选相原位法合成立方氮化硼的关键影响因素

利用选相原位法在水溶液中成功制备出了立方氮化硼晶体，对反应条件进行了优化。结果表明，利用选相原位法合成立方氮化硼的最佳实验条件是：反应压力为10.0 MPa，在氯离子加入下利用混合氮源进行反应。在该条件下得到了纯相的立方氮化硼晶体。     

Efficient and mild benzoin condensation reaction catalyzed by simple 1-N-alkyl-3-methylimidazolium salts

The benzoin reaction, catalyzed by simple 1-N-alkyl-3-methylimidazolium salt-based ionic liquid via carbene intermediate, to give the α-hydroxyl ketone proceeds in CH₂Cl₂ under mild conditions.     

超临界流体萃取-胶束电动毛细管色谱法分离测定大黄中蒽醌类组分的含量

采用ＳＴＥ－ＭＥＣＣ法分离测定大黄中的芦荟大黄素，大黄素和大黄酸。萃取条件为压 力４１．４ＭＰａ，温度５０℃，改性剂量０．４ｍＬ。被测组分在１０ｍｉｎ得到全部分离。本法准确、简 便、快速、结果令人满意。     

Two new sesquiterpene lactones with the sulfonic acid group from Saussurea lappa

Two new sesquiterpene lactones with the unusual sulfonic acid group, 13-sulfo-dihydrosantamarine (1) and 13-sulfo-dihydroreynosin (2), have been isolated from the roots of Saussurea lappa C. Their structures, including the absolute configurations, were elucidated by spectroscopic methods.     

环己烯和2-甲基戊烯-1在几种Y型分子筛上的吸附量热研究

用SETARAM热流式量热计测定了环己烯和2-甲基戊烯-1于室温下在NaY、CaY、R_EY和HY等几种分子筛上的微分吸附热。我们又用Benson基团加合法计算得到了生成仲碳离子和叔碳离子时的吸附热。根据实验测得的于不同吸附量时环己烯和2-甲基戊烯-1的吸附热之差值, 对它们在上述几种Y型分子筛上的吸附机理进行了讨论。     

Crystal Structure,Electrochemical Properties and Third-order Nonlinear Optical Response of 4-Methyloxy benzaldehyde Thiosemicarbazone and Its Copper(Ⅱ)Complex

Thecurrentsurgeofinterestinthefield0fnon-linearoptics(NL0)isderivedbothfromaquestforafundamentalunderstanding0fthenon-linearprocess,anditSimPortanceinthetechn0logyofphotonics.Amongnon-linearphen0mena,thethird-ordernon-linearophcsoccuPyanimPortantp0sihonbecauseitprovidesthemechanicsforophcalswitching,ophcallogic,andreal-hmeholograPhy"'.0rganicmaterialwithextendednconjugahonsandlargeRdelocalizahonsarewellknownastheimPortantmaterialsofachievinglargethird-ordernonlinearihes3.ForexamPle,thiosen…     

Synthesis α‐aminonitrile through anodic cyanation of N‐benzylpiperidine

Six‐membered cyclic α‐aminonitrile has been prepared from anodic cyanation of N‐benzylpiperidine. Good yields of α‐aminonitriles could be obtained through potentiostatic electrolysis under different conditions. The results also explain why high yield α‐aminonitriles could not be obtained under constant current electrolysis.     

A practical synthetic route to 4′-alkylaristeromycin derivatives: 4′-methylaristeromycin

(−)-(1S,4R)-4-Hydroxy-2-cyclopenten-1-yl acetate provided a convenient entry point for a 16-step chiral preparation of 4′-methylaristeromycin. This procedure is adaptable to a number of carbocyclic nucleosides with a diversity of substitution at C-4′ and C-5′ and a variety of heterocyclic bases.     

Morphology and thermal properties of a PC/PE blend with reactive compatibilization

Reactive compatibilization of immiscible polymers is becoming increasingly important and hence a representative study of a polycarbonate/high density polyethylene (PC/HDPE) system is the focus of this paper. A grafted copolymer PC‐graft‐ethylene‐co‐acrylic acid (PC‐graft‐EAA) was generated as a compatibilizer in situ during processing operation by ester and acid reaction between PC and ethylene‐acrylic acid (EAA) in the presence of the catalyst dibutyl tin oxide (DBTO). As the polyethylene (PE) matrix does not play any part during the synthesis of the copolymer and since PC and EAA are also immiscible, to simplify the system, the influence of this copolymer formation at the interface between PC and EAA on rheological properties, phase morphology, and crystallization behavior for EAA/PC binary blends was first studied. The equilibrium torque increased with the DBTO content increasing in EAA/PC blends on Haake torque rheometer, indicating the in situ formation of the graft copolymer. Scanning electron microscopy (SEM) studies of cryogenically fractured surfaces showed a significant change at the distribution and dispersion of the dispersed phase in the presence of DBTO, compared with the EAA/PC blend without the catalyst. Differential scanning calorimetry (DSC) studies suggested that the heat of fusion of the EAA phase in PC/EAA blends with or without DBTO reduced with the formation of the copolymer compared with pure EAA. Then morphological studies and crystallization behavior of the uncompatibilized and compatibilized blends of PC/PE were studied as functions of EAA phase concentration and DBTO content. Morphological observations in PC/PE blends also revealed that on increasing the EAA content or adding the catalyst DBTO, the number of microvoids was reduced and the interface was intensive as compared to the uncompatibilized PC/PE blends. Crystallization studies indicated that PE crystallized at its bulk crystallization temperature. The degree of crystallinity of PE phase in PC/PE/EAA blends was also reduced with the addition of EAA and DBTO compared to the uncompatibilized blends of PC/PE, indicating the decrease in the degree of crystallinity was more in the presence of PC‐graft‐EAA. Copyright © 2007 John Wiley & Sons, Ltd.