成组设计在高功率激光装置中的应用

在高功率激光装置研制中首次引入成组技术概念,并以空间滤波器为例论证了在高功率激光装置的器件研制过程中实施成组设计的必要性和可行性最后讨论了计算机辅助成组设计系统(GTCAD)的组成和在高功率激光装置中具体实施过程.     

氮烃混合工质中氖的作用机理

氮烃混合工质由于有较大的制冷量,在节流制冷器中已广泛应用,然而它的制冷温度却较高,在使用中受到一定的限制。文中通过对在氮烃混合工质中加入氖的分析,揭示了氖降低混合工质制冷温度的机理     

导体栅的静电屏蔽作用

采用保角变换的方法 ,计算了导体栅作屏蔽罩时的场强分布 ,所得结果表明导体栅具有很好的静电屏蔽作用     

Convex duality for finite-fuel problems in singular stochastic control

Upon introducing a finite-fuel constraint in a stochastic control system, the convex duality formulation can be set up to represent the original singular control problem as a minimization problem over the space of vector measures at each level of available fuel. This minimization problem is imbedded tightly into a related weak problem, which is actually a mathematical programming problem over a convex,w*-compact space of vector-valued Radon measures. Then, through the Fenchel duality principle, the dual for the finite-fuel control problems is to seek the maximum of smooth subsolutions to a dynamic programming variational inequality. The approach is basically in the spirit of Fleming and Vermes, and the results of this paper extend those of Vinter and Lewis in deterministic control problems to the finite-fuel problems in singular stochastic control. Meanwhile, we also obtain the characterization of the value function as a solution to the dynamic programming variational inequality in the sense of the Schwartz distribution.The author is much indebted to Professor Wendell H. Fleming for his constant support and many helpful discussions during the preparation of this paper.     

氢同位素化合物TiH2，TiD2和TiT2的电子

根据原子分子反应静力学和群论，确定TiH2，TiD2和TjT2的基电子状态为^3A2．应用基函数6-311G^＊＊和密度泛函理论B3P86方法，全电子计算了氢同位素分子及其钛化物的能量E、定容热容Cv和熵S应用电子振动近似理论，即用单个分子TiH2，TiD2和TjT2中的电子和振动能量和熵近似代表他们处于固态时的能量和熵,计算所得到的金属钛的氢化热力学函数△Hc^0，△S^0，△G^0以及平衡压力与温度的关系，与文献符合很好，这表明电子振动近似理论的可应用性，选用金属钛作为中子靶是很正确的。     

Enhanced Raman Scattering by Quasi-phase-matched Processes in ax^（2） Photonic Crystal

An intense comb-shaped Raman spectra were obtained from a two-dimensional nonlinear x（2） photonic crystal - a hexagonally poled LiTaO3 crystal with lattice parameter 9 micros. The lowest Raman shift was down to 2 cm^-1 and the order of anti-stokes and stokes signals both achieved 11. The novel Raman spectra were mediated first by intense phonon-polariton fields, which were driven through the quasi-phase-matched coupling between the incident dual-beam both from an optical parametric oscillation laser, and further amplified greatly also by such quasi-phasematched nonlinear optical process. The dependence of the Raman spectra character on the wavelength and intensity of incident beams were studied in detail, which accordingly revealed information of the inelastic scattering and the elementary excitation in the nonlinear medium. These results on the other hand suggest technological importance for developing a novel Raman laser with the multi-wavelength output and a tunable frequency interval and for possible applications in quantum optics.     

Gas source MBE grown wavelength extended 2.2 and 2.5 μm InGaAs PIN photodetectors

Using homo-junction structure and relative thin linear graded In_xGa_1−xAs as the buffer layer, extended wavelength InGaAs PIN photodetectors with cut-off wavelength of 2.2 and 2.5 μm at room temperature have been grown by using GSMBE, and their performance over a wide temperature range have been extensively investigated. For those 2.2 or 2.5 μm detectors with 100 μm diameter, the typical dark current (V_R = 10 mV) and R₀A are 57 nA/10.3 Ω cm² or 67 nA/12.7 Ω cm² at 290 K, and 84 pA/4.70 kΩ cm² or 161 pA/3.12 kΩ cm² at 210 K respectively. The thermal activation energies of the dark current are 0.447 eV or 0.404 eV for 2.2 or 2.5 μm detectors respectively.     

Determination of Trace Mercury by Solid Substrate-Room Temperature Phosphorimetry Quenching Method Based on Catalytic Effect of Hg2+on Formation of the Ion Association Complex [Sn(XO)6]4+·[(Fin)4]

A new method for the determination of trace mercury by solid substrate-room temperature phosphorimetry (SS-RTP) quenching method has been established. In glycine-HCl buffer solution, xylenol orange (XO) can react with Sn⁴⁺ to form the complex [Sn(XO)₆]⁴⁺. [Sn(XO)₆]⁴⁺ can interact with Fin⁻ (fluorescein anion) to form the ion associate [Sn(XO)₆]⁴⁺·[(Fin)₄]⁻, which can emit strong and stable room temperature phosphorescence (RTP) on polyamide membrane (PAM). Hg²⁺ can catalyze H₂O₂ oxidizing the ion association complex [Sn(XO)₆]⁴⁺·[(Fin)₄]⁻, which causes the RTP to quench. The ΔIp value is directly proportional to the concentration of Hg²⁺ in the range of 0.016–1.6 fg spot⁻¹ (corresponding concentration: 0.040–4.0 pg ml⁻¹, 0.40 μl spot⁻¹), and the regression equation of working cure is ΔIp=10.03+83.15 m Hg²⁺ (fg spot⁻¹), (r=0.9987, n=6) and the detection limit (LD) is 3.6 ag spot⁻¹(corresponding concentration: 9.0×10^–15 g ml⁻¹, the sample volume: 0.4 μl). This simple, rapid, accurate method is of high selectivity and good repeatability, and it has been successfully applied to the determination of trace mercury in real samples. The reaction mechanism for catalyzing H₂O₂ oxidizing the ion association complex ([Sn(XO)₆]⁴⁺·[(Fin)₄]⁻) SS-RTP quenching method to determine trace mercury is also discussed.     

β-Si3N4电子结构和光学性质的第一性原理研究

采用基于密度泛函的平面波赝势方法(PWP)和广义梯度近似(GGA),计算了β相氮化硅(β-Si3N4)的电子结构和光学性质,得到的晶格常数、能带结构等均与实验结果较好符合.进一步还研究了β-Si3N4的光吸收系数以及禁带宽度随外压力的变化规律,为β-Si3N4材料在高压条件下的应用提供了理论参考.     

Collective bands in 104,106,108Mo

We have used our analysis of γ-γ-γ data (5.7 × 10¹¹ triples and higher folds) taken with Gammasphere from prompt γ rays emitted in the spontaneous fission of ²⁵²Cf to study the collective bands in ^104,106,108Mo. The one-phonon and two-phonon γ-vibrational bands and known two-quasiparticle bands in neutron-rich ^104,106Mo were extended to higher spins. The one-and two-phonon γ-vibrational bands have remarkably close energies for transitions from the same spin states and identical moments of inertia. Several new bands are observed and are proposed as quasiparticle bands in ^104,106Mo, along with the first β-type vibrational band in ¹⁰⁶Mo. The quasiparticle bands have essentially constant moments of inertia near the rigid-body value that indicate blocking of the pairing interaction. Candidates for chiral doublet bands in ¹⁰⁶Mo are strong. These are the first reported chiral vibrational bands in an even-even nucleus. The text was submitted by the authors in English.