天然有机化合物NOESY谱的全弛豫矩阵分析

本文用定量处理2D NOE实验数据最精确的方法-全弛豫矩阵分析法定量分析了天然有机化合物显脉香茶菜素的相敏NOESY谱,计算出显脉香茶菜素分子中各质子间的交叉弛豫速率,根据1/r_tf⁶∝σ_tf计算出相应的质子间距离,结果表明:用全弛豫矩阵分析法计算出的质子间距与分子力学计算以及用单晶X-射线衍射法测得的质子间距离基本一致,为用核磁共振方法确定分子在溶液中的三维空间结构提供了可靠的结构参数。     

Balance of mass, momentum, and energy in splintering central collisions for 40Ar up to 115 MeV /Nucleon

For central collisions of (17-115)A MeV 40Ar+Cu, Ag, Au, an overall balance is determined for the average mass, energy, and longitudinal momentum. Light charged particles and fragments are separated into forward-focused and isotropic components in the frame of the heaviest fragment. Energy removal by the isotropic component reaches 1-2 GeV. For such high deposition energies, statistical multifragmentation models predict much more extensive nuclear disassembly than is observed.     

红光皂甙元及其两个甾体皂甙的NMR研究

从番麻(Agave americana L.)发酵的叶汁中分离得到红光皂甙元(hongguanggenin)、Cantalasaponin-1及一个新的甾体皂苷Agameroside-1. 运用2D NMR技术,包括DQF ¹H-¹H COS Y,HSQC,HMBC,HSQC-TOCSY,ROESY等技术,首次全归属了3个甾体化合物的氢和碳的化学位移,并总结了红光皂甙元的甙化位移效应,从而修正了文献中部分碳信号归属以及甙元的甙化位移效应.     

ZrO2在Rh/γ-Al2O3催化剂中对NO催化还原反应的作用

测定了含ＺｒＯ２的Ｒｈ／γ－Ａｌ２Ｏ３催化剂上ＮＯ＋Ｃ２Ｈ４和ＮＯ＋Ｃ２Ｈ４＋Ｏ２的反应活恬性,并应用ＴＰＲ、ＸＲＤ、ＢＥＴ比表面等表征了ＺｒＯ２的加入方式和晶型对Ｒｈ／γ／Ａｌ２Ｏ３催化剂活性和结构的影响。结果表明,ＺｒＯ２的加入一定程度也抑制了Ｒｈ＾３＋与γ－Ａｌ２Ｏ３之间的相互作用和Ａｌ２Ｏ３的相变,提高了催化剂的热稳定性,明显提高了８５０℃老化样品的ＮＯ＋Ｃ２Ｈ４反应活性。对于ＮＯ＋Ｃ２     

GaAs/SiO2纳米晶镶嵌薄膜的拉曼光谱与吸收光谱研究

采用射频磁控共溅射与高真空退火相结合的方法,分别在单晶硅片和光学石英玻璃片上制备了ＧａＡｓ／ＳｉＯ２纳米晶镶嵌薄膜样品。激光拉曼光谱的测量结果表明,退火态样品（４００℃,６０ｍｉｎ）的拉曼光谱特征峰呈现宽化和红移,红移量为９．５ｃｍ＾－１,对应薄膜中ＧａＡｓ纳米晶粒平均粒径约为３ｎｍ。样品的室浊吸收光谱测量结果表明,由于受量子限域效应的主导作用,与ＧａＡｓ块状单晶相比,样品光学吸收边呈现出明显的蓝     

可用于钕玻璃激光系统的自锁模飞秒激光器

描述了用激光二极管抽运的全固体Ｎｄ：ＬＭＡ自锁模飞秒激光振荡器,通过理论计算和分析,在其腔内加入－非线性系数较大的介质,同时对腔结构进行优化设计,实现了自锁模。它直接产生波长为１０５４ｎｍ的激光,输出激光脉冲的宽度达６１０ｆｓ,光谱宽度为２．１ｎｍ,输出功率达１５ｍＷ。     

双轴晶体光学参量放大的研究

介绍了新近提出的光学啁啾脉冲参量放大技术,并以高增益、宽谱带的双轴非线性晶体LBO为例,研究了抽运光和信号光的相位匹配的关系、增益、增益带宽、匹配角的选择,以及增益随晶体长度变化的趋势和双曲正割和高斯脉冲输入非线性晶体前后变化的情况。     

Kantorovich-type inequalities and the measures of inefficiency of the glse

In this paper we introduce some Kantorovich inequalities for the Euclidean norm of a matrix, that is, the upper bounds to (X'B ^–1 X) ^–1 X'B ^–1 AB ^–1 X(X'B ^–1X)^–1 X' BX(X'AX) ^–1 X'CX² are given, where A²=trace (A'A). In terms of these inequalities the upper bounds to the three measures of inefficiency of the generalized least squares estimator (GLSE) in general Gauss-Markov models are also established.Project supported partially by the Third World Academy of Sciences under contract TWASRG 87-46 and by the National Natural Science Foundation.     

带一类时滞项的生物种群扩散模型的行波解

本文利用Schauder不动点理论证明了微分积分方程组行波解u（x，t）＝U（z）,w（x,t）＝W（z）,z＝xγ－ct的存在性．这个方程组描述了一类在植物上繁殖，且靠飞行在空中扩散的生物种群扩散过程．特别当时滞项，中积分核K（t）（反映种群繁殖模式）属于L1（0，∞）时，本文得到极限值W（－∞）（表示最终植物上种群密度）小于M．这个结论较符合生物实际．     

Renormalization of a self-avoiding Brownian motion in two dimensions

We obtain a measure defined on the space of continuous sample paths, which describes a weakly self-avoiding Brownian motion in a 2-dimensional Euclidean space. Our method is also applicable to a Brownian motion with the Dirichlet boundary conditions in a 2-dimensional domain. For the new measures, an inequality of Simon-Lieb type is also obtained.