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41.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献
42.
The clusters of Eu3+ ion in Eu(DBM)3Phen-doped polymethyl methacrylate (PMMA) have been studied by three means. The relative fluorescence intensity ratio of the 5D0 → 7F2 to 5D0 → 7F1 transitions with different concentrations of Eu3+ in Eu(DBM)3Phen-doped PMMA and metastable-state (5D0) lifetime dependence on Eu3+ concentration are analyzed. The analysis indicates that there are no clustering effects in Eu3+ ions of Eu(DBM)3Phen-doped PMMA when the Eu3+ doping concentration is up to 1.0 wt.-%. At the same time, the clustering effect has not been observed by the scanning near-field optical microscopy (SNOM) in Eu(DBM)3Phen-doped PMMA with 1.0 wt.-% of Eu3+ ions. The analysis reveals that a high concentration of Eu3+ can be incorporated into polymer optical fiber (POF) without clustering effect.OCIS codes: 180.5810, 300.6280, 250.5460, 160.5690. 相似文献
43.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
44.
A series of 4,6-disubstituted pyrimidines were synthesized via Suzuki and Kumada coupling reaction of 4,6-dichloropyrimidine. 相似文献
45.
Zheng Yu 《manuscripta mathematica》2003,111(2):163-186
In this paper, the negative gradient flow for the L
2-integral of Ricci curvature on a 3-manifold is considered. It is not known whether the solution to this fourth order geometric
evolution equation exists, and whether it will develop singularities in finite time. Based on the trick of De Turck and the
idea of Hamilton on the flow of Ricci curvature, the local existence on any compact Riemannian manifold is obtained. In addition,
the conditions for the occurences of singularities in finite time during the evolution and the asymptotic behavior of the
flow on a 3-manifold are discussed.
Received: 22 April 2002 / Revised version: 5 January 2003
Published online: 24 April 2003
This work is partially supported by the Foundations of NNSF of China, the Foundation for University Key Teacher by MEC and
Shanghai Priority Academic Discipline. 相似文献
46.
本在Glover—Klingman算法及最小费用支撑树对策的基础上,讨论了最小费用k度限制树对策问题.利用威胁、旁支付理论制订了两种规则,并利用优超、策略等价理论分别给出了在这两种规则下最小费用k度限制树对策核心中的解,从而证明了在这两种规则下其核心非空. 相似文献
47.
Jin Sun Yihu Song Qiang Zheng Hong Tan Jie Yu Hong Li 《Journal of Polymer Science.Polymer Physics》2007,45(18):2594-2602
The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO2) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO2 causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO2 hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007 相似文献
48.
THE SCHWARZIAN DERIVATIVE IN SEVERAL COMPLEX VARIABLES(II) 总被引:1,自引:0,他引:1
THESCHWARZIANDERIVATIVEINSEVERALCOMPLEXVARIABLES(II)GONGSHENGYUQIHUANGZHENGXUEANManuscriptreceivedAugust30,1996.De... 相似文献
49.
Dao-sheng Zheng 《计算数学(英文版)》1998,(2)
1.IntroductionSince1984,severalchinesemathematicianshaveobtailledmanyresultsboutmatrixoperatornormcondition.umbe.[ll'12'18].Twokindsmatrixconditionnllmbers[9]are:(1)IfAECoxsisnonsingular,thellunlberK.(A)~IIAll.llA--'if.iscalledtheor--normconditionnumberof… 相似文献
50.
Wei‐Lie Xiao Jian‐Xin Pu Rui‐Rui Wang Liu‐Meng Yang Xiao‐Li Li Sheng‐Hong Li Rong‐Tao Li Sheng‐Xiong Huang Yong‐Tang Zheng Han‐Dong Sun 《Helvetica chimica acta》2007,90(8):1505-1513
Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1. 相似文献