全文获取类型
收费全文 | 241665篇 |
免费 | 4714篇 |
国内免费 | 2612篇 |
专业分类
化学 | 134258篇 |
晶体学 | 3540篇 |
力学 | 10362篇 |
综合类 | 131篇 |
数学 | 26782篇 |
物理学 | 73918篇 |
出版年
2021年 | 1990篇 |
2020年 | 2230篇 |
2019年 | 2411篇 |
2018年 | 3006篇 |
2017年 | 3015篇 |
2016年 | 4353篇 |
2015年 | 3070篇 |
2014年 | 4338篇 |
2013年 | 10136篇 |
2012年 | 9055篇 |
2011年 | 10972篇 |
2010年 | 7770篇 |
2009年 | 7545篇 |
2008年 | 10057篇 |
2007年 | 10083篇 |
2006年 | 9530篇 |
2005年 | 8576篇 |
2004年 | 7676篇 |
2003年 | 6677篇 |
2002年 | 6637篇 |
2001年 | 7542篇 |
2000年 | 5700篇 |
1999年 | 4291篇 |
1998年 | 3464篇 |
1997年 | 3403篇 |
1996年 | 3360篇 |
1995年 | 2918篇 |
1994年 | 2978篇 |
1993年 | 2810篇 |
1992年 | 3044篇 |
1991年 | 3096篇 |
1990年 | 2878篇 |
1989年 | 2758篇 |
1988年 | 2677篇 |
1987年 | 2595篇 |
1986年 | 2600篇 |
1985年 | 3390篇 |
1984年 | 3416篇 |
1983年 | 2847篇 |
1982年 | 3078篇 |
1981年 | 2841篇 |
1980年 | 2628篇 |
1979年 | 2807篇 |
1978年 | 3014篇 |
1977年 | 3050篇 |
1976年 | 3085篇 |
1975年 | 2820篇 |
1974年 | 2925篇 |
1973年 | 2971篇 |
1972年 | 2328篇 |
排序方式: 共有10000条查询结果,搜索用时 18 毫秒
821.
Deák L. Bottyán L. Major M. Nagy D. L. Spiering H. Szilágyi E. Tanczikó F. 《Hyperfine Interactions》2002,144(1-4):45-52
Hyperfine Interactions - Synchrotron Mössbauer Reflectometry (SMR), the grazing incidence nuclear resonant scattering of synchrotron radiation, can be applied to perform depth-selective phase... 相似文献
822.
Ricardo L. Mancera Michalis Chalaris Jannis Samios 《Journal of Molecular Liquids》2004,110(1-3):147-153
We have carried out a molecular dynamics study of dimethyl sulfoxide (DMSO) in water at 298 K at two different densities by simulating two different concentrations: 0.055 and 0.19 mole fraction. We have found an enhancement in the structure of water, an effect that becomes more pronounced as the concentration of DMSO increases. At both concentrations there is a well-defined hydration structure around the oxygen atom of DMSO, which is able to establish strong hydrogen bonds with surrounding water molecules. An increase in the concentration of DMSO depletes the solution of bulk water molecules, reducing the number of hydrogen bonds that water can have in the immediate vicinity of DMSO but increasing the strength of the hydrogen bonds made between the oxygen atom of DMSO and water. There is clear evidence of ‘hydrophobic’ hydration around the methyl groups of DMSO, which is enhanced as the concentration of DMSO increases. 相似文献
823.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
824.
Benzildithiosemicarbazone (BDTSC) is proposed as a sensitive and selective analytical reagent for the extractive spectrophotometric determination of copper(II). BDTSC reacts with copper(II) in the pH range 1.0-7.0 to form a yellowish complex. Beer's law is obeyed in the concentration range 0.5-0.4 microg cm(-3). The yellowish Cu(II)-BDTSC complex in chloroform shows a maximum absorbance at 380 nm, with molar absorptivity and Sandell's sensitivity values of 1.63 x 10(4) dm3 mol(-1) cm(-1) and 0.00389 microg cm(-2), respectively. A repetition of the method is checked by finding the relative standard deviation (RSD) (n = 10), which is 0.6%. The composition of the Cu(II)-BDTSC complex is established as 1:1 by slope analysis, molar ratio and Asmus' methods. An excellent linearity with a correlation coefficient value of 0.98 is obtained for the Cu(II)-BDTSC complex. The instability constant of the complex calculated from Edmond and Birnbaum's method is 7.70 x 10(-4) and that of Asmus' method is 7.66 x 10(-4), at room temperature. The method is successfully employed for the determination copper(II) in pharmaceutical and environmental samples. The reliability of the method is assured by analyzing the standard alloys (BCS 5g, 10g, 19e, 78, 32a, 207 and 179) and by inter-comparison of experimental values, using an atomic absorption spectrometer. 相似文献
825.
We show that the complex projection of a completely positive quaternionic map of quaternionic density matrices is a positive
map in the space of complex density matrices, and we briefly outline some of its properties. To illustrate this result, we
study the complex projection of a one-parameter quaternionic unitary dynamics of a spin-1/2 quantum system.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 151, No. 3, pp. 360–370, June, 2007. 相似文献
826.
In this work preliminary results of amorphous zirconium crystallization using ion beam pulses are presented. Energetic argon- and oxygen-ion beams generated by a plasma focus device were used to promote crystallization on amorphous ZrO2-2.5 mol% Y2O3 film deposited by chemical solution deposition onto silica glass substrate. The films were burnt at 370 °C for 1 h in normal atmosphere previous to plasma irradiation. The irradiation was performed by means of successive pulses of ion beams. The evolution of the surface morphology and crystallization was followed by AFM and X-rays diffraction in a grazing incidence asymmetric Bragg geometry (GIAB), respectively. Argon-irradiated films showed highly nucleated cubic zirconia after 10 pulses. On the other hand, oxygen-irradiated films showed a delayed and less extensive cubic nucleation, but a more ordered structure and well-defined grains. 相似文献
827.
828.
L. G. Smirnova Yu. B. Grunin S. V. Krasil'nikova M. A. Zaverkina D. R. Bakieva E. V. Smirnov 《Colloid Journal》2003,65(6):778-781
The pulsed NMR, isopiestic and pycnometric methods are applied to investigate the physicochemical properties of softwood [GOST (State Standard) 9571-89] and hardwood [GOST 28172-89] celluloses, as well as flax cellulose [GOST 10330-76, 9394-76], both in the initial state and subjected to chemical treatment. Possible changes occurring in the supramolecular structure of a polymer are analyzed. The structural and sorption characteristics of the investigated samples are calculated. Their water absorption capacities are determined. 相似文献
829.
Within the framework of free interaction theory numerical methods are used to investigate the occurrence of supersonic zones with shocks in the outer inviscid region for flow past roughness in the lower viscous sublayer, with and without the formation of local separation zones. 相似文献
830.
This paper presents some properties of two restricted classes of multi-degree-of-freedom potential systems subjected to Gaussian white-noise excitations. Specifically, potential systems which exhibit damping terms with energy-dependent polynomial form are referred to. In this context, first systems with coupled stiffness terms and damping terms depending on the total energy are investigated. Then, systems with uncoupled stiffness terms and damping terms depending on the total energy in each degree-of-freedom are considered. For these two classes, it is found that algebraic relations among the stationary statistical moments of the energy functions can be derived by applying standard tools of Itô calculus. Further, it is noted that these relations are very useful within the framework of an equivalent statistical non-linearization technique to build approximate solutions for arbitrary non-linear systems. 相似文献