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991.
992.
A new fluorogenic probe for sodium new houttuyfonate (SNH) was proposed. 4‐Methylumbelliferyl‐2,4‐dinitrobenzenesulfonate (4‐MUDNBS) was a nonfluorescent compound and was synthesized via the one‐step reaction of 4‐methylumbelliferone (4‐MU) with 2,4‐dinitrobenzenesulfonyl chloride. In basic media, SNH was decomposed to produce sodium sulfite, which then reacted with 4‐MUDNBS to yield highly fluorescent 4‐MU, hence leading to the fluorescence increase of the reaction solution. A linear correlation existed between the emission intensity and the concentration of SNH within the range from 0.5 to 15 μg·mL−1 with a detection limit of 0.15 μg· mL−1 (3δ). The effect of substituents on the benzenesulfonyl moiety of the probe is discussed, and the presence of electronegative groups is favorable for the proposed cleavage reaction. 相似文献
993.
Shou-Nian Ding Serge Cosnier Dan Shan Yue-Ming Sun Yao Wang 《Electrochemistry communications》2010,12(7):905-908
Elelctrogenerated chemiluminescence (ECL) of electropolymerized films based on [(2,2′-bipyridyl)(4-(2-pyrrol-1-ylethyl)-4′-methyl-2,2′-bipyridyl)2]ruthenium (II) was firstly investigated in both organic and aqueous solution. The ECL behaviors have been explained by two typical mechanisms, namely, redox-cycling type and oxidative-reduction type. For the former, no co-reactant was required and for the latter, tripropylamine (TPA) and (NH4)2C2O4 were selected as co-reactants in the organic and aqueous system, respectively. 相似文献
994.
Yao Yun Hu Jing Mei Yin Da Bin Gao Ying Ping Jia Guang Yun Zhou Ying Na Cui Shen Min Li 《中国化学快报》2008,19(5):529-532
Photopromoted carbonylation of 1-bromo-6-chlorohexane with CO catalyzed by CuBr2 and CdI2 has been carried out under ambient conditions. The results indicate that the carbonylation proceeds with the major product of chloroester ClCH2(CH2)5COOCH3 under catalysis of CuBr2. Furthermore, the activity of the carbonylation can be improved by addition of basic additives (NaOAc, Na3PO4 or (n-C4H9)3N). Among these additives, (n-C4H9)3N is the most efficient in terms of the yield of ClCH2(CH2)5COOCH3. However, the methoxycarbonyl substituting chlorine product of BrCH2(CH2)5COOCH3 is not obtained in the presence of CdI2. This is quite different from the carbonylation of monochloroalkane. 相似文献
995.
996.
Schiff碱N,N’-双水杨醛缩-1,6-己二胺的光致变色光谱研究 总被引:1,自引:0,他引:1
用稳态和时间相关荧光光谱、紫外 -可见吸收光谱和傅立叶变换红外光谱等方法研究了 Schiff碱N ,N -双水杨醛缩 -1 ,6-己二胺 ( BSH)的光致变色行为 .确定了光致变色的产物为双质子转移的酮式结构 . 相似文献
997.
998.
A microelectromechanical systems (MEMS) micromirror is demonstrated in this paper. The micromirror is actuated by an electrostatic force and can achieve a large out of plane stroke by eliminating the electrostatic pull-in effect. The micromirror consists of a mirror of 400 μm by 400 μm in the center, a spring and three fixed bottom electrodes each side. Design principles and the analytical model are both developed, and they are verified by finite element analysis (FEA). The resonant frequency for the piston movement of the designed micromirror is about 2.5 kHz by FEA simulation. The micromirror prototype has been fabricated by a surface micromachining process and it is successfully tested using a microsystem analyzer. An out of plane stroke of 1.65 μm is observed at 100 V and it agrees well with the predicted result from analytical model. 相似文献
999.
The title complex {[Co(dimb)2(H2O)2]·(NO3)2·(H2O)2}n ( 1 ) (dimb = 1,3‐di(imidazol‐1‐ylmethyl)‐5‐methylbenzene) has been hydrothermally synthesized by the reaction of dimb with Co(NO3)2·6H2O in aqueous solution. The cobalt(II) atoms are linked by bridging dimb ligands to form 2D corrugated and wavy networks containing Co4(dimb)4 macrocyclic motifs. Two neighboring independent layers interlinked each other in a parallel fashion to construct three‐dimensional structure by O–H···O, N–H···O and C–H···O hydrogen bonds. Magnetic measurement shows the weak antiferromagnetic interaction with a one‐dimensional chain model in the range of 5–300 K, with J of –0.68 cm−1. 相似文献
1000.