Mesoporous Carbon Nanofibers Embedded with MoS2 Nanocrystals for Extraordinary Li‐Ion Storage

MoS₂ nanocrystals embedded in mesoporous carbon nanofibers are synthesized through an electrospinning process followed by calcination. The resultant nanofibers are 100–150 nm in diameter and constructed from MoS₂ nanocrystals with a lateral diameter of around 7 nm with specific surface areas of 135.9 m² g^?1. The MoS₂@C nanofibers are treated at 450 °C in H₂ and comparison samples annealed at 800 °C in N₂. The heat treatments are designed to achieve good crystallinity and desired mesoporous microstructure, resulting in enhanced electrochemical performance. The small amount of oxygen in the nanofibers annealed in H₂ contributes to obtaining a lower internal resistance, and thus, improving the conductivity. The results show that the nanofibers obtained at 450 °C in H₂ deliver an extraordinary capacity of 1022 mA h g^?1 and improved cyclic stability, with only 2.3 % capacity loss after 165 cycles at a current density of 100 mA g^?1, as well as an outstanding rate capability. The greatly improved kinetics and cycling stability of the mesoporous MoS₂@C nanofibers can be attributed to the crosslinked conductive carbon nanofibers, the large specific surface area, the good crystallinity of MoS₂, and the robust mesoporous microstructure. The resulting nanofiber electrodes, with short mass‐ and charge‐transport pathways, improved electrical conductivity, and large contact area exposed to electrolyte, permitting fast diffusional flux of Li ions, explains the improved kinetics of the interfacial charge‐transfer reaction and the diffusivity of the MoS₂@C mesoporous nanofibers. It is believed that the integration of MoS₂ nanocrystals and mesoporous carbon nanofibers may have a synergistic effect, giving a promising anode, and widening the applicability range into high performance and mass production in the Li‐ion battery market.     

多个时间常数线性体系暂态响应方程参数的代数求解法

从线性条件出发,推导了含n个时间常数体系恒电位阶跃时暂态响应方程,并提出一套解析形为ΔI=ΔI_∞+sum from i=1 to n k_iexp(-t/τ_i)暂态方程各未知参数的代数解法。该方法可对未知体系时间常数个数进行判定,比起一般曲线拟合更加快速简便,且抗干扰能力较强。     

Ferrocene-based anion receptor bearing amide and triazolium donor groups

A novel ferrocene-based anion receptor bearing amide and triazolium donor groups and its anion complexation have been reported. We found that it shows marked electrochemical selectivity to F(-), followed by AcO(-) > Cl(-) > Br(-) > I(-), which is in accordance with (1)H NMR titration results.     

He-Ne激光诱变选育高产白藜芦醇细胞系

以葡萄皮脱分化组织为最初材料,用根癌农杆菌702菌株感染,通过纸电泳证明胭脂碱合成醇基因的存在,并在无激素培养基上培养5～6代以上,将此组织(MS)作为本次实验的研究对象.用He-Ne激光辐照,对MS进行诱变处理,通过继代选育,得到优良细胞系T₁₂,其特点是:生长迅速,生长周期比对照组(CK)缩短10～15天;生长曲线的稳定期明显延长,白藜芦醇平均产量比MS组提高40%.通过稳定性实验证明T₁₂组遗传性状是可靠的.     

The 23 K superconducting phase YPd2B2C

We have carried out a systematic structural, electric, and magnetic study on Y---Pd---B---C samples with different compositions with emphasis on the as-cast and annealed YPd₅B₃C_0.3 which was first reported to superconduct at 23 K by Cava et al. We found that the tetragonal body-centered YPd₂B₂C with lattice parameters a=3.71 Å and c=10.81 Å is the phase responsible for the 23 K superconductivity and that YPd₂B₂C is metastable, which is consistent with the suggestion made by Cava et al. [1]: it is not stable at high temperatures nor stabilizable by Ni doping, although its isostructural compound, YNi₂B₂C, exists. Two new phases with Y:Pd ratios of 1:7 and 2:3, respectively, have also bee detected.     

Regularization of Point Vortices Pairs for the Euler Equation in Dimension Two

In this paper, we construct stationary classical solutions of the incompressible Euler equation approximating singular stationary solutions of this equation. This procedure is carried out by constructing solutions to the following elliptic problem $$\left\{\begin{array}{l@{\quad}l} -\varepsilon^2 \Delta u = \sum\limits_{i=1}^m \chi_{\Omega_i^{+}} \left(u - q - \frac{\kappa_i^{+}}{2\pi} {\rm ln} \frac{1}{\varepsilon}\right)_+^p\\ \quad - \sum_{j=1}^n \chi_{\Omega_j^{-}} \left(q - \frac{\kappa_j^{-}}{2\pi} {\rm \ln} \frac{1}{\varepsilon} - u\right)_+^p , \quad \quad x \in \Omega,\\ u = 0, \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad x \in \partial \Omega,\end{array}\right.$$ where p > 1, ${\Omega \subset \mathbb{R}^2}$ is a bounded domain, ${\Omega_i^{+}}$ and ${\Omega_j^{-}}$ are mutually disjoint subdomains of Ω and ${\chi_{\Omega_i^{+}} ({\rm resp}.\; \chi_{\Omega_j^{-}})}$ are characteristic functions of ${\Omega_i^{+}({\rm resp}. \;\Omega_j^{-}})$ , q is a harmonic function. We show that if Ω is a simply-connected smooth domain, then for any given C ¹-stable critical point of Kirchhoff–Routh function ${\mathcal{W}\;(x_1^{+},\ldots, x_m^{+}, x_1^{-}, \ldots, x_n^{-})}$ with ${\kappa^{+}_i > 0\,(i = 1,\ldots, m)}$ and ${\kappa^{-}_j > 0\,(j = 1,\ldots,n)}$ , there is a stationary classical solution approximating stationary m + n points vortex solution of incompressible Euler equations with total vorticity ${\sum_{i=1}^m \kappa^{+}_i -\sum_{j=1}^n \kappa_j^{-}}$ . The case that n = 0 can be dealt with in the same way as well by taking each ${\Omega_j^{-}}$ as an empty set and set ${\chi_{\Omega_j^{-}} \equiv 0,\,\kappa^{-}_j=0}$ .     

Valence bond theoretical study for chemical reactivity

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C2轴不对称联芳香化合物的合成研究进展

概述了近年来Ｃ２轴不对称联芳香化合物的合成与不对称偶联的研究进展。