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991.
Si-Tai Zheng Huan-Huan Yin Zhao-Guang Ma Nan-Li Sheng Tian-Guang Zhan Xiao-Yang Yan Jiecheng Cui Li-Juan Liu Kang-Da Zhang 《中国化学快报》2019,30(3):707-709
Photoresponsive supramolecular hydrogel was fabricated from a small azobenzene-bridged dicationic pyridinium salt in the aqueous solution. The UV-vis light triggered reversible gel-sol transformation of such low-molecular-weight supramolecular hydrogel was systematically investigated through various analytical techniques. 相似文献
992.
Summary A rapid and accurate LC method is described for simultaneous determination of pseudoephedrine hydrochloride (PSE), acetaminophen (AMP), dextromethorphen hydrobromide (DEX), and diphenhydramine hydrochloride (DPH) in a compound formulation. Chromatographic separation of the four drugs was achieved on a Hypersil CN column (150 mm × 4.6 mm, 5 m particle) by use of a mobile phase comprising a mixture of 3 mM ion-pairing solution, 2% aqueous triethylamine solution, and 2 M phosphoric acid, 68:48:88 (v/v), pH 3.0, delivered at 1.0 mL min–1. Compounds were detected at 215 nm and the run time was less than 10 min. The linearity, accuracy, and precision of the method were found to be acceptable over the concentration ranges 6.1–36.4 g mL–1 for PSE, 65.0–390.0 g mL–1 for AMP, 3.1–18.6 g mL–1 for DEX, and 5.0–30.0 g mL–1 for DPH. 相似文献
993.
ZHENG Li-Min FU Yan LIN Jian-Jun XIN Xin-QuanCoordination Chemistry State Key Laboratory Department of Chemistry Nanjing University Nanjing Jiangsu China 《中国化学》1994,12(3):243-247
The solid-solid state reactions of o-aminobenzoic acid with Zn(OAc)2.2H2O, Cu(OAc)2 .H2O, Ni(OAc)2.4H2O and Mn(OAc)2.4H2O result in the formation of corresponding complexes M(OAB)2 (M = Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Mn(IⅡ)). XRD, IR and elemental analysis methods have been used to characterize the solid products. The activation energies of these reactions, which are calculated from the kinetic data obtained by means of the isothermal electrical conductivity measurement method, have been found to increase in the order: Cu(OAc)2.H2O(37.7 kJ.mol-1)~Mn(OAc)2.4H2O (39.7kJ.mol-1) < Zn(OAc)2.2H2O (56.3 kJ.mol-1) < Ni(OAc)2.4H2O (85.2 kJ.mol-1). The trend is related to their crystal structures. 相似文献
994.
Milena Jelikić-Stankov Dejan Stankov Dušan Malešev Zorica Radović 《Mikrochimica acta》1991,103(1-2):65-70
By means of spectroscopic methods it has been found that demeclocycline reacts with molybdate ions forming a complex compound [MoO3HDMTC]2–. The relative stability constant of this compound has been determined by applying spectrophotometric methods. Under optimum conditions for complex formation a very sensitive spectrophotometric method for the estimation of demeclocycline in the concentration range 5.0–35.1 g/ml is proposed. The detection limit of the method is 2.5 g/ml of demeclocycline. The relative standard deviation (n=10) varies between 0.76% and 1.46%. The method proved to be accurate and sensitive for the analysis of the demeclocycline content in tablets. 相似文献
995.
The quantum groupsgl
andA
are constructed. The representation theory of these algebras is developed and the universalR-matrix is presented. 相似文献
996.
CP violation in partial-decay-rate asymmetries are examined for some two-body baryonic decays of \(B_d^0 - \bar B_d^0 \) system. We discuss two feasible experimental circumstances: the symmetrice + e ? collisions (i) on theZ 0 resonance to produce incoherent \(B_d^0 \bar B_d^0 \) states, and (ii) just above the ?(4S) resonance to produceC=even \(B_d^0 \bar B_d^0 \) states. Using the quark-diagram scheme, we estimate the branching ratios of those decays, and the numbers ofb \(\bar b\) pairs needed for testing theCP-violating effects for 3σ signature. We find that the promising channels may beB d 0 , \(\bar B_d^0 \to p\bar p\) , \(\Delta ^ + \bar \Delta ^ - \) , \(p\bar \Delta ^ - \) , \(\Delta ^ + \bar p\) , \(n\bar n\) , \(\Delta ^0 \bar \Delta ^0 \) , \(n\bar \Delta ^0 \) , \(\Delta ^0 \bar n\) , \(\Sigma _c^ + \bar \Sigma _c^ - \) , \(\Lambda _c^ + \bar \Lambda _c^ - \) , \(\Sigma _c^ + \bar \Lambda _c^ - \) , \(\Lambda _c^ + \bar \Sigma _c^ - \) , \(\Sigma _c^0 \bar \Sigma _c^0 \) , \(\Xi _c^0 \bar \Xi _c^0 \) , which should be interesting for experimental observation. 相似文献
997.
自由电子激光光导的数值模拟与分析 总被引:1,自引:0,他引:1
从一维自由电子激光理论出发,唯象地考虑衍射效应,计算和分析了光导效应的特点和规律;针对曙光一号装置的自由电子激光参数,利用二维理论对光场剖面、填充因子、光场半径等进行了数值模拟;根据计算结果分析和讨论了影响光导的因素和实验条件。 相似文献
998.
Yan H 《Physical review letters》1992,68(20):3048-3051
999.
1000.
CF3O2自由基和NO反应机理的理论研究 总被引:1,自引:0,他引:1
用密度泛函理论(DFT)的B3LYP方法, 分别在6-31G、6-311G、6-311+G(d)基组水平上研究了CF3O2自由基和NO反应机理. 研究结果表明, CF3O2自由基和NO反应存在三条可行的反应通道, 优化得到了相应的中间体和过渡态. 从活化能看, 通道CH3O2+NO→IM1→TS1→IM2→TS2→CF3O+ONO的活化能最低, 仅为70.86 kJ•mol-1, 是主要反应通道, 主要产物是CF3O和NO2. 而通道CH3O2+NO→IM1→TS3→CF3ONO2和CH3O2+NO→TS4→IM3→TS5→IM4→TS6→CF3O+NOO的活化能较高, 故该反应难以进行. 相似文献