全文获取类型
收费全文 | 59257篇 |
免费 | 9781篇 |
国内免费 | 6762篇 |
专业分类
化学 | 42576篇 |
晶体学 | 775篇 |
力学 | 3436篇 |
综合类 | 403篇 |
数学 | 6773篇 |
物理学 | 21837篇 |
出版年
2024年 | 143篇 |
2023年 | 1213篇 |
2022年 | 1998篇 |
2021年 | 2281篇 |
2020年 | 2609篇 |
2019年 | 2484篇 |
2018年 | 2026篇 |
2017年 | 2023篇 |
2016年 | 2853篇 |
2015年 | 2892篇 |
2014年 | 3425篇 |
2013年 | 4411篇 |
2012年 | 5400篇 |
2011年 | 5498篇 |
2010年 | 3835篇 |
2009年 | 3550篇 |
2008年 | 3861篇 |
2007年 | 3369篇 |
2006年 | 3037篇 |
2005年 | 2598篇 |
2004年 | 1981篇 |
2003年 | 1602篇 |
2002年 | 1525篇 |
2001年 | 1190篇 |
2000年 | 1053篇 |
1999年 | 1175篇 |
1998年 | 952篇 |
1997年 | 904篇 |
1996年 | 893篇 |
1995年 | 826篇 |
1994年 | 705篇 |
1993年 | 593篇 |
1992年 | 486篇 |
1991年 | 435篇 |
1990年 | 374篇 |
1989年 | 290篇 |
1988年 | 205篇 |
1987年 | 185篇 |
1986年 | 184篇 |
1985年 | 173篇 |
1984年 | 104篇 |
1983年 | 106篇 |
1982年 | 63篇 |
1981年 | 49篇 |
1980年 | 33篇 |
1979年 | 20篇 |
1976年 | 20篇 |
1975年 | 21篇 |
1972年 | 19篇 |
1957年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
Yang Dai Faquan Li Xuewu Cheng Zhiling Jiang Shunsheng Gong 《Optics & Laser Technology》2007,39(7):1374-1379
In Shack–Hartmann wavefront sensor (SHWS), the behavior of the irradiance pattern produced by the micro-lens array is important for an accurate centroid estimation. In this paper, the behavior of a micro-lens array in SHWS is analyzed using Fourier optics, and reveals that in addition to the main, expected spots, secondary spots with smaller intensities also appeared as a result of diffraction by the small dimensions of the micro-lens and interference from the different micro-lenses. This result is confirmed by comparing with a irradiance pattern taken from an actual SHWS. The additional error in centroid estimation caused by these secondary spots is discussed and relationship to the parameters of the micro-lens of SHWS is analyzed. 相似文献
132.
133.
Haitao Qian Edith Mathiowitz 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5899-5915
We succeeded in developing the acyl chloride‐facilitated condensation polymerization method for the synthesis of new poly(anhydride‐ester)s with aromatic side groups, which cannot be polymerized by the classic melt condensation polymerization method. Using chlorinated and acylated carboxylic acids as the intermediates, the polymerization was carried out at low temperatures of 120 or 135 °C to yield pure poly(anhydride‐ester)s of molecular weights as high as 1.55 × 105 with minimal side‐reactions. A homogeneous route of preparation was developed and optimized, using butyric anhydride as the acylating reagent and oxalyl chloride as the chlorinating reagent. A comparison of the mechanisms of the classic method and the new method indicates that the effects of transacylation—cyclization and oligomer formation—were greatly reduced due to the high reactivity of carboxylic acid chloride and the steric effect of bulky acyl groups. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5899–5915, 2007 相似文献
134.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007 相似文献
135.
Gujie Qian S. Baccaro M. Falconieri Jiafang Bei A. Cecilia Guorong Chen 《Journal of Non》2008,354(40-41):4626-4629
Glasses in SiO2–ZnO–BaO system with the different ZnO/BaO ratio were studied. In some cases, BaF2 was introduced to substitute for BaO on the equal base. Photoluminescent spectra showed that ZnO in glass matrices behaved somewhat differently from ZnO crystals. Especially, the introduction of fluorine ions led to dramatic shift of UV emission band of glasses closer to that of ZnO crystals. Raman spectral analysis provided consistent results. In particular, Raman bands in the high frequency region are sensitive to effects of different ZnO/BaO or BaF2/BaO ratio on structure of glasses. 相似文献
136.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
137.
138.
Chin‐Ping Yang Ruei‐Shin Chen Kuei‐Hung Chen 《Journal of polymer science. Part A, Polymer chemistry》2003,41(7):922-938
To investigate the position and amount of the CF3 group affecting the coloration of polyimides (PIs), we prepared 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]hexafluoropropane ( 2 ) with four CF3 groups with 2‐chloro‐5‐nitrobenzotrifluoride and 2,2‐bis(4‐hydroxyphenol)hexafluoropropane. A series of soluble and light‐colored fluorinated PIs ( 5 ) were synthesized from 2 and various aromatic dianhydrides ( 3a – 3f ). 5a – 5f had inherent viscosities ranging from 0.80 to 1.19 dL/g and were soluble in amide polar solvents and even in less polar solvents. The glass‐transition temperatures of 5 were 221–265 °C, and the 10% weight‐loss temperatures were above 493 °C. Their films had cutoff wavelengths between 343 and 390 nm, b* values (a yellowness index) ranging from 5 to 41, dielectric constants of 2.68–3.01 (1 MHz), and moisture absorptions of 0.03–0.29 wt %. In a comparison of the PI series 6 – 8 based on 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane, 2,2‐bis[4‐(4‐amino‐2‐trifluoromethylphenoxy)phenyl]propane, and 2,2‐bis[4‐(4‐aminophenoxy)phenyl]propane, we found that the CF3 group close to the imide group was more effective in lowering the color; this means that CF3 of 5 , 7 , and 8f was more effective than that of 6c . The color intensity of the four PI series was lowered in the following order: 5 > 7 > 6 > 8 . The PI 5f , synthesized from diamine 2 and 4,4′‐hexafluoroisopropylidenediphthalic anhydride, had six CF3 groups in a repeated segment, so it exhibited the lightest color among the four series. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 922–938, 2003 相似文献
139.
双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响. 相似文献
140.
Z.J. Yang T.H. Johansen H. Bratsberg G. Helgesen A.T. Skjeltorp 《Physica C: Superconductivity and its Applications》1989,160(5-6):461-465
Based on a dipole-dipole interaction model, we discuss the levitation force and related vibration problems to understand the effects of flux pinning in type-II superconductors, and the applications of levitation in superconducting systems. 相似文献