Temperature dependence of protein backbone motion from carbonyl 13C and amide 15N NMR relaxation

The NMR spin-lattice relaxation rate (R1) and the rotating-frame spin-lattice relaxation rate (R1rho) of amide 15N and carbonyl 13C (13C') of the uniformly 13C- and 15N-labeled ubiquitin were measured at different temperatures and field strengths to investigate the temperature dependence of overall rotational diffusion and local backbone motion. Correlation between the order parameter of the N-H vector, SNH2, and that of the carbonyl carbon, S2C', was investigated. The effective S2C' was estimated from the direct fit of the experimental relaxation rates and from the slope of 2R2-R1 vs. B2 using Lipari-Szabo formalism. The average SNH2 decreased by 5.9%, while the average S2C' decreased by 4.6% from 15 to 47 degrees C. At the extreme low and high temperatures the difference in the temperature dependence of the order parameters vanishes. At the intermediate temperatures they do not change by the same amount but they follow the same trend. On the same peptide plane along the protein sequence, S2C' and SNH2 are highly correlated. The results suggest that fast local motion experienced at the site of the N-H vector and carbonyl nucleus is more complicated than previously thought and it cannot be easily described by one single type of motion in a broad range of temperature.     

Multipeak fitting analysis of Raman spectra on DLCH film

The hydrogenated diamond‐like carbon (DLCH) film with 1‐µm thickness is deposited by direct hydrocarbon gas ion beam method on silicon wafer and annealed at 400 °C. Detailed Raman spectra feature are fitted from nine sets of different peak fitting functions, including Gaussian, Lorentzian and Breit‐Wigner‐Fano (BWF) functions. These fitting results obtained from a two‐peak combination show some specific variances on the G peak position, FWHM_G and I_D/I_G ratio for as‐deposited and as‐annealed DLCH films. The most popular two‐peak fitting method with full Gaussian function tends to exhibit a higher ratio of the G peak position shift and higher I_D/I_G ratio than others fitting methods, the drastic difference among the most popular G (G) & G (D) and B (G) & L (D) schemes also have brought out in I_D/I_G ratio. However, for a more complex four‐peak Gaussian function fitting Raman spectra, the I_D/I_G ratio is close to that of a two‐peak fitting function with a mixture functions of BWF (G) and L (D). Furthermore, a series of systematic peak fitting procedures and comparisons of Raman spectra have been discussed in this study. Copyright © 2009 John Wiley & Sons, Ltd.     

High-efficiency,high-speed VCSELs for optical interconnects

High-efficiency, high-speed, tapered-oxide-apertured vertical-cavity surface-emitting lasers (VCSELs) emitting at 980 nm have been demonstrated. By carefully engineering the tapered oxide aperture, the mode volume can be greatly reduced without adding much optical scattering loss for the device sizes of interest. Consequently, these devices can achieve higher bandwidth at lower current and power dissipation. In addition, the parasitics are reduced by implementing deep oxidation layers and an improved p-doping scheme in the top mirror. Our devices show modulation bandwidth exceeding 20 GHz, a record for 980 nm VCSELs. Moreover, 35 Gb/s operation has been achieved at only 10 mW power dissipation. This corresponds to a data-rate/power-dissipation ratio of 3.5 Gbps/mW. Most importantly, our device structure is compatible with existing manufacturing processes and can be easily manufactured in large volume making them attractive for optical interconnects.     

Facile Construction of 3D Reduced Graphene Oxide Wrapped Ni3S2 Nanoparticles on Ni Foam for High‐Performance Asymmetric Supercapacitor Electrodes

3D reduced graphene oxide (rGO)‐wrapped Ni₃S₂ nanoparticles on Ni foam with porous structure is successfully synthesized via a facile one‐step solvothermal method. This unique structure and the positive synergistic effect between Ni₃S₂ nanoparticles and graphene can greatly improve the electrochemical performance of the NF@rGO/Ni₃S₂ composite. Detailed electrochemical measurements show that the NF@rGO/Ni₃S₂ composite exhibits excellent supercapacitor performance with a high specific capacitance of 4048 mF cm^?2 (816.8 F g^?1) at a current density of 5 mA cm^?2 (0.98 A g^?1), as well as long cycling ability (93.8% capacitance retention after 6000 cycles at a current density of 25 mA cm^?2). A novel aqueous asymmetric supercapacitor is designed using the NF@rGO/Ni₃S₂ composite as positive electrode and nitrogen‐doped graphene as negative electrode. The assembled device displays an energy density of 32.6 W h kg^?1 at a power density of 399.8 W kg^?1, and maintains 16.7 W h kg^?1 at 8000.2 W kg^?1. This outstanding performance promotes the as‐prepared NF@rGO/Ni₃S₂ composite to be ideal electrode materials for supercapacitors.     

First-principles calculations for electronic and optical properties of the zinc-blende structured BeS compound under pressure

The electronic and the optical properties of the cubic zinc-blende (ZB) BeS under high pressure have been investigated by using \it ab initio plane-wave pseudopotential density functional theory method in the generalised gradient approximation (GGA) for exchange-correlation interaction. The electronic band structure and the pressure dependence of the total and partial densities of state under pressure are successfully described. Our calculations show that the ZB BeS has large and indirect band gaps associated with (Γ → X) transitions in ambient conditions. The results obtained are consistent with the experimental data available and other calculations. The optical properties, including dielectric function, energy-loss function, complex refractive index, reflection and absorption spectra, are investigated and analysed at different external pressures. The results suggest that the optical absorption appears mostly in the ultra-violet region and the curve of refractive index shift toward high energies (blue shift) with pressure increasing.     

射频光纤链路γ射线辐致损伤特性实验研究

由于空间环境中宇宙辐射无处不在,工作在空间环境的光纤系统必须考虑辐致损伤特性。建立了10GHz的射频光纤链路传输系统,分别采用单模光纤和保偏光纤作为传输媒质。利用60 Co`γ射线源,在剂量率1rad/s总剂量50krad下,对射频光纤链路进行辐照实验,对两种系统做对比分析。实验结果表明,单模光纤链路的辐致损耗绝对值较大,保偏光纤链路的辐致损耗绝对值较小;单模光纤的幂律模型指数较保偏光纤大,即同样的辐照剂量,单模光纤受影响程度大。在辐照起主要影响因素的阶段,单模光纤延时差受辐照影响程度较保偏光纤稍小。辐致损耗和辐致延时差对光纤长度都有线性累加作用。从整体水平看,50krad的辐射总剂量对两种光纤造成的损伤并不大,传输的信号仍在可用的范围之内。     

Indication of reactor ν(e) disappearance in the Double Chooz experiment

The Double Chooz experiment presents an indication of reactor electron antineutrino disappearance consistent with neutrino oscillations. An observed-to-predicted ratio of events of 0.944±0.016(stat)±0.040(syst) was obtained in 101 days of running at the Chooz nuclear power plant in France, with two 4.25 GW(th) reactors. The results were obtained from a single 10 m(3) fiducial volume detector located 1050 m from the two reactor cores. The reactor antineutrino flux prediction used the Bugey4 flux measurement after correction for differences in core composition. The deficit can be interpreted as an indication of a nonzero value of the still unmeasured neutrino mixing parameter sin(2)2θ(13). Analyzing both the rate of the prompt positrons and their energy spectrum, we find sin(2)2θ(13)=0.086±0.041(stat)±0.030(syst), or, at 90% C.L., 0.017相似文献   

Fractional Fourier-domain random encoding and pixel scrambling technique for double image encryption

A double image encryption method is proposed using fractional Fourier-domain random encoding and pixel scrambling technique. One of the two original images is encoded into the phase function of a synthesized input signal after being scrambled, and the other original image encoded into its amplitude. The phase function serves as phase mask in the input domain, and the synthesized input signal is then encrypted into stationary white noise by utilizing random phase encoding in fractional Fourier domain. The two original images can be retrieved without cross-talk by using the correct keys with fractional orders, the random phase mask and the pixel scrambling operator. Numerical simulations and security analysis have been done to prove the validity and the security of the proposed encryption method.     

Multi-stacked organic light-emitting diodes using zinc oxide nanoparticle interfacial layers

Stacked organic light-emitting diodes (SOLEDs) with 30-nm nanoparticle (NP) interfacial layers were investigated. Zinc oxide (ZnO) was used as an interfacial layer between two green polymer (GP) layers. SOLEDs with NP interfacial layers had higher device efficiency than did a single-unit device due to the high probability of exciton recombination that originated from the Auger electron-assisted energy up-conversion process. Although the current density and luminance of SOLEDs with ZnO NP interfacial layers were smaller than those of the reference device, the efficiency was doubled because of the big band alignment difference and the large band gap between GP and ZnO NP interfacial layers, which induced more radiative-exciton recombination.     

对23P2介子九重态中同位旋标量成员的质量分析

基于实验上已经确认的基态张量介子九重态的安排和现有的实验数据,利用从雷吉轨迹理论和质量混合矩阵推导出的介子质量关系,对张量介子第一径向激发态的安排做了分析预测.根据得到的结果,可以推测f₂（1810）和f₂（2010）可能作为张量介子第一径向激发态的候选者.同时给出了f₂（1810）和f₂（2010）作为张量介子第一径向激发态时的衰变信息.这些结论对激发态张量介子,特别是其中的同位旋标量态的安排将提供帮助.