Synthesis and photophysical studies of monocarboxy phthalocyanines containing quaternizable groups

This work reports on the synthesis and photophysical properties of novel unsymmetrically substituted monocarboxy magnesium (MgPc, 3), aluminum (ClAlPc, 4) and unmetallated (H₂Pc, 5) phthalocyanines. Magnesium phthalocyanine (3) was converted into water soluble quaternized derivative (QMgPc, 6) by reaction with methyl iodide. The synthesized phthalocyanines were characterized by IR, UV-Vis, NMR, mass spectrometry and elemental analyses. Photophysical and photochemical studies were carried out in order to determine the potential of the complexes as photosensitizers for use in photodynamic therapy. Triplet quantum yields ranged from 0.37 to 0.40 and triplet lifetimes from 110 to 140 μs in DMSO.     

Effect of tilting angles on the performance of reflective and transmitting types of fiber optic-based displacement sensors

The performances of the fiber optic-based displacement sensor with reflective and transmitting techniques were investigated. The effects of axial displacement on the detected voltage were investigated for different tilting angles of the reflective and receiving fibers. Three types of light sources were used, yellow and red He-Ne including a green pointer laser at peak wavelengths of 594, 633, and 533 nm correspondingly. The highest sensitivity and resolution were obtained at 0.0017 mV/μm and 4 μm, respectively with the employment of a 594 nm laser as the light source. These were attributed to the output power and beam quality of the laser which was the highest. The tilting angles didn’t change the sensitivity and resolution of the sensors in both setups. The widest linear range was obtained at 2410 μm with the transmitting technique. The simplicity of the design, high degree of sensitivity, linear range, non-contact measurement and low cost fabrication make it suitable for industrially-orientated applications that include control and micro-displacement in the hazardous region.     

Novel synthesis of nickel oxide-copper hexacyanoferrate binary hybrid nanocomposite for high-performance supercapacitor application

Journal of Solid State Electrochemistry - Nowadays, metal hexacyanoferrate/metal oxide composites have attracted intense interest as an electrode material for supercapacitor applications due to...     

Different Dimensionalities,Morphological Advancements and Engineering of g-C3N4-Based Nanomaterials for Energy Conversion and Storage

Graphitic carbon nitride (g-C₃N₄) has gained tremendous interest in the sector of power transformation and retention, because of its distinctive stacked composition, adjustable electronic structure, metal-free feature, superior thermodynamic durability, and simple availability. Furthermore, the restricted illumination and extensive recombination of photoexcitation electrons have inhibited the photocatalytic performance of pure g-C₃N₄. The dimensions of g-C₃N₄ may impact the field of electronics confinement; as a consequence, g-C₃N₄ with varying dimensions shows unique features, making it appropriate for a number of fascinating uses. Even if there are several evaluations emphasizing on the fabrication methods and deployments of g-C₃N₄, there is certainly an insufficiency of a full overview, that exhaustively depicts the synthesis and composition of diverse aspects of g-C₃N₄. Consequently, from the standpoint of numerical simulations and experimentation, several legitimate methodologies were employed to deliberately develop the photocatalyst and improve the optimal result, including elements loading, defects designing, morphological adjustment, and semiconductors interfacing. Herein, this evaluation initially discusses different dimensions, the physicochemical features, modifications and interfaces design development of g-C₃N₄. Emphasis is given to the practical design and development of g-C₃N₄ for the various power transformation and inventory applications, such as photocatalytic H₂ evolution, photoreduction of CO₂ source, electrocatalytic H₂ evolution, O₂ evolution, O₂ reduction, alkali-metal battery cells, lithium-ion batteries, lithium–sulfur batteries, and metal-air batteries. Ultimately, the current challenges and potential of g-C₃N₄ for fuel transformation and retention activities are explored.     

The Influence of Spin-Orbit Interaction on the Electron-Phonon Coupling in Tl-Rich Cubic AuCu3-Type Superconductors: Comparison with La3Tl

In this work, the role of spin-orbit coupling (SOC) in ATl₃ (A = Ca, Y, La, and Th) and La₃Tl is investigated by theoretical investigation of their structural, electronic, elastic, mechanical, phonon, and electron–phonon interaction properties. The effect of SOC on the electronic band structures of these compounds is that some of the degeneracies at the high symmetry points that would exist in a scalar relativistic calculation without SOC are removed by considering this coupling. The replacement of La and Tl atoms in LaTl₃ increases the value of the density of states at the Fermi level N($E_{\mathrm{F}}$) by a factor of 2.1. Furthermore, this replacement makes almost all phonon modes in La₃Tl softer than those in LaTl₃. Both softer phonon modes and higher N($E_{\mathrm{F}}$) make the electron–phonon interaction in La₃Tl much stronger than in LaTl₃. The presence of SOC increases the $T_{\mathrm{c}}$ values of LaTl₃ by 34% (from 1.151 to 1.542 K) and of ThTl₃ by 65% (from 0.479 to 0.793 K), resulting in good agreement with the corresponding experimental values of 1.63 and 0.87 K. The inclusion of SOC also improves the agreement with the experiment for $T_{\mathrm{c}}$ values of CaTl₃, YTl₃, and La₃Tl.