Ni系列催化剂上甲烷直接氧化制合成气

采用固定床流动反应装置，考察负载型Ｎｉ系列催化剂在甲烷直接氧化制合成气反应上的催化活性．空速为５．０×１０５ｈ－１，ＣＨ４／Ｏ２＝２条件下，不同Ｎｉ含量的催化剂中，１５％Ｎｉ／Ａｌ２Ｏ３活性较好．利用ＴＰＤ和ＸＲＤ技术将催化剂引发温度与催化剂组成进行关联，并在７００℃下考察空速对催化性能的影响．随着空速的增加，ＣＨ４的转化率增加，７．０×１０５ｈ－１时达到最大，与此同时，ＣＯ的选择性一直增加．实验结果说明在非平衡体系中，ＣＯ和Ｈ２是由ＣＨ４直接转化而来，ＣＯ２是ＣＯ深度氧化的产物，在此基础上对催化剂过程的机理作了初步的探讨．     

A novel high-performance liquid chromatography-fluorescence analysis coupled with in situ degradation-derivatization technique for quantitation of organophosphorus thioester pesticide residues in tea

Analytical and Bioanalytical Chemistry - A novel high-performance liquid chromatography–fluorescence analysis in combination with in situ degradation–derivatization (ISD-D) technique...     

Directed Evolution of a Tryptophan 2,3-Dioxygenase for the Diastereoselective Monooxygenation of Tryptophans

Herein, we report an engineered enzyme that can monooxygenate unprotected tryptophan into the corresponding 3a-hydroxyhexahydropyrrolo[2,3-b]indole-2-carboxylic acid (HPIC) in a single, scalable step with excellent turnover number and diastereoselectivity. Taking advantage of directed evolution, we analyzed the stepwise oxygen-insertion mechanism of tryptophan 2,3-dioxygenases, and transformed tryptophan 2,3-dioxygenase from Xanthomonas campestris into a monooxygenase for oxidative cyclization of tryptophans. It was revealed that residue F51 is vital in determining the product ratio of HPIC to N′-formylkynurenine. Our reactions and purification procedures use no organic solvents, resulting in an eco-friendly method to prepare HPICs for further applications.     

微型计算机在脉冲磁场作用下的效应试验

 介绍了脉冲强磁场模拟器的工作原理, 将微型计算机置于脉冲磁场模拟器中，通过改变脉冲磁场的幅度和上升时间，研究脉冲磁场对微电子设备的干扰途径、干扰阈值与脉冲上升时间、脉冲宽度的关系。试验结果表明，微电子设备的连接电缆是脉冲磁场干扰引入的主要途径；简单的屏蔽措施对于脉冲磁场干扰有一定的抑制作用；脉冲磁场的时间变化率越大，对微电子设备的干扰作用越强。     

三种光电混合神经网络系统衍射误差的仿真研究

介绍了三种类型的光电混合神经网络系统,重点研究了衍射引起的误差对系统输出的影响。根据衍射、光学信息处理和神经网络理论,采用实验中的参量和输入数据,对衍射造成的输出误差做了仿真分析。分析表明,近场衍射造成较大的输出误差。近场与远场衍射综合作用时,误差因输入图像模式不同而差异较大;其中,当输入较小的简单图像时相对误差较大;而对实验中实际采用的复杂图像,相对误差较小。利用线性回归方法对输出数据做了校正,并分析了其可行性,校正后的数据误差降低一个量级。衍射误差对实验中识别率的影响可以控制在较小的范围内,识别率可以保持在97.7%以上。     

不同Ni前驱物对Ni催化剂甲烷部分氧化制合成气的影响

考察了由硝酸镍,醋酸镍和氯化镍为前驱物制备的催化剂（分别记为Ｎｉ－Ｎ,Ｎｉ－Ａｃ和Ｎｉ－Ｃｌ）对催化甲烷部分氧化反应的影响,并结合和ＴＧ等手段对催化剂进行了表征,结果表明,Ｎｉ－Ａｃ催化剂在６２５℃就能自引发甲烷部分氧化反应,而在Ｎｉ－Ｎ和Ｎｉ－Ｃｌ催化剂上,直到７５０℃甲烷部分氧化反应仍未能引发,三种催化剂上的反应结果表明,Ｎｉ－Ｎ和Ｎｉ－Ｃｌ的催化活性较低。９００℃下的高温反应结果表明,Ｎｉ－     

光电混合实现全双极WTA模型的新方法

提出了一种光电混合实现全双极Ｗｉｎｎｅｒ－Ｔａｋｅ－Ａｌｌ（ＷＴＡ）神经网络模型的新方法，并应用于ＷＴＡ模式识别系统，给出了实验结果。该方法能更有效地利用系统空间，取阈方便，能够进行非存储模式的判断和容错性识别，使系统具有更大的存储容量和寻址能力。     

全自动索氏萃取/气相色谱–质谱法测定电子电气产品中十溴二苯醚的不确定度评定

采用全自动索氏萃取仪/气相色谱–质谱法测定电子电气产品中的十溴二苯醚,对测量结果的不确定度进行评定,探讨影响测量准确度的关键因素.根据测定方法建立数学模型,分析整个测定过程中不确定度的来源,包括样品制备、标准溶液配制、标准工作曲线拟合以及测量重复性等因素引入的不确定度,计算各不确定度分量并合成得到相对扩展不确定度.当样...     

A competitive immunoassay for ultrasensitive detection of Hg in water,human serum and urine samples using immunochromatographic test based on surface-enhanced Raman scattering

An immunochromatographic test (ICT) strip was developed for ultrasensitive competitive immunoassay of Hg²⁺. This strategy was achieved by combining the easy-operation and rapidity of ICT with the high sensitivity of surface-enhanced Raman scattering (SERS). Monoclonal antibody (mAb) against Hg²⁺ and Raman active substance 4-mercaptobenzoic acid (MBA) dual labelled gold nanoparticles (GNPs) were prepared as an immunoprobe. The Raman scattering intensity of MBA on the test line of the ICT strip was measured for quantitative determination of Hg²⁺. The ICT was able to directly detect Hg²⁺ without complexing due to the specific recognition of the mAb with Hg²⁺. The IC₅₀ and limit of detection (LOD) of the assay for Hg²⁺ detection were 0.12 ng mL⁻¹ and 0.45 pg mL⁻¹, respectively. There was no cross-reactivity (CR) of the assay with other nineteen ions and the ICT strips could be kept for 5 weeks without loss of activity. The recoveries of the assay for water, human serum and urine samples spiked with Hg²⁺ were in range of 88.3–107.3% with the relative standard deviations (RSD) of 1.5–9.5% (n = 3). The proposed ICT was used for the detection of Hg²⁺ in urine samples collected from Occupational Disease Hospital and the results were confirmed by cold-vapor atomic fluorescence spectroscopy (CV-AFS). The assay exhibited high sensitivity, selectivity, stability, precision and accuracy, demonstrating a promising method for the detection of trace amount of Hg²⁺ in environmental water samples and biological serum and urine samples.