富勒烯在SiO_2与SiO_2－TiO_2凝胶中的掺入及光谱特性研究

本工作以ＳｉＯ_２和ＳｉＯ_２－ＴｉＯ_２凝胶体系为基质，选择合适的溶剂，采用特定的溶胶一凝胶工艺，成功地将纯的Ｃ_（６０）和Ｃ_（６０）／Ｃ_（７０）混合物分别均匀掺入上述基质中．研究了吸收与荧光光谱特性．室温下观测到峰置位于６６０ｎｍ附近的较强荧光带．对上述光谱性质作了初步的解释．     

具超前变元的二阶微分方程三点边值问题的正解

§ 1　 IntroductionRecently,certain three-point boundary value problems for nonlinear ordinarydifferential equations have been studied by many authors[1— 6] .However,few papers havebeen published on the same problems for nonlinear functional differential equations.In thispaper,we are concerned with the following second order differential equation with anadvanced argumentu″(t) +λa(t) f(u(h(t) ) ) =0 ,t∈ (0 ,1 ) (1 .1 )with the three-point boundary conditionsu(0 ) =0 ,αu(η) =u(1 ) ,(1 .2 )…     

Convex duality for finite-fuel problems in singular stochastic control

Upon introducing a finite-fuel constraint in a stochastic control system, the convex duality formulation can be set up to represent the original singular control problem as a minimization problem over the space of vector measures at each level of available fuel. This minimization problem is imbedded tightly into a related weak problem, which is actually a mathematical programming problem over a convex,w*-compact space of vector-valued Radon measures. Then, through the Fenchel duality principle, the dual for the finite-fuel control problems is to seek the maximum of smooth subsolutions to a dynamic programming variational inequality. The approach is basically in the spirit of Fleming and Vermes, and the results of this paper extend those of Vinter and Lewis in deterministic control problems to the finite-fuel problems in singular stochastic control. Meanwhile, we also obtain the characterization of the value function as a solution to the dynamic programming variational inequality in the sense of the Schwartz distribution.The author is much indebted to Professor Wendell H. Fleming for his constant support and many helpful discussions during the preparation of this paper.     

BV estimates of Lax-Friedrichs' scheme for a class of nonlinear hyperbolic conservation laws

We give uniform BV estimates and -stability of Lax-Friedrichs' scheme for a class of systems of strictly hyperbolic conservation laws whose integral curves of the eigenvector fields are straight lines, i.e., Temple class, under the assumption of small total variation. This implies that the approximate solutions generated via the Lax-Friedrichs' scheme converge to the solution given by the method of vanishing viscosity or the Godunov scheme, and then the Glimm scheme or the wave front tracking method.

     

无溶剂顶空气相色谱法测定盐酸左氧氟沙星残留溶剂

采用无溶剂-顶空-气相色谱直接测定盐酸左氧氟沙星中残留溶剂乙醇、甲苯、二甲基亚砜(DMSO)等.各残留溶剂的检出限分别在0.007-0.032 μg,6次测定的相对标准偏差RSD在1.84%-1.92%,加标回收在90.9%-110%.方法简便、快速、灵敏,可应用于其他药品中残留溶剂的分析.     

综合性、设计性实验教学的探讨

综合性、设计性实验是培养学生的创新意识、创新精神和创新能力的有效措施;本文就开设综合性、设计性实验的意义、内涵、与基础实验的关系以及如何设计项目内容进行了初步的探讨。     

Widely tunable, high-repetition-rate, dual signal-wave optical parametric oscillator by using two periodically poled crystals

This paper reports on a high-repetition-rate dual signal-wave (DSW) optical parametric oscillator (OPO) operating at the 1.5 μm band with tunable wavelength intervals from 2.5 nm to 69.1 nm. Two periodically poled crystals, a periodically poled lithium niobate (PPLN) with multiple gratings and a single grating MgO-doped PPLN (PPMgOLN), are cascaded in the same OPO cavity to generate dual signal-waves by using quasi-phase-matched (QPM) technique. The pump source was a Q-switched diode-pumped Nd:YVO₄ laser operating at 50 kHz. At an incident pump power of 3 W, an average output power of 169.6 mW at 1489.2 nm and 1558.3 nm has been achieved.     

An Experimental Study of Mg Aggregation in AA5754 Alloys by Positron Annihilation Spectroscopy

Defects in an AA5754 （Al-3.0%Mg） alloy are investigated by coincidence Doppler broadening spectroscopy and positron lifetime spectroscopy. The results indicate enhancement of positron trapping by Mg atoms in this Al-Mg alloy after quenching treatment at 623K, which may be due to the formation of vacancy-Mg complexes or the aggregation of Mg near the vacancy sites. It is speculated that the aggregation of Mg atoms in the moderate temperature range is responsible for cracking in spot welding of AA5754 alloys.