Mn（Ⅱ）,Co（Ⅱ）与HSA相互作用的荧光光谱研究

用荧光光谱法研究了生理ｐＨ和等离子点（ｐＨ＝５．３０）时Ｍｎ（Ⅱ）、Ｃｏ（Ⅱ）与ＨＳＡ的相互作用。根据Ｆｏｒｓｔｅ非辐射能量转移理论,得到了不同ｐＨ时Ｍｎ（Ⅱ）、Ｃｏ（Ⅱ）在ＨＳＡ中的第一强结合位置与Ｔｒｐ－２１４残基间的距离。这一结果远大于文献报道值,根据Ｍｎ（Ⅱ）、Ｃｏ（Ⅱ）在ＨＳＡ中的结合部位及ＨＳＡ的畴结构对这一显著差异进行了讨论。     

牛津型斯特林制冷机的失效分析方法

分析了牛津型斯特林制冷机的主要失效机理、参数表征及探测方法,提出了制冷机的失效分析方法和程序。该方法将用于80K/2W制冷机加速寿命试验后的失效分析,为确认其失效模式和机理提供依据。     

Engineering Plasmonic Environments for 2D Materials and 2D-Based Photodetectors

Two-dimensional layered materials are considered ideal platforms to study novel small-scale optoelectronic devices due to their unique electronic structures and fantastic physical properties. However, it is urgent to further improve the light–matter interaction in these materials because their light absorption efficiency is limited by the atomically thin thickness. One of the promising approaches is to engineer the plasmonic environment around 2D materials for modulating light–matter interaction in 2D materials. This method greatly benefits from the advances in the development of nanofabrication and out-plane van der Waals interaction of 2D materials. In this paper, we review a series of recent works on 2D materials integrated with plasmonic environments, including the plasmonic-enhanced photoluminescence quantum yield, strong coupling between plasmons and excitons, nonlinear optics in plasmonic nanocavities, manipulation of chiral optical signals in hybrid nanostructures, and the improvement of the performance of optoelectronic devices based on composite systems.     

基于非齐次复合Poisson过程的正交异性钢桥面板细节疲劳裂纹随机扩展研究

传统的正交异性钢桥面板疲劳损伤评估常采用确定性和可靠性分析方法,忽略了疲劳裂纹扩展的随机性影响,针对这一问题,提出钢桥面板细节疲劳随机扩展分析方法。本文以南溪长江大桥为工程背景,基于长期车辆荷载监测数据,建立了车辆荷载非齐次复合Poisson过程模型。建立钢桥面板有限元模型,采用瞬态分析方法将随机车辆荷载转化成细节疲劳应力,基于线弹性断裂力学理论推导U肋-顶板焊接细节疲劳裂纹扩展时变微分方程,实现宏观关系式疲劳应力幅次数-疲劳损伤至微观表达式应力时间序列-疲劳损伤转换,讨论了车载次序及超载对疲劳裂纹扩展的影响。研究结果表明,非齐次复合泊松过程模型能够较好描述随机车流运营状态,车辆荷载的次序对疲劳裂纹扩展速率的影响不可忽略,重车排序靠前时能够促使疲劳裂纹扩展增速,南溪长江大桥细节点的车辆超载迟滞效应修正系数取值0.804。     

大空间三向组合平板网架研究

利用中心节点、交叉梁、三角形拉杆和空心板所构成承力单元的组合以及内部支承柱的自由布置,本文提出了一种新型大空间三向组合平板网架结构。相关的TDGS分析系统针对原型试验取得了较好的模拟效果。通过引入柱的局部影响区域这一全新概念,系统总结了加入内部支承柱前后网架结构的内力和变形规律,进而为进一步的工程应用提供了可行性建议。     

Monoterpenoid Indole Alkaloids with Promoting Neurite Growth from Tabernaemontana divaricata

Main observation and conclusion Phytochemical investigations on Tabernaemontana divaricata led to the isolation of seven undescribed monoterpenoid indole alka-l...     

Guajamers A-I,Rearranged Polycyclic Phloroglucinol Meroterpenoids from Psidium guajava Leaves and Their Antibacterial Activity

Main observation and conclusion Eight new polycyclic phloroglucinol meroterpenoids guajamers A-H (1-8),a methylated benzoylphloroglucinol meroterpenoid guajamer...     

Base-Promoted Formylation and N-Difluoromethylation of Azaindoles with Ethyl Bromodifluoroacetate as a Carbon Source

Main observation and conclusion We reported for the first time that ethyl bromodifluoroacetate directly reacts with azaindole without transition metal catalysis...     

一种油田原油含水率的近红外光谱检测与分析方法

石油作为重要战略资源,对其组分进行实时分析检测在石油化工领域有着重要意义.随着石油资源的不断开发,在已长时间开采油井的生产过程中以及新油井开采前,需要对井下原油组分进行分析检测,以判定开采的必要性.原油组分实时检测,在原油开采、生产、储运以及销售过程中都起着关键的作用,针对传统检测方法存在精度低、效率低等问题,近年来在...     

高温吸热管内超临界CO2传热特性的数值模拟

研究超临界CO2在高温吸热管内的传热特性是将其应用于聚光太阳能热发电技术中的基础.本文对此进行了数值模拟研究,分析了流体温度、流动方向、系统压力、质量流率和热流密度对对流传热系数和Nu数的影响.结果表明:高温区(800—1050 K)的对流传热系数和Nu数受流动方向和系统压力的影响均很小,但都随着质量流率的增大以及热流...