全文获取类型
收费全文 | 22024篇 |
免费 | 3687篇 |
国内免费 | 2571篇 |
专业分类
化学 | 15284篇 |
晶体学 | 275篇 |
力学 | 1491篇 |
综合类 | 172篇 |
数学 | 2520篇 |
物理学 | 8540篇 |
出版年
2024年 | 95篇 |
2023年 | 526篇 |
2022年 | 851篇 |
2021年 | 889篇 |
2020年 | 916篇 |
2019年 | 928篇 |
2018年 | 803篇 |
2017年 | 749篇 |
2016年 | 1122篇 |
2015年 | 1087篇 |
2014年 | 1269篇 |
2013年 | 1617篇 |
2012年 | 1920篇 |
2011年 | 1930篇 |
2010年 | 1434篇 |
2009年 | 1292篇 |
2008年 | 1425篇 |
2007年 | 1217篇 |
2006年 | 1183篇 |
2005年 | 967篇 |
2004年 | 721篇 |
2003年 | 574篇 |
2002年 | 611篇 |
2001年 | 437篇 |
2000年 | 410篇 |
1999年 | 465篇 |
1998年 | 353篇 |
1997年 | 333篇 |
1996年 | 317篇 |
1995年 | 290篇 |
1994年 | 233篇 |
1993年 | 205篇 |
1992年 | 176篇 |
1991年 | 165篇 |
1990年 | 155篇 |
1989年 | 127篇 |
1988年 | 95篇 |
1987年 | 63篇 |
1986年 | 64篇 |
1985年 | 62篇 |
1984年 | 38篇 |
1983年 | 29篇 |
1982年 | 27篇 |
1981年 | 13篇 |
1980年 | 13篇 |
1978年 | 8篇 |
1975年 | 10篇 |
1973年 | 6篇 |
1972年 | 9篇 |
1965年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
82.
Fang Yao 《Journal of multivariate analysis》2007,98(1):40-56
The estimation of a regression function by kernel method for longitudinal or functional data is considered. In the context of longitudinal data analysis, a random function typically represents a subject that is often observed at a small number of time points, while in the studies of functional data the random realization is usually measured on a dense grid. However, essentially the same methods can be applied to both sampling plans, as well as in a number of settings lying between them. In this paper general results are derived for the asymptotic distributions of real-valued functions with arguments which are functionals formed by weighted averages of longitudinal or functional data. Asymptotic distributions for the estimators of the mean and covariance functions obtained from noisy observations with the presence of within-subject correlation are studied. These asymptotic normality results are comparable to those standard rates obtained from independent data, which is illustrated in a simulation study. Besides, this paper discusses the conditions associated with sampling plans, which are required for the validity of local properties of kernel-based estimators for longitudinal or functional data. 相似文献
83.
自由电子激光振荡器的二维数值模拟 总被引:2,自引:2,他引:0
在柱二维坐标系中,用数值计算方法求解了摇摆器内电子模拟方程组、光场方程组和无源区(不含摇摆器区)经非自适应方法变换后的无源旁轴波动方程并设计了相应的程序R_2D。用该程序计算的数值结果表明,在有源条件下二维数值模拟结果与高斯光束近似下的数值模拟结果符合较好;取完全相同的计算条件R-2D程序与洛斯阿拉莫斯实验室(LANL)的FELEX程序的计算结果符合较好;初步认为LANL实验数据的物理图象合理,数值结果基本可信;最后给出北京自由电子激光器(BFEL)的一些物理数据。 相似文献
84.
类锂硅离子软X射线激光研究 总被引:1,自引:0,他引:1
在激光等离子体典型参数条件下,利用碰撞-辐模型计算了类锂硅离子5f-3d和4f-3d跃的粒子数反转比率和激光增益系数。讨论了不同热带条件和不同冷却速度下,激光增益系统数的变化。计算结果表明,高功率,短脉冲激光生产的高温等离子体在快速冷却条件下能产生软X射的线激光增益。 相似文献
85.
86.
87.
Cun Feng Fan David A. Waldman Shaw Ling Hsu 《Journal of Polymer Science.Polymer Physics》1991,29(2):235-246
Raman mechanical spectroscopy was used to examine interfacial effects on the stress distribution in model polydiacetylene fiber/epoxy composites. Epoxy release agents were coated on fiber surfaces to modify the interfacial adhesion properties. The modified fiber surfaces were then characterized by scanning electron microscopy and x-ray photoelectron spectroscopy as well as optical microscopy. No difference in the maximum stress value or stress distribution was observed for the two types of fibers, coated or uncoated, used in composites. This suggests that adhesion properties at the composite interface do not affect tensile stress transfer efficiency nor, therefore, the composite tensile modulus along the fiber axis direction in uniaxial composites. Experimental data were also compared with theoretical calculations assuming perfect bonding between fiber and matrix, and idealized frictional force transfer mechanism at the fiber–matrix interface. 相似文献
88.
89.
不同激发密度下CdS晶体的光致发光和受激发射 总被引:1,自引:1,他引:0
本文主要研究在77-111K温度范围内、不同激发密度的N2激光器的337.1nm谱线激发下,激子-激子(Ex-Ex)、激子-载流子(Ex-e)的相互作用和发射一个LO声子(Ex-1LO)、两个LO声子(Ex-2LO)的自由激子的辐射复合行为.并在77K温度下观测到由Ex-Ex发射产生的受激发射. 相似文献
90.