甘氨酸与氯化碱金属在水中的焓相互作用参数

氨基酸在混合溶液中的热力学性质及相互作用的研究不论对溶液化学还是生命科学都是十分重要的．对此国内已有不少的研究h，’1．利用偿效应的方法研究氨基酸与电解质间的相互作用是很有效的卜一句，但大多数的工作都是在低浓度下研究一个氨基酸分子和一个电解质离子对间的相互作用烩．本文测定了甘氨酸在水中和在LICI、NaCI、KCI的水溶液中的溶解偿，计算出甘氨酸与各个公在水中的偿对相互作用参数和三相互作用参数，并由此讨论了甘氨酸与这些盐的对分子相互作用和三分子相互作用．1实验部分试剂：甘氨酸为ARfa，K甲醇一水重结晶．LI…     

Correlation and response functions with non-Markovian dissipation: a reduced Liouville-space theory

Based on a recently developed quantum dissipation formulation [R. X. Xu and Y. J. Yan, J. Chem. Phys. 116, 9196 (2002)], we present a reduced Liouville-space approach to evaluate the response and correlation functions of dissipative systems. The weak system-bath interaction is treated properly for its effects on the initial state, the evolution, and the correlation between coherent driving and non-Markovian dissipation. Numerical demonstration shows this correlated effect cannot be neglected even in the calculation of linear response quantities that do not explicitly depend on external fields. Highlighted in this paper is also the proper choice of theory among various formulations in the weak system-bath interaction regime.     

THE STRUCTURE OF $\[\Pi \]$ SPACES (I)

The spectral theory of selfadjoint operators and unitary operators in Hilbert space has been successfully generalized to $\[{\Pi _k}\]$ space. However, there are only a few results for the spectral theory of selfadjoint operators and unitary operators in $\[\Pi \]$ space. One of the important reasons is that the structure of $\[\Pi \]$ space is more complex than that of $\[{\Pi _k}\]$ space. This paper and the forthcoming paper "The structure of $\[\Pi \]$ space (II)" will mainly be dealt with the structure of $\[\Pi \]$ spaces, which will be used to further study the operators in $\[\Pi \]$ spaces.     

氟的离子选择电极瞬时电位法测定

研究了氟离子选择电极瞬时电位分析法，其检出限和Nernst响应下限均低于传统电位分析法，空白液切换到试液时瞬时电位达到稳定的峰电位Vp比传统电位法的响应快得多，可以实现小体积试液的快速准确分析；用该法测定了自来水和矿泉水中氟的含量；利用校正曲线的截距和检出限计算了LaF3的溶度积，在0.1mol/L KNO3介质中Ksp(LaF3)=10^-28.45，在0.001mol/L柠檬酸钠＋HAc-NaAc缓冲液（pH=5.50，离子强度I＝0.10mol/L)介质中溶度积K′sp(LaF3)=10^-26.26；据此，计算得柠檬酸与La^3 络合物的稳定常数K1=10^5.46和K2=10^3.99；用离子水合吉氏自由能ΔGh(F^-,g)解释了不同浓度F^-试液瞬时电位的跃迁时间。     

Crystal Structure, Thermal Stability and Luminescence of Coordination Polymer [Cd（BBP）（p-PDOA）]n

Hydrothermal reaction of Cd（NO3）2·4H2O with bbp and p-PDOAH2 at 140 ℃ yielded a novel 1D cadmium（Ⅱ） coordination polymer, [Cd（bbp）（p-PDOA）]n （bbp=2,6-bis（benzimidazol-2-yl）pyridine, p-PDOA=p-phenylenedioxydiacetate dianion）, in which CdN3O4 pentagonal bipyramids were linked by p-PDOA ligands in a bis-bidentate mode to construct a zigzag chain with the adjacent Cd…Cd distance of 1.14（1） nm, There exists a 2D supramolecular network linked by π-π stacking with a face-to-face distance of 0.35（1） nm between the 2,6-bis（benzimidazol-2-yl） pyridine ligands and hydrogen-bonding interactions （0.27（4） nm）. A 3D supramolecular network was further constructed by these non-covalent interactions between the zippers. The TG/DTG showed that its chain skeleton was thermally stable up to 389 ℃ and the blue fluorescent emission of the complex was determined at 428 nm in a solid state with its long decay lifetime of 7.24 ns.     

四元交互体系Li+, Mg2+/SO42-, B4O72-—H2O25℃溶解度和溶液物化性质的研究

研究了Li⁺,Mg²+/SO₄^2-,B₄O₇^2-—H₂O四元交互体系25℃时的溶解度和溶液的密度及折光率.四种原始组份未发生脱水作用,体系中也没有复盐或固溶体形成.体系25℃溶解度等温线由五段组成,有四个结晶区,分别对应于四种原始组份,其中以MgB₄O₇·9H₂O的结晶区最大.溶解度等温线上有两个零变量点,其一为MgB₄O₇·9H₂O,MgSO₄·7H₂O,Li₂SO₄·H₂O三盐共饱点,另一为MgB₄O₇·9H₂O,Li₂B₄O₇·3H₂O,Li₂SO₄·H₂O三盐不相称共饱点.     

Syntheses, structures, and magnetic properties of mixed-valent diruthenium(II,III) diphosphonates with discrete and one-dimensional structures

Four mixed-valent ruthenium diphosphonates, namely, Na(4)[Ru(2)(hedp)(2)X]x16H(2)O [X = Cl (1), Br (2)], K(3)[Ru(2)(hedp)(2)(H(2)O)(2)]x6H(2)O (3), and Na(7)[Ru(2)(hedp)(2)Fe(CN)(6)]x24H(2)O (4), where hedp represents 1-hydroxyethylidenediphosphonate [CH(3)C(OH)(PO(3))(2)](4-), were synthesized and structurally characterized. Compounds 1, 2, and 4 show linear chain structures in which the mixed-valent [Ru(2)(hedp)(2)](3-) dimers are linked by X(-) or [Fe(CN)(6)](4-) bridges. Compound 3 contains discrete species of [Ru(2)(hedp)(2)(H(2)O)(2)](3-) where the axial positions of [Ru(2)(hedp)(2)](3-) paddlewheel are terminated by water molecules. Magnetic studies show that significant antiferromagnetic exchanges are mediated between the [Ru(2)(hedp)(2)](3-) (S = 3/2) units through halide bridges in compounds 1 and 2.     

Ultraviolet photodissociation dynamics of the SH radical

Ultraviolet (UV) photodissociation dynamics of jet-cooled SH radical (in X 2pi(3/2), nu"=0-2) is studied in the photolysis wavelength region of 216-232 nm using high-n Rydberg atom time-of-flight technique. In this wavelength region, anisotropy beta parameter of the H-atom product is approximately -1, and spin-orbit branching fractions of the S(3P(J)) product are close to S(3P2):S(3P1):S(3P0)=0.51:0.36:0.13. The UV photolysis of SH is via a direct dissociation and is initiated on the repulsive 2sigma- potential-energy curve in the Franck-Condon region after the perpendicular transition 2sigma(-)-X 2pi. The S(3P(J)) product fine-structure state distribution approaches that in the sudden limit dissociation on the single repulsive 2sigma- state, but it is also affected by the nonadiabatic couplings among the repulsive 4sigma-, 2sigma-, and 4pi states, which redistribute the photodissociation flux from the initially excited 2sigma- state to the 4sigma- and 4pi states. The bond dissociation energy D0(S-H)=29,245+/-25 cm(-1) is obtained.     

Grid‐like Cobalt(II) Layered Complex with an Unprecedented Double 1,2‐Bis(1,2,4‐triazole‐1‐yl)methane Bridges

A novel two‐dimensional cobalt complex, [Co(btrm)₂(dca)]ClO₄ ( 1 , btrm = 1,2‐bis(1,2,4‐triazole‐1‐yl)methane, dca = dicyanamide), was synthesized and characterized. X‐ray diffraction analyses reveal that the title complex crystallizes in the monoclinic space group C2/m with a = 29.507(13)Å, b = 17.804(8) Å, c = 14.709(7) Å, β = 119.916(7)°, Z = 12, and R₁ = 0.0784, wR₂ = 0.2041. The cobalt atom involves a six‐coordinated CoN₆ environment, with a distorted octahedral coordination. Two btrm ligands connect the Co^II atoms with the exodentate nitrogen atoms on the 4‐position of triazole rings to form a sixteen‐membered rhombic grid. The unprecedented double btrm bridges and μ_1,5‐dca bridge connect the cobalt atoms to form a two‐dimensional grid‐like layered structure. The spectroscopic and magnetic properties have also been investigated.     

Homolysis of the Ln-N (Ln = Yb, Eu) bond. Synthesis, structural characterization and catalytic activity of ytterbium(II) and europium(II) complexes with methoxyethyl functionalized indenyl ligands

The interaction of methoxyethyl functionalized indene compounds (C(9)H(6)-1-R-3-CH(2)CH(2)OMe, R =t-BuNHSiMe(2)(1), Me(3)Si (2), H (3)) with [(Me(3)Si)(2)N](3)Ln(mu-Cl)Li(THF)(3)(Ln=Yb (4), Eu (5)) produced a series of new ytterbium(II) and europium(II) complexes via tandem silylamine elimination/homolysis of the Ln-N (Ln=Yb, Eu) bond. Treatment of the lanthanide(III) amides [(Me(3)Si)(2)N](3)Ln(mu-Cl)Li(THF)(3)(Ln=Yb (4), Eu (5) with 2 equiv. of, 1,2 and 3, respectively, produced, after workup, the ytterbium(II) complexes [eta5:eta1-Me(2)Si(MeOCH(2)CH(2)C(9)H(5))(NHBu-t)](2)Yb(II) (6), (eta5:eta1-MeOCH(2)CH(2)C(9)H(5)SiMe(3))(2)Yb(II) (7), (eta5:eta1-MeOCH(2)CH(2)C(9)H(6))(2)Yb(II)(8) and the corresponding europium(II) complexes [eta5:eta1-Me(2)Si(MeOCH(2)CH(2)C(9)H(5))(NHBu-t)](2)Eu(II)(9), (eta5:eta1-MeOCH(2)CH(2)C(9)H(5)SiMe(3))(2)Eu(II)(10) and (eta5:eta1-MeOCH(2)CH(2)C(9)H(6))(2)Eu(II)(11) in moderate to good yield. In contrast, interaction of the corresponding indene compounds 1, 2 or 3 with the lanthanide amides [(Me(3)Si)(2)N](3)Ln (Ln = Yb, Eu) was not observed, while addition of 0.5 equiv. of anhydrous LiCl to the corresponding reaction mixture produced, after workup, the corresponding ytterbium(II) or europium(II) complexes. All the new compounds were fully characterized by spectroscopic and elemental analyses. The structures of complexes, and were determined by single-crystal X-ray analyses. The catalytic activity of all the ytterbium(II) and europium(II) complexes on MMA polymerization was examined. It was found that all the ytterbium(II) and europium(II) complexes can function as single-component MMA polymerization catalysts. The temperature, solvent and ligand effects on the catalytic activity were studied.