for dissolution of nuclear fuel samples, (ii) effect of diluents namely ethyl
alcohol and N,N-dimethyl formamide on sensitivity of method which are employed for final dilution, and (iii) studies on loss
of boron, if any, during conversion of uranium compounds to U3O8. Based on the present studies, the existing procedure has been suitably modified to improve the sensitivity in the measurements.
In addition, this paper also describes about interference studies with Al, Cr, Mg, Ca, Fe, Mn, Mo, F− and W and amount of EHD on modified method. Absolute detection limit was found to be 10 ng. The precision and accuracy of
the method, is 3% at level 100 ng·g−1 of boron. 相似文献
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Jabbar A Tufail M Arshed W Bhatti AS Ahmad SS Akhter P Dilband M 《Isotopes in environmental and health studies》2010,46(4):495-505
In Rechna Doab, samples of the most common vegetation, perennial grass Desmostachya bipinnata (dab), were collected along with soil samples from 29 sites. Natural radioactivity of 22?Ra, 232Th/22?Ac and ??K was measured by using high purity germanium-based gamma ray spectrometer. Activity concentration levels of 22?Ra, 232Th/22?Ac and ??K in soil were found to be 46.8 ± 6.2 (36.0-57.6), 61.4 ± 5.9 (48.2-73.2) and 644.8 ± 73.9 (537.7-868.4) Bq kg?1 (dry mass), respectively, and those in vegetation were 2.74 ± 1.70 (1.00-6.39), 2.24 ± 0.59 (1.56-2.61) and 172.72±113.37 (53.14-469.24) Bq kg?1 (dry mass), respectively. The measured values of the activity concentration in vegetation are comparable with some other international data. Calculated soil to vegetation transfer factors of 22?Ra, 22?Ac and ??K were 0.06 ± 0.03 (0.02-0.14), 0.04 ± 0.01 (0.03-0.04) and 0.26 ± 0.16 (0.09-0.69). The mean outdoor absorbed dose rate in air for the area under study was determined as 8.22 nGy h?1 and the mean indoor absorbed dose rate in air was 11.52 nGy h?1. The total annual effective dose to the general public from the vegetation was found to be (0.02-0.16) mSv, which is below the recommended limit value of 1 mSv y?1 for the general public. The dab vegetation under study was found to be radiologically safe for the population and environment. 相似文献
28.
Abdul Jabbar Muhammad Tufail Waheed Arshed Arshed Salem Bhatti Syed Salman Ahmad Perveen Akhter 《Isotopes in environmental and health studies》2013,49(4):495-505
In Rechna Doab, samples of the most common vegetation, perennial grass Desmostachya bipinnata (dab), were collected along with soil samples from 29 sites. Natural radioactivity of 226Ra, 232Th/228Ac and 40K was measured by using high purity germanium-based gamma ray spectrometer. Activity concentration levels of 226Ra, 232Th/228Ac and 40K in soil were found to be 46.8±6.2 (36.0–57.6), 61.4±5.9 (48.2–73.2) and 644.8±73.9 (537.7–868.4) Bq kg?1 (dry mass), respectively, and those in vegetation were 2.74±1.70 (1.00–6.39), 2.24±0.59 (1.56–2.61) and 172.72±113.37 (53.14–469.24) Bq kg?1 (dry mass), respectively. The measured values of the activity concentration in vegetation are comparable with some other international data. Calculated soil to vegetation transfer factors of 226Ra, 228Ac and 40K were 0.06±0.03 (0.02–0.14), 0.04±0.01 (0.03–0.04) and 0.26±0.16 (0.09–0.69). The mean outdoor absorbed dose rate in air for the area under study was determined as 8.22 nGy h?1 and the mean indoor absorbed dose rate in air was 11.52 nGy h?1. The total annual effective dose to the general public from the vegetation was found to be (0.02–0.16) mSv, which is below the recommended limit value of 1 mSv y?1 for the general public. The dab vegetation under study was found to be radiologically safe for the population and environment. 相似文献
29.
Mukhtar Amir Nasir Habib Rashid Badar Waheed Hizba 《Journal of Thermal Analysis and Calorimetry》2019,138(6):3939-3947
Journal of Thermal Analysis and Calorimetry - For effective and reliable ignition of ammonium perchlorate and hydroxyl-terminated polybutadiene (AP/HTPB) solid composite propellant base bleed (BB)... 相似文献
30.
Hafiz Ejaz Ahmed Yasir Iqbal Muhammad Hammad Aziz Muhammad Atif Zahida Batool Atif Hanif Nafeesah Yaqub W. A. Farooq Shafiq Ahmad Amanullah Fatehmulla Hijaz Ahmad 《Molecules (Basel, Switzerland)》2021,26(15)
Metal oxide nanoparticles synthesized by the biological method represent the most recent research in nanotechnology. This study reports the rapid and ecofriendly approach for the synthesis of CeO2 nanoparticles mediated using the Abelmoschus esculentus extract. The medicinal plant extract acts as both a reducing and stabilizing agent. The characterization of CeO2 NPs was performed by scanning electron microscopy (SEM), X-ray diffraction (XRD), ultraviolet-visible spectroscopy (UV-Vis), and Fourier transform infrared spectroscopy (FTIR). The in vitro cytotoxicity of green synthesized CeO2 was assessed against cervical cancerous cells (HeLa). The exposure of CeO2 to HeLa cells at 10–125 µg/mL caused a loss in cellular viability against cervical cancerous cells in a dose-dependent manner. The antibacterial activity of the CeO2 was assessed against S. aureus and K. pneumonia. A significant improvement in wound-healing progression was observed when cerium oxide nanoparticles were incorporated into the chitosan hydrogel membrane as a wound dressing. 相似文献