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41.
铝酸钠和含硅铝酸钠溶液结构和性质的研究 总被引:1,自引:0,他引:1
本文通过对铝酸钠和硅铝酸钠溶液的红外光谱、拉曼光谱、粘度、表面张力、丁达尔现象和聚沉等光谱和物理化学性质的研究测定,分析了硅在铝酸钠溶液中的行为.认为硅主要是取代Al-O-Al结构中的Al,形成Al-O-Si结构和Al-O-Si-O-Al-O结构等多种形式硅氧铝键以及由氢键相连的大分子结构.这种结构直接影响其物理化学性质,表现为随硅含量增加表面张力增加,粘度上升,具有丁达尔现象等.说明含硅铝酸钠溶液中存在大分子的胶性基团,属于无机高分子溶液,这种网络状"大分子"结构是硅铝酸钠溶液稳定的原因. 相似文献
42.
Bong H. Lian 《Communications in Mathematical Physics》1994,163(2):307-357
Inspired by a recent work of Frenkel-Zhu, we study a class of (pre-)vertex operator algebras (voa) associated to the self-dual Lie algebras. Based on a few elementary structural results we propose thatV, the category of Z+-graded prevoasV in whichV[0] is one-dimensional, is a proper setting in which to study and classify simple objects. The categoryV is organized into what we call the minimalk
th types. We introduce a functor —which we call the Frenkel-Lepowsky-Meurman functor—that attaches to each object inV a Lie algebra. This is a key idea which leads us to a (relative) classification of thesimple minimal first type. We then study the set of all Virasoro structures on a fixed minimal first typeV, and show that they are in turn classified by the orbits of the automorphism group Aut((V)) in cent((V)). Many new examples of voas are given. Finally, we introduce a generalized Kac-Casimir operator and give a simple proof of the irreducibility of the prolongation modules over the affine Lie algebras. 相似文献
43.
Y. Lian H. Gao S. X. Dou H. Wang P. Ye Q. Guan J. Wang 《Applied physics. B, Lasers and optics》1994,59(6):655-658
Mechanism transitions of Self-Pumped Phase Conjugation (SPPC) with wavelength and doping concentration are observed in KTN:Fe (KTa1 –x
Nb
x
O3:Fe with
x
= 0.48) crystals. The SPPC mechanism in KTN: Fe (0.4 wt. %) crystal transforms from Stimulated Photorefractive Backscattering and Four-Wave Mixing (SPB-FWM) to cat (or total internal reflection) as the wavelength increases from 514.5 nm to 620 nm. SPPC at 514.5 nm is formed with the cat mechanism in a 0.2 wt. % doped KTN:Fe crystal, while with the SPB-FWM mechanism in a 0.4 wt. % doped one. These mechanism transitions are discussed with respect to the dependence of the backscattering gain coefficient of the crystals on wavelength and doping concentration. 相似文献
44.
Hongmin Liu Xiaojiang Ye Zhiwei Lian Yuangao Wen Wenfeng Shangguan 《Research on Chemical Intermediates》2006,32(1):9-16
Formaldehyde is one of the most harmful pollutants that endanger occupants' health and the way of its effective removal has
become a focus in the field of air quality. This paper studies the static photocatalytic removal of formaldehyde experimentally
and finds out that carbon monoxide, which is more harmful to occupants' health than the formaldehyde itself, is one of the
by-products in the process of photocatalytic oxidation of formaldehyde. The increase of carbon monoxide concentration should
be taken into consideration in the photocatalytic application. The photocatalyst surface at room temperature can weakly adsorb
CO and CO2, which can deactivate the photocatalysts. 相似文献
45.
Lysophosphatidic acid (LPA, 1- or 2-acyl-sn-glycerol 3-phosphate) displays an intriguing cell biology that is mediated via interactions both with G-protein coupled seven transmembrane receptors and with the nuclear hormone receptor PPARgamma. Synthesis and biological activities of fluorinated analogues of LPA are still relatively unknown. In an effort to identify receptor-selective LPA analogues and to document in detail the structure-activity relationships of fluorinated LPA isosteres, we describe a series of monofluorinated LPA analogues in which either the sn-1 or the sn-2 hydroxy group was replaced by fluorine, or the bridging oxygen in the monophosphate was replaced by an alpha-monofluoromethylene (-CHF-) moiety. The sn-1 or sn-2 monofluorinated LPA analogues were enantiospecifically prepared from chiral protected glycerol synthons, and the alpha-monofluoromethylene-substituted LPA analogues were prepared from a racemic epoxide with use of a hydrolytic kinetic resolution. The sn-2 and sn-1 fluoro LPA analogues were unable to undergo acyl migration, effectively "freezing" them in the sn-1-O-acyl or sn-2-O-acyl forms, respectively. The alpha-monofluoromethylene LPA analogues were unique new nonhydrolyzable ligands with surprising enantiospecific and receptor-specific biological readouts, with one compound showing a 1000-fold higher activity than native LPA for one receptor subtype. 相似文献
46.
铱(Ⅲ)与2-(5-溴-2-吡啶偶氮)-5-二甲氨基苯胺的显色反应及其应用 总被引:1,自引:0,他引:1
研究了试剂2_(5_溴_2_吡啶偶氮 )_5_二甲氨基苯胺 (5_Br_PADMA)与铱 (Ⅲ )的显色反应 ;在 pH4.75~6.00的HAc -NaAc缓冲溶液中 ,铱 (Ⅲ )与5_Br_PADMA形成摩尔比为1∶2型稳定的红色络合物 ,在0.6mol/LH2SO4溶液中 ,其最大吸收波长为558nm ,表观摩尔吸光系数为5.1×104L/(mol·cm) ,铱 (Ⅲ )含量在0~0.8mg/L范围内符合比尔定律 ,采用加入适量EDTA的方法消除了Fe3 + 、Co2 + 、Ni2 + 等干扰离子 ,建立了在二元络合物体系中测定微量铱 (Ⅲ )的灵敏度高、选择性好、简便、稳定的分光光度法 相似文献
47.
石墨炉原子吸收法直接测定高温合金中硅 总被引:2,自引:0,他引:2
研究了混合基体改进剂,灰北、原子化温度以及共存元素的干扰,采用镧和钙作混合基体改进剂后,硅的灵敏度提高,抗干扰能力增强,可以用石墨炉原子吸收直接测定高温合多中硅。方法特征量为0.2ng,检出限为2.3μg/g,对于含硅量为400μg/g左右的合金样品,相对标准偏差为5%左右,回收率在90%-110%之间。 相似文献
48.
The atom transfer radical polymerization(ARP)of (-)-menthyl methacrylatc((-)-MnMA) mediated by CuCl/bipyridine and ethy1 2-bromopropionate or 1-phenylethyl bromide in THF system has been studied.The dependence of the specific rotation on molecular weight and the CD of Poly((-)-MnMA) thus obatined was investigated. 相似文献
49.
非晶态镍磷—镍钨磷双层组合镀层的耐蚀性能研究 总被引:2,自引:0,他引:2
本文对比研究了镍磷镀层、镍钨磷镀层及非晶态镍磷和镍钨磷双层组合镀层的耐蚀性能,分别进行了各种镀层的浸渍腐蚀实验,镀层的X射线衍射图象、镀层的扫描电镜图象、以及在工厂实际的腐蚀环境里进行的腐蚀实验。实验结果表明镍磷及镍钨磷双层组合镀层的耐 性优于镍磷镀层、镍钨磷镀层的耐蚀性。 相似文献
50.