Optically pumped GaAs waveguide lasers with a fundamental 0.11 μ corrugation feedback

Surface corrugations with a period of 0.115 μ were ion-milled on GaAs dielectric waveguides. Laser action was observed under optical pumping. Single mode as well as multimode oscillation was obtained under different pumping conditions.     

Narrowing and rebroadening of amplified spontaneous emission in high gain laser media

A series of recent papers by Allen and Peters on line narrowing in high gain laser media is criticized. New data demonstrating spectral narrowing followed by rebroadening are presented.     

GaAs distributed Bragg reflector lasers

An equivalent cavity approach is used to derive the oscillation condition of a distributed Bragg reflector laser. The oscillation frequencies and thresholds are determined graphically. The effect of lossy reflectors is discussed. Several advantages and potential applications of distributed Bragg reflector structures are pointed out. Experimental results on optically pumped GaAs lasers are presented.     

DNA unzipping and the unbinding of directed polymers in a random media

We consider the unbinding of a directed polymer in a random media from a wall in d=1+1 dimensions and a simple one-dimensional model for DNA unzipping. Using the replica trick we show that the restricted partition functions of these problems are identical up to an overall normalization factor. Our finding gives an example of a generalization of the stochastic matrix form decomposition to disordered systems, a method which allows us to reduce the dimensionality of the problem. The equivalence between the two problems, for example, allows us to derive the probability distribution for finding the directed polymer a distance z from the wall. We discuss implications of these results for the related Kardar-Parisi-Zhang equation and the asymmetric exclusion process.     

Giant fiber lasers: a new paradigm for secure key distribution

We propose and analyze a new concept for secure key distribution based on establishing laser oscillations between the sender and receiver. Compared to quantum mechanics based systems, our scheme allows for significantly higher key-establishing rates and longer ranges. By properly designing the laser structure, it is possible to increase the difficulty of eavesdropping almost arbitrarily, thus making our scheme an intriguing alternative and a complementary technology to quantum key-distribution systems.     

Cusp Singularities in Boundary-Driven Diffusive Systems

Boundary driven diffusive systems describe a broad range of transport phenomena. We study large deviations of the density profile in these systems, using numerical and analytical methods. We find that the large deviation may be non-differentiable, a phenomenon that is unique to non-equilibrium systems, and discuss the types of models which display such singularities. The structure of these singularities is found to generically be a cusp, which can be described by a Landau free energy or, equivalently, by catastrophe theory. Connections with analogous results in systems with finite-dimensional phase spaces are drawn.     

Thermo-infrared-spectroscopy analysis of dimethylsulfoxide-kaolinite intercalation complexes

Dimethylsulfoxide (DMSO) kaolinite complexes of low-and high-defect kaolinites were studied by thermo-IR-spectroscopy analysis. Samples were gradually heated up to 170°C, three hours at each temperature. After cooling to room temperature, they were pressed into KBr disks and their spectra were recorded. From the spectra two types of complexes were identified. In the spectrum of type I complex two bands were attributed to asymmetric and symmetric H-O-H stretching vibrations of intercalated water, bridging between DMSO and the clay-O-planes. As a result of H-bonds between intercalated water molecules and the O-planes, Si-O vibrations of the clay framework were perturbed, in the low-defect kaolinite more than in the high-defect. Type II complex was obtained by the thermal escape of the intercalated water. Consequently, the H-O-H bands were absent from the spectrum of type II complex and the Si-O bands were not perturbed. Type I complex was present up to 120°C whereas type II between 130 and 150°C. The presence of intercalated DMSO was proved from the appearance of methyl bands. These bands decreased with temperature due to the thermal evolution of DMSO but disappeared only in spectra of samples heated at 160°C. Intercalated DMSO was H-bonded to the inner-surface hydroxyls and vibrations associated with this group were perturbed. Due to the thermal evolution of DMSO the intensities of the perturbed bands decreased with the temperature. They disappeared at 160°C together with the methyl bands.     

Soft matter dispersions with ordered inner structures, stabilized by ethoxylated phytosterols

This paper describes the formation and characterization of liquid crystalline dispersions based on the hexagonal phase of GMO/tricaprylin/water. As a stabilizer of the soft particles dispersed in the aqueous phase, a non-ionic, non-polymeric surfactant—ethoxylated phytosterol with 30 oxyethylene units (PhEO) was utilized. In contrast to Pluronic copolymers, normally utilized in the stabilization of liquid crystalline dispersions with ordered inner structure, use of such non-polymeric surfactant is not a common practice in this field. We revealed how properties of these particles, such as internal structure, size, and stability, can be rationally modified by the concentration of the stabilizing agent and processing conditions. The physical stability of the hexosomes was further examined by the LUMiFuge technique.Structural effect of PhEO solubilization on the properties of the bulk H_II mesophase system showed that phase behavior was greatly influenced following phase transitions: H_II → H_II + cubic → cubic + L_α → L_α. The decrease of hydrogen bonding of the hydroxyl and carbonyl groups of monoolein with water and simultaneous hydration of EO groups of PhEO appeared to be important for the observed behavior. The use of PhEO as a dispersant resulted in a soft matter multi-phase water dispersion with bimodal distribution of the particle population. Effective stabilization of hexosomes was obtained in an extremely narrow concentration range of PhEO (0.1–0.2 wt%), coexisting with small vesicles and disordered particles. At higher PhEO content, particles had disordered inner structure, and unilamellar and multilamellar vesicles, at the expense of hexosomes in consequence of incorporation of the dispersant into the hexosome structure. PhEO was found to induce lamellar phase formation, introducing disorder into the hexagonal LLC and reducing their domain size.Finally, hexosomes were evaluated as delivery vehicles for the therapeutic peptide desmopressin. Sustained release of this drug was observed during the first 10 h; however, permeation drastically increased in the 10–24 h range.