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91.
正交试验选择组织电极的最佳分析条件 总被引:1,自引:0,他引:1
本文用正交试验法对花椰菜组织L-抗坏血酸传感器和香蕉组织儿茶酚类化合物传感器的分析条件进行了优化,通过与单因子分析方法及4种儿茶酚类化合物之间正交试验结果的比较,说明用正交试验选择组织传感器的最佳分析条件,在少量的试验次数内,得到较多的分析实验信息,是一种较理想的试验方法。 相似文献
92.
A home-made high sensitive photoacoustic transducer was used to determine the photoacoustic signal in a solution. The photoacoustic spectra of Ho in different solvents were measured and comparedwith its absorption spectrum. The affection factors of photoacousticsensitivity are discussed. The trivalent rare earth ions Ho3+ and Nd3+in an aqueous acetonitrile solution were determined. The detection limit is 5×10-8 mol/L for Ho3+ and 1.0 ×10-7 mol/L for Nd3+, and corresponds to the absorbance of 1.5×10 and 6.3×10-7.respectively. 相似文献
93.
A series of N-aryl β-bromodifluoromethyl β-enaminoketones were regioselectively synthesized in good yield by the reaction of N-aryl bromodifluoroacetimidoyl chlorides with methyl ketones. β-Bromodifluoromethyl β-enaminoketones smoothly cyclized to give a novel class of cyclic (2,2-difluoro-5-phenyl-furan-3-ylidene)-aryl-amines under basic condition. An intramolecular halophilic substitution mechanism was proposed. 相似文献
94.
测量反应体系压力变化的装置已有报道,但本文装置具有操作方便、记数准确等优点。 1 实 验 1.1 实验原理及试剂 详见文献。 1.2 装置及仪器 本文的无汞动力学测量装置用于乙炔氢氯化均相催化反应力学研究,其组装图如图1所示。 相似文献
95.
Gallium(III) triflate catalyzed the rearrangement of 2-substituted vinylepoxides into beta,gamma-unsaturated carbonyl compounds with high regio- and chemoselectivity (>97/3) in low catalyst loading (1-5 mol %). The alkyl-substituted trimethylsilylvinyl epoxides gave beta,gamma-unsaturated ketone, but aryl-substituted vinylepoxides gave the aldehydes instead. 相似文献
96.
The highly stereoselective intramolecular metal carbenoid insertion reaction of sulfinimine-derived delta-amino alpha-diazoesters is used to prepare cis-5-tert-butylproline. A concerted or nearly concerted metal carbenoid N-H insertion reaction mechanism is proposed. 相似文献
97.
A facile and environment friendly approach was developed to graft vinyl acetate (VAc) onto plastic articles in an aqueous solution using tert‐butyl alcohol (TBA) as a compatiblizer and benzoyl peroxide (BPO) as an initiator. In a novel setup, excessive monomer suspended in a water phase, VAc could be conveniently grafted on the model substrate of low‐density polyethylene (LDPE) film and the graft percentage (GP) could be developed up to 7.3%. Reaction temperature could increase GP significantly, while adding monomer over a critical volume did not influence GP. By adding some paradioxybenzene, i.e. 0.06–0.08% in VAc phase, homopolymer PVAc could be avoided practically, while graft polymerization proceeded favorably in aqueous solutions. It was proved by attenuated total reflection‐infrared (ATR‐IR) spectroscopy that grafted VAc was located mainly at the surface of the LDPE film and hydrophilic nature of both grafted and alcoholyzed films were improved via contact angle measurements. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
98.
示差脉冲伏安法测定黄酒中的酪氨酸 总被引:3,自引:0,他引:3
本文研究了硼砂介质中镍与酪氨酸络合物的示差脉冲吸附伏安特性,实验了仪器参数对示差脉冲阴极吸附伏安法的影响,在最佳条件下络合物峰电流与酪氨酸浓度在2.0×10^-7~4.0×10^-5mol.L^-1范围内有线性关系,并以此法测定了黄酒中酪氨酸的含量。 相似文献
99.
本文报道以青蒿酸(2)为原料合成了一些含羟基的青蒿倍半萜内酯差向异构体9与10、11与12、13与14。其中9已从青蒿中分离到。 相似文献
100.
THz spectroscopic investigation of 2,4-dinitrotoluene 总被引:5,自引:0,他引:5
Yunqing Chen Haibo Liu Yanqing Deng Dunja Schauki Michael J. Fitch Robert Osiander Caroline Dodson James B. Spicer Michael Shur X.-C. Zhang 《Chemical physics letters》2004,400(4-6):357-361
We have investigated the terahertz (THz) spectrum of 2,4-DNT by using Fourier transform infrared spectroscopy in the 0.2–19.5 THz region. We also examined low-frequency intermolecular or phonon modes between 0.2 and 1.8 THz via THz time-domain spectroscopy. The extracted absorption coefficient and refractive index of an intermolecular band at 1.08 THz are 110 cm−1 and 1.67, respectively. Density functional theory (DFT) was applied to obtain structure and vibrational frequencies of 2,4-DNT. The calculated results are in agreement with the experimental data. Observed vibrational frequencies have been interpreted using DFT. Two intermolecular or phonon modes were identified at 1.08 and 2.52 THz. 相似文献