The structural and magnetic properties of barium ferrite powders prepared by the solben gel method

In this paper, M-type hexagonal barium ferrite powders are synthesized using the sol-gel method. A dried precursor heated in air is analyzed in the temperature range from 50 to 1200 ℃ using thermo-gravimetric analysis and differential scanning calorimetry. The effects of the additives and the cacinating temperature on the magnetic properties are investigated, and the results show that single-phase barium ferrite powders can be formed. After heat-treating at 950 ℃ for 4h with 3 wt% additive, the coercivity and saturation magnetization are found to be 440 Oe and 57.9 emu/g, respectively.     

Anilinolysis of O‐butyl phenyl phosphonochloridothioate in acetonitrile: Synthesis,characterization, kinetic study,and reaction mechanism

This paper describes a simple optimized method for the synthesis of O‐butyl phenyl phosphonochloridothioate ( 4 ) under mild conditions. The target compounds were characterized by ¹H‐nuclear magnetic resonance (NMR), ¹³C‐NMR, and ³¹P‐NMR spectroscopy, as well as mass spectroscopy. The apparent structure of 4 was confirmed by optimization using the B3LYP/6‐311 + G(d,p) level in the Gaussian 09 program in acetonitrile. The nucleophilic substitution reactions of 4 with X‐anilines (XC₆H₄NH₂) and deuterated X‐anilines (XC₆H₄ND₂) were investigated kinetically in acetonitrile at 55.0°C. The free energy relationship with X in the anilines looked biphasic concave upwards with a break region between X = H and X = 3‐MeO, giving large negative ρ_X and small positive β_X values. The deuterium kinetic isotope effects were secondary inverse (k_H/k_D < 1: 0.789‐0.995) and the magnitudes, (k_H/k_D), increased when the nucleophiles were changed from weakly basic to strongly basic anilines. A concerted S_N2 mechanism is proposed on the basis of the selectivity parameters and the variation trend of the deuterium kinetic isotope effects with X.     

Enhanced Efficiency of Polymer： Fullerene Bulk Heterojunction Solar Cells with the Insertion of Thin TiO2 Layer near the LiF/A1 Electrode

The insertion layer of TiO2 between polymer-fullerene blend and LiF/AI electrode is used to enhance the shortcircuit current Isc and fill factor （FF）. The solar cell based on the blend of poly[2-methoxy-5-（2＇-ethylhexyloxy）- 1,4-phenylenevinylene] （MEH-PPV） and C60 with the modifying layer of TiO2 （about 20nm） shows the open- circuit Voc of about 0.62 V, short circuit current Isc of about 2.35 mA/cm^2, filling factor FF of about 0.284, and the power conversion efficiency （PCE） of about 2.4% under monochromatic light （50Onto） photoexcitation of about 17mW/cm^2. Compared to ceils without the TiO2 layer, the power conversion efficiency increases by about 17.5%. Similar effect is also obtained in cells with the undoped MEH-PPV structure of ITO/PEDOT：PASS/MEH- PPV/（TiO2）LiF/AI. The improved solar cell performance can be attributed to enhanced carrier extraction efficiency at the active layer/electrode interfaces when TiO2 is inserted.     

受激布里渊散射新介质——全氟胺的研究

本文从介质化学结构与受激布里渊散射(SBS)特性的关系入手,寻找出了SBS特性良好的全氟胺系列新介质——FC-131,FC-3283,FC-40,FC-43,FC-70等,并测定或计算出了新介质的SBS参数. 结果表明,新介质的吸收系数均小于10^-3 cm^-1,光学击穿阈值均高于100 GW/cm². 全氟胺系列新介质不仅具有良好的SBS特性,而且还具有无毒、低挥发性和高稳定性等一系列独特的物理化学性质. 新介质的发现不仅增加SBS介质的种类,而且能够有效提高SBS系统的性能,对于SBS相位共轭镜在高功率激光系统中的应用打下了良好的基础. 关键词： 受激布里渊散射(SBS) 全氟胺 吸收系数 光学击穿阈值     

Role of TiO2 Nanotube on Improvement of Performance of Hybrid Photovoltaic Devices

The performance of TiO₂ nanotubes in bulk heterojunction of poly (2-methoxy-5-(2'-ethylhexyloxy)-1, 4-phenylenevinylene) (MEH-PPV)/TiO₂ nanotubes is investigated. The transport properties are studied by using the time-of-flight technique (TOF). The carrier mobilities of both holes and electrons are not improved for the MEH-PPV:TiO₂ composites compared with the pristine MEH-PPV. However, photoluminescence under the influence of the electric field indicates that the dissociation of excitons in the MEH-PPV:TiO₂ composites, which is facilitated by photoinduced charge transfer, only requires a smaller electric field.     

有机/无机复合结构光电导型器件的光激发机制

制备了PVK/ZnS有机无机复合的光电导型器件 ,器件结构分别为Glass/ITO/PVK/Al;Glass/ITO/ZnS/Al;Glass/ITO/ZnS/PVK/Al。通过研究此复合器件在外加电场作用下的稳态光电导激发谱 ,得到了基本光激发过程。把PVK/ZnS的吸收谱和器件的光电导谱进行比较 ,知道虽然两者的吸收对器件光电流都有贡献 ,但有效部分在PVK和ZnS的界面处。最大光电流对外加电场的依赖性与器件的暗电流和光电流谱为此提供了证据     

基于石墨烯振幅可调的宽带类电磁诱导透明超材料设计

基于石墨烯的电控特性提出了一种由金属线谐振器和"H"型谐振器组成的宽带可调的类电磁诱导透明(类EIT)超材料结构.首先,利用CST Microwave Studio软件对该超材料结构的透射特性进行了仿真.该结构在1.05—1.46 THz内的透射窗由金属线谐振器的等离子谐振和"H"型谐振器的电感-电容谐振干涉相消引起,且暗模式谐振器的数量增多导致了透射窗带宽的增加.其次,仿真模拟了该结构在不同石墨烯费米能级下的透射特性.当石墨烯费米能级由0 eV逐渐增加到1.5 eV时,该结构透射窗在1.05—1.46 THz内的平均透射振幅由87%逐渐减少到25%,实现了宽带可调.同时,通过仿真模拟该结构在1.26 THz下的电场分布对其透射机理进行了分析,并实验制备了类EIT超材料结构样品,且利用太赫兹时域光谱对样品进行了透射性能测试,测试结果与仿真分析的趋势基本一致.     

M(o)bius不变的Qp空间:结果、技巧和问题

本文是关于Mobius不变的Qp函数空间方面的综述文章，给出了近10年来有关Qp函数空间的若干结果、技巧和问题。