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801.
使用双沸点仪测定了丙酮、乙酸乙酯、对二氧六环、乙腈或三乙胺与甲醇或1,2→二氯乙烷以及二者混合物等十一组二元体系在99.3 kPa下的汽液平衡数据(T,x,p), 计算了有关体系的过量吉布斯自由能。结果表明, 六种非质子溶剂与甲醇组成的二元系GE>0; 乙腈或三乙胺与1,2-二氯乙烷组成的二元系GE>0, 而丙酮、乙酸乙酯或对二氧六环与1,2-二氯乙烷的二元混合物GE<0。从同种分子间或不同种分子间的缔合作用对上述结果进行了讨论。本文还在固定极性非质子溶剂(第三组分)物质的量浓度的条件下, 测定了非质子溶剂+1,2-二氯乙烷+甲醇三元混合物的汽液平衡数据, 考察了非质子溶剂的加入对甲醇+1,2-二氯乙烷二元系GE的影响。 相似文献
802.
803.
建立了耐硫甲烷化循环式反应器的拟均相一维模型,考察了床层直径,循环比,入口气体温度及压力和温度范围对反应器操作的影响,结果表明:循环比和温度操作范围是反应器操作的决定因素,对日产5万标准立方煤气的反应器进行了优化设计分析。 相似文献
804.
Analytical methodologies for aluminium speciation in environmental and biological samples--a review 总被引:1,自引:0,他引:1
Bi SP Yang XD Zhang FP Wang XL Zou GW 《Fresenius' Journal of Analytical Chemistry》2001,370(8):984-996
It is recognized that aluminium (Al) is a potential environmental hazard. Acidic deposition has been linked to increased Al concentrations in natural waters. Elevated levels of Al might have serious consequences for biological communities. Of particular interest is the speciation of Al in aquatic environments, because Al toxicity depends on its forms and concentrations. In this paper, advances in analytical methodologies for Al speciation in environmental and biological samples during the past five years are reviewed. Concerns about the specific problems of Al speciation and highlights of some important methods are elucidated in sections devoted to hybrid techniques (HPLC or FPLC coupled with ET-AAS, ICP-AES, or ICP-MS), flow-injection analysis (FIA), nuclear magnetic resonance (27Al NMR), electrochemical analysis, and computer simulation. More than 130 references are cited. 相似文献
805.
(Z)-3-丁烯基苯酞和它的衍生物广泛地存在于微形科植物,如当归、川芎等,这些植物有些是重要的中药材。(Z)-3-丁烯基-4,5-二羟基苯酞是(Z)-3-丁烯基苯酞的类似物;它对前列腺素F2α具有抑制作用。本文以3,4-二甲氧基苯甲醇(2)或价廉易得的胡椒醇(6)为起始原料,分别经四步反应顺利地合成了(Z)-3-丁烯基-4,5羟基苯酞(1)。和一步是本方法的关键,即利用杂原子诱导的区域选择性的芳环 相似文献
806.
An N2O laser is used to pump the ground vibrational state (8,7) inversion doublet of 14NH3 while simultaneously monitoring other ground state doublets. Time-resolved rotational energy transfer signals are observed in accordance with known selection values. Absolute rates of rotational energy transfer processes are estimated. 相似文献
807.
Jiang Hu Wei‐Dong Zhang Yun‐Heng Shen Chuan Zhang Run‐Hui Liu Xi‐Ke Xu Bin Wang 《Helvetica chimica acta》2007,90(4):720-722
Two novel alkaloids, 4,5‐dihydroxy‐1‐methyl‐3‐oxo‐2‐(trichloromethyl)‐3H‐indolium chloride ( 1 ) and 4‐(2‐methoxyethyl)‐N,N‐dimethylbenzenamine ( 2 ), were isolated from the EtOH extract of the roots of Zanthoxylum nitidum. Their structures were identified on the basis of spectroscopic and mass‐spectrometric analyses. 相似文献
808.
809.
Ung-Ping Wang 《中国化学会会志》1973,20(2):57-73
Vinyl monomers such as vinyl acetate, vinyl chloride, methyl methacrylate and styrene etc., can be polymerized without catalyst into the composites of bagasse material by gamma-radiation induced in situ liquid polymerization process. The fundamental factors, such as polymerization-rate, effect of swelling agent, molecular weight of vinyl polymers and graft reaction between bagasse cellulose and vinyl polymers, have been investigated and discussed. The use of suitable low G-value polar swelling agents and the application of suitable gamma dose-rate are two key factors found to control the smooth in situ liquid polymerization system of vinyl monomers in bagasse. 相似文献
810.
Jinmao You Xiangming Chen Xianen Zhao Yourui Suo Honglun Wang Yulin Li Jing Sun 《Chromatographia》2006,63(7-8):337-343
A pre-column derivatization method for the sensitive determination of amines using the labeling reagent 1,2-benzo-3,4-dihydrocarbazole-9-isopropyl
chloroformate (BCIC-Cl) followed by high-performance liquid chromatography with fluorescence detection has been developed.
Identification of derivatives is carried out by high performance liquid chromatography/atmospheric pressure chemical ionization
(LC-APCI-MS-MS). The chromophore of 2-(9-carbazole)-ethyl chloroformate (CEOC) reagent is replaced by 1,2-benzo-3,4-dihydrocarbazole-9-isopropyl
functional group, which results in a sensitive fluorescence derivatizing reagent BCIC-Cl. BCIC-Cl can easily and quickly label
amines. Derivatives are stable enough to be efficiently analyzed by high-performance liquid chromatography and show an intense
protonated molecular ion corresponding m/z [MH]+ under APCI in positive-ion mode. The collision-induced dissociation of protonated molecular ion formed a product at m/z 260 corresponding to the cleavage of CH2-OCO bond. Studies on derivatization demonstrate excellent derivative yields over the pH 9.0–10.0. Maximal yields close to
100% are observed with a 3 to 4-fold molar reagent excess. In addition, the detection responses for BCIC derivatives are compared
with those obtained using CEOC and FMOC as derivatization reagents. The ratios of IBCIC/ICEOC and IBCIC/IFMOC are, respectively, 1.23–3.14 and 1.25–3.08 for fluorescent (FL) responses (here, I is relative fluorescence intensity). Separation of the derivatized amines had been optimized on reversed-phase Eclipse XDB-C8 column. Detection limits are calculated from 1.0 pmol injection, at a signal-to-noise ratio of 3, are 10.6–37.8 fmol. The
mean interday accuracy ranges from 94 to 105% for fluorescence detection with the largest mean %CV<7.5. The mean interday
precision for all standards is < 6.0% of the expected concentration. Excellent linear responses are observed with coefficients
of > 0.9997.
Revised: 12 December 2005 and 13 Febrauary 2006 相似文献