An efficient multistep iteration scheme for systems of nonlinear algebraic equations associated with integral equations

The aim of this research is to present a new iterative procedure in approximating nonlinear system of algebraic equations with applications in integral equations as well as partial differential equations (PDEs). The presented scheme consists of several steps to reach a high rate of convergence and also an improved index of efficiency. The theoretical parts are furnished, and several computational tests mainly arising from practical problems are given to manifest its applicability.     

The Performance of the Time-Frequency Analysis Software (TF32) in the Acoustic Analysis of the Synthesized Pathological Voice

The purpose of this study was to examine the algorithm-measuring capabilities used in the Time-Frequency Analysis Software Program for 32-bit Windows (TF32) for measuring fundamental frequency (F0), its dependent measures, and signal-to-noise ratio (SNR). The stability, accuracy, and linearity of its algorithm to systematic changes in aspiration noise and/or spectral slope (to mimic the perceptual characteristics of breathiness, roughness, and hoarseness) were evaluated using its analysis output to five female and five male synthesized voices. TF32 was used to calculate F0, Jitter%, Shimmer%, and SNR for each of the synthesized signals. The findings indicate that although TF32 produced stable results for male synthesized samples, they were not accurate when measuring F0, Jitter%, and Shimmer% with the addition of noise and variations in open quotient independently and in combination. In contrast, TF32 was neither stable nor accurate in making the same measurements for female synthesized samples. However, TF32 was stable and accurate in measuring SNR for male and most of female voices. These results point to an inappropriate F0 extraction algorithm in TF32 and stress the need for further research to remediate the algorithm or to identify a superior one.     

Organic vapor sensing properties and characterization of α-naphthylmethacrylate LB thin films

Determination of organic vapor sensing properties of α-Naphthylmethacrylate (α-NMA) monomer based Langmuir-Blodgett (LB) thin films was aimed in this study. LB thin film fabrication was performed on quartz glass and quartz crystal substrates in order to investigate the characterization and organic vapor properties of α-NMA materials by using UV-Visible, Atomic Force Microscopy (AFM) and Quartz Crystal Microbalance (QCM) techniques. π-A isotherm graph was taken and a suitable surface pressure value were primarily determined as 13?mN m^?1 for successful α-NMA LB thin film fabrication. Transfer ratio value was found to be ≥ 0.93 for quartz glass and quartz crystal substrates. The typical frequency shift per layer was obtained as 16.93?Hz/layer and the deposited mass onto a quartz crystal was calculated as 271.30?ng/layer (1.02?ng mm^?2). The sensing responses of α-NMA LB films against dichloromethane, chloroform, toluene and m-xylene were measured by QCM system. Dichloromethane created the maximum shift in the resonance frequency than other organic vapors used in this study. Results exhibited that α-NMA LB thin films were potential candidates for organic vapor sensing applications, especially high sensitive detection of dichloromethane at room temperature.     

Target transform fitting in a voltammetric study of metal complexation

In this work target transform fitting (TTF) is proposed as a hard-model based data analysis method to analyze differential pulse polarograms recorded in a successive metal complexation system. In such cases, equations for both complexation equilibria and shape of the differential pulse polarogram for individual species are available. Utilizing TTF to fit these models in separate stages, stability constants and E_1/2 values of species were estimated. In the first stage, E_1/2 values of all species were acquired using the shape-equation of voltamograms and projection of a test vector into the row space of data matrix. In the second stage, using equations derived from relationships among species’ concentrations in complexation equilibria and a non-linear parameter fitting algorithm, the optimum values of overall formation constants were estimated. Finally, rank annihilation (RA) method was employed for calculation of diffusion coefficients. In spite of the fact that proposed method is a hard-model based approach, obtained results show that analysis can be performed correctly even in presence of unknown species. The reliability of the method was tested analyzing simulated data and also polarograms obtained from Cd(II) and 1, 10-phenanthroline complexation system. This experimental system yields three successive complexes which are relatively inert from electrochemical point of view. The results were in a good agreement with reported results in the literature.     

Recent progress in pillar[n]arene-based thin films on chemical sensor applications

Journal of Inclusion Phenomena and Macrocyclic Chemistry - Pillar[n]arene is one of the most favorited supramolecular materials that possess a special chiral structure. The major property of...