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951.
In this paper, experimental results of the investigation of the periodic structure on thermoelectric semiconductor Cu2Se are presented. Periodic structures were formed on surfaces of semiconductors due to multi-beam interaction of Q-switched Nd:YAG laser, which was operated in the lowest order of Gaussian mode and pulse duration 7 ns. Surface temperature evolution and transient reflectivity are studied during laser treatment. Creation of Cu islands in the maximal intensity of interference pattern was found. 相似文献
952.
Dmitry Yu. Murzin 《Reaction Kinetics and Catalysis Letters》2007,90(2):225-232
Reaction route analysis is applied to visualize reaction networks in several heterogeneous catalytic reactions. Combination
of the theory of complex reactions with the notion of catalytic cycles results in a topological representation of complex
mechanisms with the nodes comprising all possible surface species including free sites and branches indicating interconnections
between reactions. 相似文献
953.
Yu. A. Dobrovolsky P. Jannasch B. Lafitte N. M. Belomoina A. L. Rusanov D. Yu. Likhachev 《Russian Journal of Electrochemistry》2007,43(5):489-501
The 2000–2006 achievements in the field of synthesis, property examination, and application of proton-exchange membranes are reviewed on the basis of more than 120 papers. 相似文献
954.
The theory of asymptotic speeds of spread and monotone traveling waves is established for a class of monotone discrete and continuous‐time semiflows and is applied to a functional differential equation with diffusion, a time‐delayed lattice population model and a reaction‐diffusion equation in an infinite cylinder. © 2005 Wiley Periodicals, Inc. 相似文献
955.
A. P. Menushenkov S. Yu. Mukhalov B. I. Sevast'yanov 《Mechanics of Composite Materials》1989,24(5):659-662
Conclusions These tests on quasistationary irradiated for polyethylene-matrix powder-filled composites show that the filler composition and content have marked effects on the damage.There are ranges where the specific loss, the pressure, and the integral recoil pulse decrease as the power density increases because of changes in the damage mechanism, which are most prominent for zirconium oxide as filler. Bulk absorption contributes considerably, and causes various types of defect. Estimates have been made of the pressures arising in explosive matrix decomposition in the bulk together with the specific damage energies.These measurements are useful in modeling laser effects on composites.Translated from Mekhanika Kompositnykh Materialov, No. 5, pp. 868–872, September–October, 1988. 相似文献
956.
Yan Shun MA Qing Hua MENG Hong Yu SHI Yuan De LONG Tian Bao HUANG 《中国化学快报》2006,17(6):807-808
Dencichine (β-N-oxalyl-L-α, β-diaminopropionic acid, L-ODAP), a nonprotein amino acid, is a haemostatic agent present in important Chinese medicinal herbs such as Panax notoginseng, as well as other Panax species1. It was first isolated from the seeds … 相似文献
957.
In this paper we examine clathrate formation in the tetraisoamylammonium propionate-water binary system. We have found formation
of four polyhydrates, two of which are metastable over the whole temperature range studied. All polyhydrate crystals were
isolated and their compositions and densities determined; for (i-C5H11)4NC2H5COO·36.5H2O, unit cell parameters were additionally found. The results are compared with data for tetra-n-butylammonium carboxylate
polyhydrates, and the structure of the title compounds is suggested. It is confirmed that the isoamyl radical stabilizes the
tetradecahedral void of the clathrate hydrate framework better than the n-butyl radical.
Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 35, No. 3, pp. 67–71, May–June, 1994.
Translated by L. Smolina 相似文献
958.
T. N. Sokolova V. R. Kartashov I. V. Timofeev Yu. K. Grishin N. S. Zefirov 《Russian Chemical Bulletin》1994,43(3):461-465
The dependence of the regiochemistry of the mercuration of bornylene on the nature of the mercurating reagent and on the solvent has been found. The structures of the intermediate and transition state in these reactions have been proposed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 501–505, March, 1994. 相似文献
959.
L. T. Eremenko L. B. Romanova M. E. Ivanova I. L. Eremenko S. E. Nefedov Yu. T. Struchkov 《Russian Chemical Bulletin》1994,43(4):619-623
An effective method of esterification of 1,4-cubanedicarboxylic acid with alkylsulfuric acids is proposed. The derivatives of alkanols with substantially different pKa Valus are obtained in high yields. Molecular structures of the esters obtained are confirmed by various methods. The X-ray study showed a remarkable effect of the nature of an alkyl radical on the geometry of the cubane core.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp.668–672, April, 1994.The authors thank Dr. G. V. Lagodzinskaya for analyzing the NMR spectra and for useful discussions. 相似文献
960.
S. V. Lindeman Yu. T. Struchkov I. A. Khotina V. N. Mikhailov A. L. Rusanov 《Russian Chemical Bulletin》1994,43(11):1873-1879
The crystal structure of 1,3,5-tris[4-(phenylethynyl)phenyl]benzene (1) has been investigated. Compound1 represents a model of the repeating unit of the most typical polyphenylene, which contains 1,3,5-trisubstituted benzene rings (chain centers) and acetylenic groups (complex-forming and cross-linking centers) in the main chain. The acetylene groups of neighboring molecules have a tendency to close mutual arrangement, which is favorable for their topochemical interaction. However, the relative conformational rigidity of molecules1 restricts not only the possibility of the optimal adjustment of the reactive sites of neighboring molecules to one another, but also hampers the close packing of molecules in the crystal, which contains channels filled by the solvent molecules (chloroform).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1986–1992, November, 1994.The work was carried out with the financial support of the International Science Foundation and the American Crystallographic Association. 相似文献