Al2O3衬底上生长ZnO薄膜的结构和光学特性

用脉冲激光沉积法在Al2O3(0001)衬底上沉积了ZnO薄膜.衬底温度分别为300℃、400℃、500℃、600℃和700℃.利用X射线衍射(XRD)和光致发光谱(PL)对薄膜的结构和光学性能进行研究.X射线衍射的结果表明在不同温度下生长的ZnO薄膜均具有高度c轴择优取向,衬底温度400℃时,膜的应力较小质量较高.ZnO薄膜有很强的紫外发光峰,紫外发光峰的强度与衬底温度密切相关,并发现当衬底温度从300℃增到400℃时,紫外发射峰出现6nm的蓝移.     

新型空间调制微型傅里叶变换光谱仪的设计与仿真

傅里叶变换光谱仪(FTS)在光谱分析中的应用越来越广泛,并且其微型化的趋势也愈加明显。文章设计了一种新型空间调制微型傅里叶变换光谱仪。在介绍其结构理论的基础上,对其空间的光强分布进行了模拟,通过对该结构下引起相位误差因素的详细分析,采用改进的Mertz相位校正方法对小双边的采样数据进行了光谱复原,其理论分辨率可达到3.43 nm@800 nm,信噪比的理想分辨极限为6.8 dB。该结构的微型FTS可以用微机械加工的方法来实现,具有性能稳定,误差容易校正等优点,文章对空间调制微型傅里叶变换光谱仪的结构设计及仿真,为微型FTS的微机械加工实验提供了理论支持, 还为微型傅里叶变换光谱仪的进一步应用提供了更广阔的空间。     

Electrochemical Metalloimmunoassay Based on Enlargement of Gold Nanoparticle Label Treated with Ag Enhancement System

A novel sensitive electrochemical immunoassay with colloidal gold as the antibody labeling tag and subse-quent signal amplification by silver enhancement is described. Colloidal gold was treated by a light-sensitive silver enhancement system which made silver deposit on the surface of colloidal gold(form Au/Ag core-shell structure), followed by the release of the metallic silver atoms anchored on the antibody by oxidative dissolu-tion of them in an acidic solution and the indirect determination of the dissolved Ag ions by anodic stripping voltamrnetry(ASV) at a carbon fiber microelectrode. The electrochemical signal is directly proportional to the amount of analyte(goat IgG) in the standard or a sample, The method was evaluated by means of a non-competitive heterogeneous immunoassay of immunoglobulin G(IgG) with a concentration as low as 0. 2 ng/mL. The high performance of the method is related to the sensitive ASV determination of silver( I ) at a car-bon fiber microelectrode and to the release of a large number of Ag^ ions from each silver shell anchored on the analyte (goat IgG).     

基于完备格的模糊数学形态学

数学形态学被广泛应用于信号与图像处理。本文在完备格的框架下,利用模糊逻辑运算及其伴随,给出模糊数学形态学运算的定义,并深入讨论了这些运算的性质。特别是,由这种途径定义的模糊形态学,模糊闭和模糊开具有很好的性质。本文还探讨了模糊形态学运算和古典形态学运算之间的关系。     

引发剂结构对原子转移自由基聚合反应的影响

研究了三种不同结构的引发剂,溴代乙酸乙酯（EBrA)、α-溴代丁乙酯（EBrB)、α－溴代异丁酸乙酸（EBriB)引发的苯乙烯的原子转移自由基聚合反应（ATRP）。发现EBrA引发的苯乙烯的ATRP不是“活性”聚合。EBriB引发的苯乙烯的ATRP引发效率不够高,也不是典型的“活性”聚合。EBrB引发的苯乙烯的ATRP是较为典型的“活性”聚合：聚合物的分子量可以通过调节单体／引发剂的投料量及反应时间来控制,所得聚合物的分子量分布很窄,且有随转化率的增加而逐渐变窄的趋势。     

From exfoliation to intercalation—changes in morphology of HNBR/organoclay nanocomposites

Hydrogenated nitrile rubber (HNBR)/organoclay nanocomposites (HNBR/OCNs) were prepared by mechanical mixing technique. By altering the temperature, pressure, and treatment time, respectively, the microstructural changes of HNBR/OCNs compounds under those treatments were studied by X-ray diffraction (XRD) and transmission electron microscopy (TEM) in detail. It was investigated that after the treatment, the exfoliated organoclay dispersion in untreated HNBR/organoclay compounds transformed into the co-existing of exfoliated, intercalated, and aggregated structures by de-intercalation action. Moreover, pressure, and temperature played accelerated roles in determining the final clay structures in HNBR/OCNs. It was suggested that the transformation was caused by the relaxation of HNBR chains, and it could be proceed spontaneously in thermodynamics under the treatment condition.     

横向监督中基于社会偏好匹配的员工组合问题研究

考虑横向监督中基于社会偏好的三种员工组合方式:同质组合、异质组合与双高组合。运用委托代理理论,研究基于社会偏好匹配的员工组合问题。模型分别给出了不存在横向监督、存在横向监督且员工是同质组合、存在横向监督且员工是异质组合与存在横向监督且员工是双高组合四种情形下的均衡结果。根据均衡结果做进一步分析,得出结论:①存在横向监督时员工的努力程度与企业收益总是高于不存在横向监督的情形,但不同的员工组合方式对其努力程度的激励效果是相同的;②异质组合能够通过节约薪酬成本而间接地提高企业总收益,双高组合能够通过获得较多的员工投入而直接增加企业总收益,并且异质组合与双高组合总是优于同质组合;③员工的社会偏好与风险成本是决定企业最佳员工组合方式选择的关键因素:当员工的风险成本很小而社会偏好差距较大时企业应选择异质组合;而当员工的风险成本很大或者风险成本小并且员工社会偏好差距也较小时企业应选择双高组合;因此,根据员工的个性特征选择适宜的组合方式是实现横向监督激励效应最大化的关键。     

一类非线性微分方程解的存在性

考虑了一类非线性微分方程边值问题.通过应用Krasnoselskii锥不动点定理及不动点指数给出了这类问题解的存在性及多解性.所得结果推广了最近文献中一些相关结论.     

奇异积分在Herz型Sobolev空间上的有界性

采用Hardy空间的原子分解理论、Riesz-Thorin内插定理以及调和分析中的一些基本方法讨论了粗糙核奇异积分算子TΩ,βf(x)=p.v.∫Rnb(|y|)Ω(y′)|y|-n-βf(x-y)dy,当Ω∈Hr(Sn-1)(r=n-1/n-1+β)时,是从Herz型Sobolev空间到Herz型空间有界的.其中b(?)是一个有界函数,β≥0,Ω是Sn-1上满足某些消失性条件的分布.