全文获取类型
收费全文 | 241295篇 |
免费 | 4651篇 |
国内免费 | 2604篇 |
专业分类
化学 | 134034篇 |
晶体学 | 3540篇 |
力学 | 10336篇 |
综合类 | 131篇 |
数学 | 26780篇 |
物理学 | 73729篇 |
出版年
2021年 | 1953篇 |
2020年 | 2221篇 |
2019年 | 2399篇 |
2018年 | 2988篇 |
2017年 | 2997篇 |
2016年 | 4341篇 |
2015年 | 3053篇 |
2014年 | 4324篇 |
2013年 | 10110篇 |
2012年 | 9027篇 |
2011年 | 10972篇 |
2010年 | 7770篇 |
2009年 | 7545篇 |
2008年 | 10057篇 |
2007年 | 10083篇 |
2006年 | 9530篇 |
2005年 | 8574篇 |
2004年 | 7676篇 |
2003年 | 6677篇 |
2002年 | 6636篇 |
2001年 | 7542篇 |
2000年 | 5699篇 |
1999年 | 4291篇 |
1998年 | 3463篇 |
1997年 | 3403篇 |
1996年 | 3360篇 |
1995年 | 2918篇 |
1994年 | 2978篇 |
1993年 | 2810篇 |
1992年 | 3044篇 |
1991年 | 3096篇 |
1990年 | 2877篇 |
1989年 | 2756篇 |
1988年 | 2677篇 |
1987年 | 2595篇 |
1986年 | 2600篇 |
1985年 | 3390篇 |
1984年 | 3416篇 |
1983年 | 2846篇 |
1982年 | 3078篇 |
1981年 | 2840篇 |
1980年 | 2627篇 |
1979年 | 2805篇 |
1978年 | 3014篇 |
1977年 | 3050篇 |
1976年 | 3085篇 |
1975年 | 2820篇 |
1974年 | 2925篇 |
1973年 | 2971篇 |
1972年 | 2328篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
861.
862.
A two-dimensional linear analysis of the planar flame front stability for a compressible fluid is presented. The analysis shows that there are two types of perturbations. The first type, corresponding to waves in incompressible media, has already been studied by Landau. It predicts absolute instability of the flame front. The second type of perturbations is due to fluid compressibility and the dependence on upstream flow parameters of the flame front velocity. Three different regimes for these perturbations are possible: stable, acoustically unstable, and absolutely unstable. The instability results in a pronounced pressure wave generation.A one-dimensional analysis of the interaction of the flame front with flow boundaries is performed. Under some circumstances, this interaction is shown to cause exponential growth of the perturbations. 相似文献
863.
设H为复的可分无限维Hilbert空间,称有界线性算子T为强不可约的,如果与T可交换的幂等算子只有0和I.王宗尧、蒋春澜、纪有清等人证明了在任何一个套的套代数中都存在大量的强不可约算子,并且找到了它们的酉轨道闭包.本文考虑有限个套的张量积的代数中强不可约算子的存在性问题。证明了:对复平面上任何一个连通完备集σ、总存在一个对角算子N和它的一个范数可以任意小的紧摄动T=X+K,使得T是一个强不可约算子、T在有限个良序套的张量积的代数中,并且σ(T)=σlre(T)=σ(N)=σlre(N)=σ进一步,文章还对具有单点谱的算子和良序套与正交补为良序套的张量积的代数进行了讨论,得到了一些结果. 相似文献
864.
865.
866.
Deák L. Bottyán L. Major M. Nagy D. L. Spiering H. Szilágyi E. Tanczikó F. 《Hyperfine Interactions》2002,144(1-4):45-52
Hyperfine Interactions - Synchrotron Mössbauer Reflectometry (SMR), the grazing incidence nuclear resonant scattering of synchrotron radiation, can be applied to perform depth-selective phase... 相似文献
867.
Ricardo L. Mancera Michalis Chalaris Jannis Samios 《Journal of Molecular Liquids》2004,110(1-3):147-153
We have carried out a molecular dynamics study of dimethyl sulfoxide (DMSO) in water at 298 K at two different densities by simulating two different concentrations: 0.055 and 0.19 mole fraction. We have found an enhancement in the structure of water, an effect that becomes more pronounced as the concentration of DMSO increases. At both concentrations there is a well-defined hydration structure around the oxygen atom of DMSO, which is able to establish strong hydrogen bonds with surrounding water molecules. An increase in the concentration of DMSO depletes the solution of bulk water molecules, reducing the number of hydrogen bonds that water can have in the immediate vicinity of DMSO but increasing the strength of the hydrogen bonds made between the oxygen atom of DMSO and water. There is clear evidence of ‘hydrophobic’ hydration around the methyl groups of DMSO, which is enhanced as the concentration of DMSO increases. 相似文献
868.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
869.
Benzildithiosemicarbazone (BDTSC) is proposed as a sensitive and selective analytical reagent for the extractive spectrophotometric determination of copper(II). BDTSC reacts with copper(II) in the pH range 1.0-7.0 to form a yellowish complex. Beer's law is obeyed in the concentration range 0.5-0.4 microg cm(-3). The yellowish Cu(II)-BDTSC complex in chloroform shows a maximum absorbance at 380 nm, with molar absorptivity and Sandell's sensitivity values of 1.63 x 10(4) dm3 mol(-1) cm(-1) and 0.00389 microg cm(-2), respectively. A repetition of the method is checked by finding the relative standard deviation (RSD) (n = 10), which is 0.6%. The composition of the Cu(II)-BDTSC complex is established as 1:1 by slope analysis, molar ratio and Asmus' methods. An excellent linearity with a correlation coefficient value of 0.98 is obtained for the Cu(II)-BDTSC complex. The instability constant of the complex calculated from Edmond and Birnbaum's method is 7.70 x 10(-4) and that of Asmus' method is 7.66 x 10(-4), at room temperature. The method is successfully employed for the determination copper(II) in pharmaceutical and environmental samples. The reliability of the method is assured by analyzing the standard alloys (BCS 5g, 10g, 19e, 78, 32a, 207 and 179) and by inter-comparison of experimental values, using an atomic absorption spectrometer. 相似文献
870.
We show that the complex projection of a completely positive quaternionic map of quaternionic density matrices is a positive
map in the space of complex density matrices, and we briefly outline some of its properties. To illustrate this result, we
study the complex projection of a one-parameter quaternionic unitary dynamics of a spin-1/2 quantum system.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 151, No. 3, pp. 360–370, June, 2007. 相似文献